• 펄프종이기술
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• 제42권2호
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• pp.46-52
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• 2010

The annals of Joseon Dynasty has been known as one of the UNESCO's Memory of the World Heritage. The annals of Joseon Dynasty composed with two kind of books, wax coated book and non coated book. Especially the waxed book have been severely damaged by various reason. For the safety preservation of the annals of Joseon Dynasty waxed book, the thermal ageing mechanism of beeswax coated Hanji paper has been evaluated. The weight loss of waxed Hanji were rapidly increased until 30 days in three temperatures(105, 120 & $150^{\circ}C$) and stabilized after 30 days. The acid value and relative intensity of carbonyl groups in beeswax were increased with strong conditions. This means that the deterioration of beeswax should be progressed with oxidizing reaction. The physical strength and the crystallinity of dewaxed Hanji were decreased with ageing time.

• 펄프종이기술
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• 제44권3호
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• pp.15-21
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• 2012

The optimum dewaxing ratio in dewaxing treatment by the heat and pressure method was investigated by considering aging stability of dewaxed Hanji. Commercial Hanji was coated with beeswax and thermally aged at $150^{\circ}C$ for 24 hours. Then it was dewaxed using the laboratory sheet press equipped with hot plates on both top and bottom sides. Dewaxing ratio was controlled by pressing temperature and time. Four type of dewaxed Hanji samples with different dewaxing ratio were prepared and thermally aged at $150^{\circ}C$. Then the aging stability of dewaxed Hanji samples was evaluated in terms of optical and strength properties. It was found that the aging stability of dewaxed Hanji was superior with higher dewaxing ratio. The result concluded that, in the aspect of aging stability, the coated beeswax in beeswax-treated Hanji shall be completely removed if the coated wax would be dewaxed.

• 펄프종이기술
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• 제43권3호
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• pp.73-79
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• 2011

The annals of Joseon Dynasty is one of the UNESCO's Memory of the World Register. For the safety preservation of wax applied volumes of the annals of Joseon Dynasty, the aging behavior of beeswax and beeswaxed Hanji with $CO_2$, $O_3$, $SO_2$ and $NO_2$ gas has been evaluated. The weight loss of beeswaxed Hanji after aging under ozone gas were increased because of strong acidity of ozone. The acid value and relative intensity of carbonyl groups in beeswax were stabilized with aging time. The physical strength of dewaxed Hanji after ozone aging were rapidly decreased by aging time. The crystallinity of dewaxed Hanji were stabilized at all aging times.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2009년도 추계학술발표회 논문집
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• pp.13-17
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• 2009

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
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• pp.73-79
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• 2011

The annals of Joseon Dynasty has been known as one of the UNESCO's Memory of the World Heritage. Some of the annals of Joseon Dynasty was composed with wax coated book. Especially the waxed book have been severely damaged by various reason. To find out the safety preservation method of the annals of Joseon Dynasty waxed book, the characteristics of reinforced dewaxed Hanji was evaluated in this paper. From strength properties of MC treated dewaxed Hanji after dewaxing with different method, dewaxing ratio was been high, polymer treated dew axed Hanji showed a better strength. As the aging time, polymer layer on dewaxed Hanji was became brittle and cracked.