• Journal of the Korean Electrochemical Society
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• v.12 no.4
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• pp.342-348
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• 2009

Zn/Air secondary batteries are high energy density type and environment-friendly. Also, they have safer properties than batteries of other type by low manufacturing cost and using the electrolyte solution. But, they have a weak concerning large output discharge. Oxygen evolution reaction(OER) and oxgen reduction reaction(ORR) in aqueous solution make a result of a decrease of cell efficiency and life span. Therefore, to minimize the voltage drop from between OCV and charge/discharge voltage is key point. The problem should be solved through developing catalysts of high efficiency. In this study, we synthesized $Pr_{1-x}(Sr,\;Ca)_x\;CoO_3$ powders by citric method and then measured physical characteristics of each powder by XRD, SEM, TGA etc. We examined its electrochemical properties by the cathodic polarization, anodic polarization and cyclic voltammogram. We achieved results that new catalysts showed better performances than existing $La_{1-x}Sr_xCoO_3$, $La_{1-x}Ca_xCoO_3$, ect. catalysts prepared in our lab.

• 전자공학회논문지 IE
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• v.46 no.4
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• pp.1-7
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• 2009

The final goal of ITS and ETC will be to improve the traffic efficiency and mobile safety without new road construction. DSRC system is emerging nowadays as a solution of them. China DSRC standard which was released in May 2007 has low bit rate, short message and simple MAC control. The DSRC system users want a long lifetime over 1 year with just one battery. In this paper, we propose the SoC of very low power consumption architecture. Several digital logic concept and analog power control logics were used for very low power consumption. The SoC operation mode and clock speed, operation voltage range, wakeup signal detector, analog comparator and Internal Voltage Regulator & External Power Switch were designed. We confirmed that the SoC power consumption is under 8.5mA@20Mhz, 0.9mA@1Mhz in active mode, and under 5uA in power down mode, by computer simulation. The design of SoC was finished on Aug. 2008, and fabricated on Nov. 2008 with $0.18{\mu}m$ CMOS process.

• Journal of Advanced Navigation Technology
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• v.18 no.1
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• pp.35-43
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• 2014

In this paper, it is about to non-contact wireless power transmission according to various conditions of self induction principle between the two planar coils at a transmission unit and a receiving unit based on the theory of wireless power transmission. The experiments are occurred in order to power transfer of noncontact method from designed wireless circuits in the primely coil and secondary coil, and the applying to Half Bridge Resonant converter transmission unit and receiving unit. and that were able to prepared circumstance to calculate of the output voltage and power source. The main power of the inductive coupling the resonant converter at the transmission unit is converted electrical energy using the solar cell module and artificial light source (halogen lamp) as a replace light and received 24 V power supply from solar power was used a input power source for the wireless power transmission device. Experimental results, to received of power is used to illuminate the lighting and to charge the battery in receiving circuit.And the wireless power transmission efficiency measured at the output side of the transmission unit is obtained about 70% to 89% compared to input power of receiving unit.In addition, efficiency were tested through ID verification method and comparing the phase difference between the voltage when foreign substances interfere with wireless power transmission.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.4
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• pp.39-48
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• 2020

Since the fire accident of ESS (energy storage system) occurred at Gochang KEPCO Power Testing Center in August 2017, 29 fire cases with significant property losses have occurred in Korea. Although the cause of fire accidents have not been identified precisely, it should be considered battery and PCS (power conditioning system) as well as unbalance issues in the distribution system. In particular, circulating currents in a neutral line of a grid-connected transformer, which can affect a magnetized current, may have a negative effect on the ESS with unintentional core saturation and surge voltages at the secondary side of the transformer. Therefore, this paper proposes the modeling of the distribution system, which was composed of a substation, grid-connected transformer, and customer loads using PSCAD/EMTDC S/W, to analyze the phenomena of circulating current and surge voltages of the transformer with unbalanced currents in the distribution system. This paper presents a countermeasure for a circulating current with the installation of NGR (neutral grounding resistor) in grid-connected transformer. From the simulation results, it is clear that exceeding the circulating current and surge voltage at the secondary side of the transformer can be one of the causes of fire accidents.

• Journal of the Korean Electrochemical Society
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• v.21 no.2
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• pp.39-46
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• 2018

Many studies on the electrochemical performance of Li secondary batteries have been obtained using coin-type cells due to the ease of assembly, low cost and ensuring reproducibility. The coin-type cell consists of a case, a gasket, a spacer disk, and a wave spring. These structural features require a greater amount of liquid electrolyte to assemble than other types of cells such as laminated cells and cylindrical cells. Nevertheless, little research has been conducted on the effect of excess liquid electrolytes on the electrochemical performances of Li secondary batteries. In this study, we investigate the effect of different amounts of electrolyte on the coin-type cells. The amount of electrolytes is adjusted to 30 and $100mg\;mAh^{-1}$. Cycle performances at room temperature ($25^{\circ}C$) and high temperature ($60^{\circ}C$) and high voltage are performed to investigate the electrochemical properties of the different amount of electrolytes. In the case of the unit cell including the electrolyte of $30mg\;mAh^{-1}$, the discharging capacity retention characteristic is excellent in comparison with the case of $100mg\;mAh^{-1}$ under the high temperature and high voltage condition. The former shows a larger increase in internal resistance than the latter, confirming that the amount of electrolyte significantly influences the discharge capacity retention characteristics of the battery.

• Korean Journal of Materials Research
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• v.17 no.8
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• pp.447-451
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• 2007

We investigated the dependence of the various annealing conditions and thickness ($6\sim45nm$) of the Ti-doped $Al_2O_3$ coating on the electrochemical properties and the capacity fading of Ti-doped $Al_2O_3$ coated $LiCoO_2$ films. The Ti-doped-$Al_2O_3$-coating layer and the cathode films were deposited on $Al_2O_3$ plate substrates by RF-magnetron sputter. Microstructural and electrochemical properties of Ti-doped-$Al_2O_3$-coated $LiCoO_2$ films were investigated by transmission electron microscopy (TEM) and a dc four-point probe method, respectively. The cycling performance of Ti-doped $Al_2O_3$ coated $LiCoO_2$ film was improved at higher cut-off voltage. But it has different electrochemical properties with various annealing conditions. They were related on the microstructure, surface morphology and the interface condition. Suppression of Li-ion migration is dominant at the coating thickness >24.nm during charge/discharge processes. It is due to the electrochemically passive nature of the Ti-doped $Al_2O_3$ films. The sample be made up of Ti-doped $Al_2O_3$ coated on annealed $LiCoO_2$ film with additional annealing at $400^{\circ}C$ had good adhesion between coating layer and cathode films. This sample showed the best capacity retention of $\sim92%$ with a charge cut off of 4.5 V after 50 cycles. The Ti-doped $Al_2O_3$ film was an amorphous phase and it has a higher electrical conductivity than that of the $Al_2O_3$ film. Therefore, the Ti-doped $Al_2O_3$ coated improved the cycle performance and the capacity retention at high voltage (4.5 V) of $LiCoO_2$ films.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.162-168
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• 2013

$Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) nano-composite is a promising cathode material for xEV application due to its high theoretic capacity. However high voltage operating system of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) has worked as a hurdle in its application because of the inherent demerits, such as cycle life degradation and gas evolution. In order to enhance cell performance of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn)/graphite cell, we examined electrolyte mainly composed of FEC, fluroalkyl ether and $LiPF_6$ (F-based EL). F-based EL showed much better discharging retention ratio than 1.3 M $LiPF_6$ EC/EMC/DMC (3/4/3, v/v/v) (STD). Furthermore gas evolution, especially CO and $CO_2$ during $60^{\circ}C$ storage for 30 days was dramatically reduced owing to thermal stable SEI formation effect of F-based EL.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.832-840
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• 2019

To improve the electrochemical performances of the cathode materials, boron-doped $LiNi_{0.90}Co_{0.05}Ti_{0.05}O_2$ were synthesized by using concentration gradient precursor. The characteristics of the prepared cathode materials were analyzed by XRD, SEM, EDS, PSA, ICP-OES and electrical conductivity measurement. The electrochemical performances were investigated by initial charge/discharge capacity, cycle stability, C-rate, cyclic voltammetry and electrochemical impedance spectroscopy. The cathode material with 0.5 mol% boron exhibited a capacity of 187 mAh/g (0.5 C) in a voltage range of 2.7~4.3 V(vs. $Li/Li^+$), and an capacity retention of 94.7% after 50 cycles. In the relatively high voltage range of 2.7~4.5 V(vs. $Li/Li^+$), it showed a high capacity of 200 mAh/g and capacity retention of 80.5% after 50 cycles.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.6
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• pp.26-37
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• 2019

Recently, standardization of installation progress and technology of site acceptance test(SAT) for energy storage system(ESS) are being required due to performance of ESS depending on working condition and environment even though the quality and safety of each component of ESS　is guaranteed. And also, it has been required to perform not only performance testing by H/W equipments but also performance verification by S/W tool, in order to more accurately and reliably validate the performance of the ESS in advanced countries. Therefore, this paper proposes evaluation algorithm for SAT to evaluate performance of ESS and presents modeling of SAT test equipment for ESS by using PSCAD/EMTDC. Furthermore, 30[kW] scaled portable test equipments is implemented based on the proposed algorithm and modeling. From the various simulation and test results, it is confirmed that performance of ESS related to characteristics of capacity and Round-trip efficiency, Duty-cycle efficiency, low voltage ride through(LVRT) and Anti-islanding can be accurately evaluated and that the simulation results of PSCAD/EMTDC are identical to test results of 30[kW] test equipment.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.14 no.1
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• pp.56-69
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• 2021

In this paper, the PV system with a link to the commercial system needs some advantages like small capacity, high power factor, high reliability, low harmonic output, maximum power operation of solar cell, and low cost, etc. as well as the properties of inverter. To transfer the PV energy of photovoltaic power generation system to the system and load, it requires PCS in both directions. The purpose of this paper is to confirm the stable power supply through the load leveling by presenting the PCS considering ESS of photovoltaic power generation. In order to achieve these purpose, 5 step process of operation mode algorithm were used according to the solar insolation amount and load capacity and the controller for charging/ discharging control was designed. For bidirectional and effective energy transfer, the bidirectional converter and battery at DC-link stage were connected and the DC-link voltage and inverter output voltage through the interactive inverter were controlled. In order to prove the validity of the suggested system, the simulation using PSIM was performed and were reviewed for its validity and stability. The 3[kW] PCS was manufactured and its test was conducted in order to check this situation. In addition, the system characteristics suggested through the test results was verified and the PCS system presented in this study was excellent and stronger than that of before system.