• 한국전기전자재료학회논문지
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• 제19권2호
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• pp.139-144
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• 2006

A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1598-1602
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• 2009

The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.

• 한국반도체및디스플레이장비학회:학술대회논문집
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• 한국반도체및디스플레이장비학회 2007년도 춘계학술대회
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• pp.244-249
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• 2007

In this paper, in order to get the characteristics of the lithium secondary cell, such as cycle life, charge and discharge characteristic, temperature characteristic, self-discharge characteristic and the capacity recovery rate etc, we build a mathematical model of battery. In this one-dimensional model, Seven governing equations are made to solve seven variables $c,\;c_s,\;{\Phi}_1,\;{\Phi}_2,\;i_2,\;j\;and\;T$. The mathematical model parameters used in this model have been adjusted according to the experimental data measured in our lab. The connecting research of this study is to get an accurate estimate of the capacity of battery through comparison of results from simulation and fuzzy logic system. So the result data from this study is reorganized to fit the fuzzy logic algorithm.

• 공업화학
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• 제8권4호
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• pp.667-672
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• 1997

고용량 Nickel/Metal hybride 전지의 온도 거동을 3차원 유한요소법 software인 NISA를 사용하여 해석하였다. 전지 내부의 열전도에는 미분형 에너지 수지식을, 외부 대기와의 접촉면은 대류 열전달 방식을 사용하였다. 전지 온도에 영향을 미치는 요소인 열발생량과 대류 열전달계수에 대한 실험을 행하였고, 이 결과로부터 일반식을 도출하였다. 금속 재질의 cooling fin을 사용하므로써 급속한 충전이나 방전시 야기될 수 있는 온도 상승을 상당 부분 방지할 수 있었다. 전지 외벽에 열전도도가 낮고 얇은 절연물질을 부착하여도 최고온도의 상승에 미치는 영향은 미미하였다.

• 전기화학회지
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• 제5권2호
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• pp.74-78
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• 2002

아연공기전지는 공기중의 산소를 사용하므로 cathode의 재활용이 가능하다는 장점이 있으며 아연의 이론용량이 820(mAh/g)으로 상당히 높다. 그러나, 아연공기전지는 cathodf치 기공이 너무 작으면 외부로부터 유입되는 산소량이 부족하여 전지의 방전전압이 낮아지는 결과를 초래하게 되며 cathode에 포함되어 있는 도전재의 함량에 따라 저항 및 기공율에 많은 변화를 보이고 있다. 이에 본 연구에서는 전지의 용량, 출력특성, 방전전압, DC저항, ASTM에 의한 기공율 측정을 통해 도전재의 종류 및 함량이 아연공기전지에 미치는 영향을 연구하였으며, Super P의 도전재를 $5wt\%$ 첨가하였을 때 가장 우수한 전지특성을 얻을 수 있었다.

• 전기화학회지
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• 제2권1호
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• pp.46-49
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• 1999

Electron-beam 증발장치를 이용하여 리튬 박막 2차 전지 양극용 lithium cobalt oxide 박막을 제조하였다. Stainless steel -기판 위에 입혀진 $LiCoO_2$ 박막은 열처리 과정을 거쳐 잘 발달된 hexagonal 구조의 (003)면을 나타냈으며, 3.9 V 부근에서 전위 평탄 영역이 나타났다. $LiCoO_2$, 박막은 증착속도가 증가함에 따라 Li/co 조성비가 양론비에 근접하였으며, $15{\AA}/s$의 증착속도로 제작한 경우 높은 방전용량을 나타내었다. 열처리 온도가 증가함에 따라 용량이 증가하여 $700^{\circ}C$에서 최대 값을 나타내었으나, 그 이상의 온도에서는 기판과의 반응 때문에 방전용량이 현저히 감소하였다. 박막 내부의 리튬과 코발트의 불균일한 조성은 초기 방전용량의 감소를 가져왔다.

• 대한전자공학회논문지SD
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• 제46권12호
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• pp.43-49
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• 2009

본 논문에서는 무선 센서 노드의 다양한 전력 소모 유형을 고려한 배터리 수명 계산 방법을 제시하였다. 무선센서 노드의 전력 소모 유형을 일회성 및 주기성으로 구분하고 여러 가지 동작 모드에 따른 소비 전력의 차이를 고려함으로써 전체 전류 소모량을 계산 할 수 있다. 여기에 배터리의 자기 방전율을 추가적으로 고려함으로써 센서노드의 배터리 수명을 계산하는 일반화된 식을 제시하였다. 제시된 계산 방식은 Zigbee등 임의의 센서노드에서 배터리 수명을 계산하는데 유용하게 이용될 수 있을 것이다.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2000년도 전력전자학술대회 논문집
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• pp.493-497
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• 2000

A battery is the device that transforms the chemical energy into the direct-current electrical energy without a mechanical process. Unit cells are connected in series to obtain the required voltage while being connected in parallel to organize capacity for load current. Because the voltage drop down in one set of battery is faster than in two one it may result in the low efficiency of power converter with the voltage drop and cause the system shutdown. However when the system being shutdown. However when the system being driven in parallel a circular-current can be generated,. It is shown that as a result the new batteries are heated by over-charge and over-discharge and the over charge current increases rust of the positive grid and consequently shortens the lifetime of the new batteries. The difference between the new batteries and old ones is the amount of internal resistance. In this paper we can detect the unbalance current using the microprocessor and achieve the balance current by adjusting resistance of each set, The internal resistance of each set becomes constant and the current of charge and discharge comes to be balanced by inserting the external resistance into the system and calculating the change of internal resistance.

• 반도체디스플레이기술학회지
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• 제6권1호
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• pp.53-57
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• 2007

In this paper, the intelligent estimation algorithm is developed for residual quantity estimate of lithium secondary cell and we suggest the control algorithm to get battery SOC through thermal modeling of electric cell. Lithium secondary cell gives cycle life, charge characteristic, discharge characteristic, temperature characteristic, self-discharge characteristic and the capacity recovery rate etc. Therefore, we make an accurate estimate of the capacity of battery according to thermal modeling to know the capacity of electric cell that is decreased by various special quality of lithium secondary cell. And we show effectiveness through comparison of value as result that use simulation and fuzzy logic.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1414-1417
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• 1996

The purpose of this study Is to research and develop $V_{6}O_{13}$ composite cathode for lithium thin film battery. $V_{6}O_{13}$ represents a class of cathode active material used in Li rechargeable batteries. In this study, we investigated cyclic voltammetry and charge/discharge characteristics of $V_6O_{13}$/SPE/Li cells. Cyclic voltammogram of $V_{6}O_{13}$/SPE/Li cell at scan rate 1mV/sec showed reduction peaks of 2.25V and 2.4V and oxidation peaks of 2.4V and 2.2V. The discharge curve of $V_{6}O_{13}$/SPE/Li cell showed 4 potential plateaus. The discharge capacity was decreased in the beginning of charge/discharge cycling. After 8th cycling, the discharge capacity was stable. The discharge capacity of 1st cycle and 15th cycle was 290mAh/g and 147mAh/g at $25^{\circ}C$, respectively.