• Title/Summary/Keyword: Batch method

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Batch Scale Storage of Garlic by Irradiation Combined with Natural Low Temperature (방사선(放射線) 조사(照射)와 자연저온(自然低溫)에 의한 마늘의 저장)

  • Cho, Han-Ok;Kwon, Joong-Ho;Byun, Myung-Woo;Yoon, Hyung-Sik
    • Korean Journal of Food Science and Technology
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    • v.16 no.1
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    • pp.66-70
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    • 1984
  • An attempt was made on the development of a commercial scale storage method of garlic by irradiation. Irradiated garlics with 50, 100 and 150 Gy were stored at natural low temperature storage room $(12{\pm}6^{\circ}C,{\;}75-85%{\;}RH)$ and the physicochemical properties during the 10 months storage were investigated. The unirradiated garlic was mostly sprouted after 8 months storage, whereas the sprouting of all irradiated groups was completely inhibited until 10 months storage, The rotting rate and weigh loss of garlic after 10 months storage were reduced by 25 to 54% at 100 Gy irradiation compared with those of an unirradiated group. The moisture content remained relatively constant during the whole storage period. The total sugar content was increased with storage period. Ascorbic acid content was also decreased until 8 months storage but its content was rapidly increased along with sprouting. Garlic was marketable after 10 months storage by 100 Gy irradiation combined with natural low temperature.

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As (v) immobilization in an aqueous solution by zerovalent iron under various environmental conditions (영가철(Zerovalent Iron)을 이용한 수용액 중 비소(V)의 불용화)

  • Yoo, Kyung-Yoal;Ok, Yong-Sik;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.197-203
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    • 2007
  • Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. The objective of this research was to assess the efficiency of ZVI for immobilization of As (V) in the contaminated water under various chemical conditions. Batch-type experiments showed that the immobilization process followed a first-order kinetic model. Rate constant (k) of the reaction increased consistently and proportionally as increasing ZVI concentrations from 1% (0.158 $hr^{-1}$) to 3% (0.342 $hr^{-1}$), and temperatures from $15^{\circ}C$ (0.117 $hr^{-1}$) to $35^{\circ}C$ (0.246 $hr^{-1}$), respectively. Whereas the rate constant decreased as increasing As (V) concentrations from 1 mg $\Gamma^{-1}$ (0.284 $hr^{-1}$) to 3 mg $\Gamma^{-1}$ (0.153 $hr^{-1}$), and the initial pH from 3 (0.393 $hr^{-1}$) to 9 (0.067 $hr^{-1}$), respectively. Results demonstrated that As (V) in an aqueous solution was rapidly immobilized by ZVI treatments. Zerovalent iron was fast method for remediation of As (V) contaminated water.

Rinsing Water Reduction in the Food (Kimchi) Industry (식품(김치)산업에서 세척수 사용량 절감에 관한 연구)

  • Yi, Hosang;Hyoung, Hoon;Choo, Kwang-Ho;Lee, Chung-Hak
    • Clean Technology
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    • v.5 no.1
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    • pp.78-85
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    • 1999
  • In the Kimchi manufacturing industry that has recently been on its greatest growth, the rinsing process for salt-pickled Chinese cabbage in a brining step generates a vast amount of rinsing wastewater containing salts, colloids, and organics released from the raw material. In this study, the experimental method was developed to optimize the rinsing water consumption and thus to minimize the rinsing wastewater generation. The continuous counter-current rinsing basin in the actual plant was simulated through the lab-scale three batch-wise rinsing tanks. Rinsing efficiencies for the brined cabbage from the same brining tank were almost in the same level, whereas those varied substantially from source to source in the raw Chinese cabbage provided. When rinsing water used were decreased from 3.3 L/head to 2.7 L/head, no significant change was observed with respect to COD, turbidity, conductivity, $Na^+$, and $Cl^-$ concentrations in the extracted solution of the rinsed cabbage. However, the quality of the extracted solution was badly deteriorated as the amount of rinsing water used dropped down to below 2.7 L/head. The reduction of rinsing water up to 18% was proved to be possible without any negative effect on the quality of the product, Kimchi.

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Orbit Determination of High-Earth-Orbit Satellites by Satellite Laser Ranging

  • Oh, Hyungjik;Park, Eunseo;Lim, Hyung-Chul;Lee, Sang-Ryool;Choi, Jae-Dong;Park, Chandeok
    • Journal of Astronomy and Space Sciences
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    • v.34 no.4
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    • pp.271-280
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    • 2017
  • This study presents the application of satellite laser ranging (SLR) to orbit determination (OD) of high-Earth-orbit (HEO) satellites. Two HEO satellites are considered: the Quasi-Zenith Satellite-1 (QZS-1), a Japanese elliptical-inclinedgeosynchronous-orbit (EIGSO) satellite, and the Compass-G1, a Chinese geostationary-orbit (GEO) satellite. One week of normal point (NP) data were collected for each satellite to perform the OD based on the batch least-square process. Five SLR tracking stations successfully obtained 374 NPs for QZS-1 in eight days, whereas only two ground tracking stations could track Compass-G1, yielding 68 NPs in ten days. Two types of station bias estimation and a station data weighting strategy were utilized for the OD of QZS-1. The post-fit root-mean-square (RMS) residuals of the two week-long arcs were 11.98 cm and 10.77 cm when estimating the biases once in an arc (MBIAS). These residuals were decreased significantly to 2.40 cm and 3.60 cm by estimating the biases every pass (PBIAS). Then, the resultant OD precision was evaluated by the orbit overlap method, yielding three-dimensional errors of 55.013 m with MBIAS and 1.962 m with PBIAS for the overlap period of six days. For the OD of Compass-G1, no station weighting strategy was applied, and only MBIAS was utilized due to the lack of NPs. The post-fit RMS residuals of OD were 8.81 cm and 12.00 cm with 49 NPs and 47 NPs, respectively, and the corresponding threedimensional orbit overlap error for four days was 160.564 m. These results indicate that the amount of SLR tracking data is critical for obtaining precise OD of HEO satellites using SLR because additional parameters, such as station bias, are available for estimation with sufficient tracking data. Furthermore, the stand-alone SLR-based orbit solution is consistently attainable for HEO satellites if a target satellite is continuously trackable for a specific period.

A Study on the Application of Manganese Oxidizing Bacteria for Manganese Treatment in Acid Mine Drainage (산성광산배수의 망간처리를 위한 MOB 적용에 관한 연구)

  • Lee, Kang Yu;Jang, Min;Park, In Gun;Um, Tae Young;Lim, Kyeong Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.564-570
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    • 2013
  • Domestic treatment facilities for acid mine drainage (AMD) mostly used a passive treatment process. But some passive treatment facility discharged high manganese concentrations because it is required high pH (>9) for abiotic oxidation of Mn(II) to Mn(IV). This study was focused on the feasibility of biological manganese treatment using the manganese-oxidizing bacteria (Pseudomonas sp. MN5) from AMD and economical application method of it. To investigate the various conditions of water quality the most part of the experiments were based on batch test. And result of it showed that maximum manganese oxidation rate were $10.4mg/L{\cdot}h$ at the pH7. We also performed small column tests in which MOB were attached to the functional polyurethane (FPU) media containing alkaline chemicals. Manganese concentration decreased 42 mg/L to below 6 mg/L. But anaerobic condition formed by excessive bacterial respiration in column resulted in increasing effluent manganese concentration.

Synthesis and Single-crystal Structure of Fully Dehydrated Fully Ca2+exchanged Zeolite Y (FAU), |Ca35.5|[Si121Al71O384]-FAU

  • Seo, Sung-Man;Choi, Sik-Young;Suh, Jeong-Min;Jung, Ki-Jin;Heo, Nam-Ho;Lim, Woo-Taik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1703-1710
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    • 2009
  • The single-crystal structure of |$Ca_{35.5}$|[$Si_{121}Al_{71}O_{384}$]-FAU, $Ca_{35.5}Si_{121}Al_{71}O_{384}$ per unit cell, a = 24.9020(10) $\AA$, dehydrated at 673 K and 2 ${\times}\;10^{-6}$Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd$\overline{3}$m at 294 K. The large single crystals of zeolite Y (Si/Al = 1.70) were synthesized up to diameters of ${\mu}m\;and\;Ca^{2+}$-exchanged zeolite Y were prepared by ion exchange in a batch method of 0.05 M aqueous Ca($NO_3)_2$ for 4 hrs at 294 K. The structure was refined using all intensities to the final error indices (using only the 971 reflections for which $F_o\;>\;4{\sigma}(F_o))\;R_1$ = 0.038 (based on F) and $R_2$ = 0.172 (based on $F^2$). About 35.5 $Ca^{2+}$ ions per unit cell are found at an unusually large number of crystallographically distinct positions, four. Nearly filling site I (at the centers of the double 6-rings), 14.5 octahedrally coordinated $Ca^{2+}$ ions (Ca-O = 2.4194(24) $\AA$ and O-Ca-O = 87.00(8) and 93.00($8^o$) are found per unit cell. One $Ca^{2+}$ ion per unit cell is located at site II’ in the sodalite cavity and extends 0.50 $\AA$ into the sodalite cavity from its 3-oxygen plane (Ca-O = 2.324(13) $\AA$ and O-Ca-O = 115.5(10)o). The remaining twenty $Ca^{2+}$ ions are found at two nonequivalent sites II (in the supercages) with occupancies of 10 and 10 ions, respectively. Each of these $Ca^{2+}$ ions coordinates to three framework oxygens, either at 2.283(3) or 2.333(5) $\AA$, respectively, and extends either 0.24 or 0.54 $\AA$, respectively, into the supercage from the three oxygens to which it is bound. In this crystal, site I is the most populated; sites II’ and II are only sparsely occupied.$Ca^{2+}$+ appears to fit the octahedral site I best. No cations are found at sites III or III’, which are clearly less favorable for $Ca^{2+}$ ions in dehydrated zeolite Y.

Surface Properties of Color Concrete Using Acid Stained Agent (표면 착색용 산화제를 사용한 컬러 콘크리트의 표면 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Park, Hyo-Jin
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.265-272
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    • 2011
  • Even though concrete is the most important material for building structures, its intrinsic gray color degrades urban esthetics. In order to improve this problem, coloring methods of mixing pigment in concrete batch and painting the surface of concrete surface have been tried. However, applications of the coloring methods in construction field are difficult due to high cost and low durability. Recently, acid stain agent is emerging as a new coloring method for concrete. It is able to apply a remarkably thin colored layer on a concrete surface from chemical reaction between acid and alkaline solutions. This study has examined the changes and variations of the surface layer of mortar specimen from chemical reaction of acid stained agents. The colors were changed into natural irregular stains according to aging. After the staining, no shape change was found from visible inspections. Microstructure of the colored surface applied with acid stained agent was much rougher than that of original mortar. When the colored layer was compared to original surface, crystals of hydrate such as $Ca(OH)_2$ and C-S-H gel were observed. Surface hardness was same or slightly higher in the colored layer. The value of pH was reduced by approximately 10%, weight contents of elements such as Ca, Si, and Al were low. In the chemical composition of the colored layer, the non-cement based elements of Mn, Cr, and Cu increased. Also, Fe and alkali elements of K and Na increased.

Decomposition of Triclosan onto E-beam Process using a Design of Experiment(DOE) (전자빔을 이용한 triclosan 제거에 있어서 실험계획법의 이용)

  • Jang, Tae-Bum;Lee, Si-Jin
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.6
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    • pp.51-57
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    • 2012
  • This study investigated on the photolytic degradation of Triclosan by E-beam process. The optimization of process was investigated during a series of batch experiments by design of experiments(DOEs). The DOE was one of the statistical application that was used for designed the response surface to determine the effects of each parameters. The responses were applied as removal rate of Triclosan(%, $Y_1$) and TOC removal rate(%, $Y_2$). Two independent variables were concentration of Triclosan and irradiation intensity that were designed as "$x_1$" and irradiation intensity was designed as "$x_2$". The regression equation in coded parameter between the Triclosan removal efficiencies(%) and TOC removal efficiencies(%) was $Y_1=63-12.4335x_1+15.1835x_2+5.8125x{_1}^2-5.6875x{_2}^2-0.75x_1x_2(R^2=95.1%,\;R^2(Adj)=91.7%)$ and $Y_2=46-8.8462x_1+11.7175x_2-0.75x{_1}^2-6.25x{_2}^2(R^2=98.7%,\;R^2(Adj)=97.7%)$, respectively. The model predictions agreed well with the experimentally observed results $R^2$ and $R^2(Adj)$ over 90% within both of $Y_1$ and $Y_2$. This result shows that the regression model express well about the effects of parameters on E-beam process and the statistical method was successfully applied.

Production of Poly(Hydroxybutyric-Co-Hydroxyvaleric) Acid by Pseudomonas sp. HJ (Pseudomonas sp. HJ에 의한 Poly(Hydroxybutyric-Co-Hydroxyvaleric) Acid의 생산)

  • 손홍주;민관필이상준
    • KSBB Journal
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    • v.10 no.4
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    • pp.349-356
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    • 1995
  • To produce PHA(polyhydroxyalkanoic acid) from microbr, dozens of microorganism have been screened from sewage sludge. Selected a strain HJ out of 50 strains of PHA producing bacteria has a capability of accumulating large amounts of PHB/HV copolymer when grown in batch culture with a single carbon source (glucose) that was not generally considered as precursor of hydroxyvalerate monomer unit. The strain HJ was identified as the genus Pseudomonas with respect to morphological, cultural, and biochemical characteristics. The optimal temperature and pH for cell growth were $37^{\circ}C$ and 7.0. The optimal medium compositions for cell growth were glucose 1% as a carbon source, (NH4) 2SO4 0.2% as a nitrogen source, K2HPO4 0.3%, and KH2PO4 0.45%. TO investigate she optimal condition for PHA production two-step cultivation method was employed. PHA production was inducted by deficiency of NH4+, SO4-2, Mg+2. Besides carbon source, deficiency of all nutrients stimulated PHA productivity but deficiency of NH4+ stimulated the most HV monomer content. The highest PHA production was C/N molar ratio 95.2. Pseudomonas sp. HJ was also able to pyoduc PHB/HV copolymer when cultivated on alkane, alkanoate, alcohol as carbon sources. The contents of PHA and she proportions of hydroxyvalerate monomer units varied depending on the carbon sources. Especially Pseudomonas sp. HJ was able to incorporate hydroxyvalerate into PHB/HV to level as high as from 49 to 74 mol% when grown in a medium containing hexadecane and propionate. The purified PHA was identified PHB/HV copolymer by HNMR analysis.

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The Effects of Metathesis for Concentrating the Tocopherols from Soybean and Rice-bran Scum Oils (대두유 및 미강유의 찌꺼기유로부터 토코페롤의 농축을 위한 메타세시스 반응효과)

  • 안호근;문일식
    • KSBB Journal
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    • v.10 no.4
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    • pp.449-454
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    • 1995
  • The effects of metathesis for concentrating the tocopherols from soybean and rice-bran scum oils were studied by using the batch reactor under helium atmosphere. The contents of tocopherols in the scum oils decreased consticuously when heated under air atmosphere or when kept in hexane solution above 5 days even at room temperature. The sterols in the scum oils were removed by the mixed solvent method. Metathesis of the sterol-removed scum oils in hexane was performed over Re2O7/Al2O3 and WO3/Al2O3 catalysts, and the concentrate was obtained by distillation in vacuum at $190^{\circ}C$. The effect of metathesis was evaluated as relative ratio of ${\alpha}$-tocopherol in the concentrate to that in scum oil. The maximum ratio for both scum oils was obtained on 12.8%(w/w)$Re_2O_7/Al2O_3$ catalyst which formed effectively the active sites for metathesis by the reaction between the added tetramethyltin and $Re_2O_7$ on the surface of the catalyst. The optimum amount of the catalyst was 0.5g pre l0g scum oil, and the optimum reaction temperature was $25^{\circ}C$ for both scum oils. The metathesis was more effective in rice-bran scum oil than in soybean scum oil. These facts indicated that the tocopherols in the scum oils can be highly concentrated by applying metathesis.

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