• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.459-462
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• 2011

In the present work, catalytic activity of basic alumina in water has been demonstrated for the synthesis of poly functionalized pyridines. This strategy has some remarkable advantages, such as use of heterogeneous catalyst in aqueous media, reusability of catalyst and scalable approach.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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• pp.215-232
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• 2000

The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

• 한국세라믹학회지
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• 제16권1호
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• pp.21-25
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• 1979

This study is proposed to find an appropriate body for high expansion glass ceramics of ${Na}_2O-{Al}_2O_3-{SiO}_2$ system. The compositions of basic glasses are selected to be melted easily and to be crystallized into nepheline with various contents of alumina. The crystallization temperatures of basic glasses are determined by DTA. The crystals in the basic glasses developed by heat treatment are investigated by X-ray diffraction analysis, and thermal properties such as expansion coefficients, fusion points are measured. We find, therefore,that crystallization temperatures, crystal phases and thermal properties are affected by content of alumina.

• 한국세라믹학회지
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• 제52권6호
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• pp.403-409
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• 2015

Porous alumina ceramics are involved in many industrial applications due to the exceptional properties of these products. This study addresses the preparation of porous alumina ceramics using hollow microspheres as a pore-forming agent and slip casting as a green-body-forming technique. A uniform distribution of pores is a basic requirement of a porous material. This study investigates three different slurry systems, i.e., as-prepared alumina slurry, alumina slurry electrostatically dispersed by hydrochloric acid (HCl), and slurry dispersed by the commercial dispersant 'Darvan C-N'. At a low viscosity, the hollow microspheres in the slurry tend to float, which causes a non-uniform pore distribution. To avoid this phenomenon, the viscosity of the slurry was increased to the extent that the movement of hollow microspheres ceased in the slurry. As a result, a uniform pore distribution was achieved.

• 한국세라믹학회지
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• 제15권2호
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• pp.89-97
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• 1978

The basic mechanism of adherence in sintered high purity alumina ceramic-to-metal bonding was studied. Emphasis was placed on flux composition, porosity of the fired ceramics, and metallizing mixtures. The study was conducted on 95 and 99.5% alumina, using molydbenum-manganese, molybdenum-manganese-silicon dioxide metallizing compositions. Metallizing was performed in wet hydrogen (dew point, ＋17$^{\circ}C$) at 145$0^{\circ}C$ for 45min. This experiment indicated that adhernece mechanism of ultra high purity alumina ceramic was attributed to formation of $MnAl_2O_$4, and in the case of 95% alumina containing glass, the migration of glass from the interface into the void of the metal coating was the main role to the adhrence. It showed also that greater the bond-strength was resulted as porosity was increased.

• Elastomers and Composites
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• 제33권3호
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• pp.201-209
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• 1998

고무배합물의 충진제로 사용되는 알루미나 분말의 제조에 있어서 재래식 및 마이크로파 에너지원에 의하여 황산용액중의 카올린으로 부터 알루미나를 얻는다. 이때 카올린으로부터 알루미나 분말의 최대 추출율은 각각 재래식의 경우는 $80^{\circ}C$, 1M 황산, 180분에서 72.8%이고, 마이크로파 추출 공정의 경우는 $90^{\circ}C$, 1m 황산, 60분에서 $99\%$였다. 또한 추출된 시료는 TG/DTA, XRD, SEM, Atomic Emission Spectroscopy 및 BET법에 의하여 분석하였다..

• 한국지구과학회지
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• 제43권4호
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• pp.532-538
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• 2022

Under anoxic conditions, this study investigated removal of dissolved As(III) by Si and Al oxides including natural sand, chemically washed sand (silica), alumina, and activated alumina. Despite the similar surface area, natural sand showed greater extents of As(III) sorption than chemically washed sand. This was likely due to the high reactivity of Fe(oxyhydr)oxide impurities on the surface of natural sand. For both sands, As(III) sorption was the greatest at pH 7.1, in agreement with the weakly dissociating tendency of arsenous acid. Also, the least sorption was observed at pH 9.6. At basic pH, elevated silicate, which originated from the dissolution of silica in sands, would compete with As(III) for sorption. Due to the highest surface area, activated alumina was found to quantitatively immobilize the initially added As(III) (6.0×10^-7-2.0×10^-5 M). Alumina showed As(III) sorption compared to or greater than chemically washed sand, although the former had less than 6% of the surface of area the latter. The greater reactivity of alumina than chemically washed sand can be explained by using the shared charge of oxygen.

• Journal of Welding and Joining
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• 제14권6호
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• pp.93-100
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• 1996

Effect of a flux composition on weld metal toughness in submerged arc welding with 60kgf/$\textrm{mm}^2$ grade C-Mo type wires was investigated and interpreted in terms of weld metal microstructure and hardenability. Flux workability was also studied by characterizing a weld bead profile. Compared to other weld metals, .weld metal used alumina basic flux with nickel showed lowest oxygen content, highest hardenability and the most acicular ferrite. The highest impact toughness of that weld metal, however, was attributed to the tough matrix due to the nickel rather than to the larger amount of acicular ferrite. Manganese silicate flux had better workability than alumina basic flux, showing broader welding conditions resulting in a depth-to-width ratio of 0.5. The composition of oxides in the weld metal was dependent on the flux composition, showing MnO-SiO$_2$-TiO in manganese silicate flux and MnO-SiO$_2$-Al$_2$O$_3$-TiO in alumina basic flux. MnO-SiO$_2$composition in both oxides was similar to a tephroite.

• 대한치과보철학회:학술대회논문집
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• 대한치과보철학회 2004년도 추계학술대회
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• pp.44-44
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• 2004

• 대한심미치과학회지
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• 제9권1호
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• pp.82-90
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• 2000

치과 재료분야는 그 동안 많은 발전을 해왔음에도 불구하고 자연치아의 색조 재현 및, 인접 치와의 조화에 따른 심미성과 지대치와의 적합성 등에 많은 문제가 야기되어왔다. 기존 all ceramic 은 단관 제작 시 심미적인 요구가 다소 해결되었으나 bridge work 에 있어서는 그 강도 및, 작업의 효율성은 여전히 문제시되어 오고 있다. 최근 기존 Inceram의 단점을 보안한 Celay Inceram system은 spinell, alumina, zirconia Blanks를 이용하여 더욱더 기능적인 자연스러움으로 접근되어진다. 이에 그 system의 alumina blank를 이용한 bridge work 의 임상 증례를 살펴보기로 한다.