• Title/Summary/Keyword: Basic Metals

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Properties of inorganic components in the specified waste (지정폐기물 내 미량 무기물질의 특성)

  • Kwon, Young-Hyun;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.7
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    • pp.3327-3333
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    • 2011
  • The interest on the recovery of thermal energy using the industrial waste has been rising to solve the problems of continuous increase of waste generation and the depletion of the fossil fuel recently. To recovery from the waste among the new recyclable energies has been proved as the most favorable when the potential value of energy source is compared. The RDF made from the industrial waste has been approved as the most economical method. This research has analyzed the heavy metal components containing in the industrial waste. The concentration of Cl and S in the industrial waste generated in C-industrial complex are slightly high than that of the B- and A-industrial complex. The main components generated from A-industrial complex, B-industrial complex, and C-industrial complex are alumina-silicates, calcium alumina silicates, and the mixture of lime and calcium alumina silicate. These results could be used to reveal the origin of inorganic components in industrial waste and utilized as a basic data to improve the performance of the RDF as fuel.

Physico-chemical Characteristics and Utilization of Raw Materials for Mushroom Substrates (버섯 병재배 배지재료의 이화학성과 활용)

  • Cheong, Jong-Chun;Jhune, Chang-Sung;Lee, Chan-Jung;Oh, Jin-A
    • The Korean Journal of Mycology
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    • v.38 no.2
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    • pp.136-141
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    • 2010
  • To provide a basic information on the chemical concentrations of different raw materials used in mushroom cultivation, the raw materials were collected from 13 Flammulina velutipes, 14 Pleurotus eryngii, and 8 P. ostreatus farms and analyzed to calculate moisture contents, pH, total carbon(T-C), total nitrate(T-N), total phosphate(T-P) and 13 different cations. In our results, the C : N ratios of cotton seed meal, beet pulp, and corn-cob were 6~17, 12~29 and 56~127, respectively. Depending on the companies which process these materials, the range of C:N ratio of soybean curd residue was approximately either 8~9 or 14~17 with wider range of C : N ratio of the raw materials imported from other countries without the detection of heavy metals. In this study, the formula was provided to calculate the composition of mixed media for mushroom cultivation based on the ingredient chart of different raw materials.

Melting of PCB scrap for the Extraction of Metallic Components (PCB스크랩으로부터 유가금속성분 회수를 위한 용융처리)

  • Kwon Eui-Hyuk;Jang Sung-Hwan;Han Jeong-Whan;Kim Byung-Su;Jeong Jin-Ki;Lee Jae-Chun
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.31-36
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    • 2005
  • It is well known that PCB (Printed Circuit Board) is a complex mixture of various metals mixed with various types of plastics and ceramics. In this study, high temperature pyre-metallurgical process was investigated to extract valuable metallic components from the PCB scrap. For this purpose, PCB scrap was shredded and oxidized to remove plastic materials, and then, quantitative analyses were made. After the oxidation of the PCB scrap, $30.6wt\%SiO_2,\;19.3wt\%Al_2O_3\;and\;14wt{\%}CaO$ were analyzed as major oxides, and thereafter, a typical composition of $32wt\%SiO_2-20wt\%Al_2O_3-38wt{\%}CaO-10wt\%MgO$ was chosen as a basic slag system for the separation of metallic components. Moreover a size effect of crushed PCB scrap was also investigated. During experiments a high frequency induction furnace was used to melt and separate metallic components. As a result, it was found that the size of oxidized PCB scrap was needed to be less 0.9 m to make a homogeneous liquid slag and to recycle metallic components over $95\%$.

Fabrication of Ferroelectric BaTiO3Thin Film on Ti Substrate and Formation of Calcium Phosphate in Eagle’s MEM Solution (티타늄 기판 위에 강유전성 BaTiO3박막 형성과 분극처리에 의한 Eagle’s MEM 용액에서의 Calcium Phosphate 생성)

  • Lee, Yong-Ryeol;Jeong, Young-Hwa;Hwang, Kyu-Seog;Song, Ho-Jun;Park, Yeong-Joon
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.560-567
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    • 2002
  • Titanium (Ti) is a bioinert material and has lower elastic coefficient and better strength/volume property than other metals. Ferroelectric materials show alignment of positive and negative charges by poling treatment. This study was purposed to develop a new implant system by combining the advantages of Ti and ferroelectric property of $BaTiO_3$ (BTO). It was performed with the assumption that the $Ca^{2+ }$ ions would be easily attracted on negatively charged surface and the attracted cation might behave as nuclei for bone-like crystal growth in biological solutions. A ferroelectric BTO thin film on Ti was fabricated and the effect of poling treatment on the improvement of calcium phosphate (Ca-P) formation in biological solutions was evaluated. After immersion in Eagle’s minimum essential media (MEM) solution, NaCl was formed on Ti, and Ca-P layer containing NaCl was formed on Ti-O. Weak and sparse Ca-P layers were formed on BTO, while thick, homogeneous, and dense Ca-P layer was formed on negatively polarized BTO (N-BTO), which was confirmed by FE-SEM and EDX. In summary, these results demonstrate that poling the ferroelectric BTO surface negatively is effective for the formation of Ca-P layer in MEM solution, and that N-BTO coating on Ti could be used as a possible alternative method for enhancing the osseointegration of the implants.

Leaching Behaviour of vanadium from Orimulsion ash (오리멀젼회로부터 바나듐 침출특성에 관한 연구)

  • Park Kyung-Ho;Yoon Seung-Han;Nam Chul-Woo;Choi Yeung-Ki;Yoon Oh-Seub
    • Resources Recycling
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    • v.13 no.4
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    • pp.32-38
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    • 2004
  • Recently, Orimulsion (a bitumen-in emulsion) has received increasing attention as an alternative fuel. Orimulsion combusion produces an ash rich in V, Ni and Mg which are processed to recover metals. As a basic study to recover V from Orimulsion ash, physico-chemcial properties and leaching behaviours were investigated. Orimulsion ash was fine size grains ($d_{50}$ 5.9 $\mu\textrm{m}$) with 16% V, 4 % Ni and 9% S. Vanadium was easily leached in water because Orimulsion ash was mainly constituted of metal sulfates. However, the increase of leaching temperature decreased the extraction percentage of vanadium because of hydrolysis of V(V) to vanadium pentoxide. The addition of sulfuric acid could increase the leaching percentage vanadium. In case of alkaline leaching for selective recovery of vanadium, the oxidzing agent such as $H_2$$O_2$ is required to improve the leaching per-centage

Chemical Composition and Heavy Metal Contents in Commercial Liquid Pig Manures (국내유통 돈분액비의 화학성 및 중금속 함량)

  • Lee, Ji-Ho;Go, Woo-Ri;Kunhikrishnan, Anitha;Yoo, Ji-Hyock;Kim, Ji-Young;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1085-1088
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    • 2011
  • Heavy metal concentration as well as chemical composition were surveyed in commercial liquid pig manure to provide the basic information for mitigation research of hazardous material to agro-product. Seventy-five samples of liquid pig manure were collected and analyzed from 2009 to 2010 nationwide. Average contents of T-N, $P_2O_5$, and $K_2O$ were 0.29%, 0.08%, and 0.11%, respectively. The contents of heavy metals ranged from 0.001~0.083 for As, 0.001~0.108 for Cd, 0.002~0.495 for Cr, 0.07~47.8 for Cu, ND~0.005 for Hg, 0.035~1.033 for Ni, ND~0.291 for Pb, and $0.75{\sim}342.4mg\;L^{-1}$ for Zn, respectively. It was noted that among 75 samples, only four samples exceeded the Zn guideline ($130mg\;L^{-1}$) of liquid fertilizer derived from livestock manure but others were not exceeded the regulation.

A Research Trend on Diaphragm Membranes Alkaline Water Electrolysis System (알칼리 수전해용 격리막 기술 연구동향)

  • Im, Kwang Seop;Son, Tae Yang;Jeong, Ha Neul;Kwon, Dong Jun;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.2
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    • pp.133-144
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    • 2021
  • Alkaline water electrolysis system is the oldest technology among various hydrogen production processes to produce green hydrogen with the least amount of greenhouse gas generated. Alkaline water electrolysis (AWE) system is used in alkaline atmosphere condition. In comparison to polymer electrolyte membrane water electrolysis (PEMWE), this system can utilize stable transition metals such as nickel, cobalt, and silver, as electrode catalysts. AWE is relatively inexpensive, and can easily be scaled up to large scale. The system is a mature technology, as it has been in operation since the beginning of the 20th century in MW-scale for hydrogen generation, and there are currently more than 20 commercial manufacturers. In this review, the basic principles of AWE, along with catalysts, electrodes, and diaphragm membranes, are summarized. Particularly, the research and development trends of the diaphragm membrane unit, which is the core component of an AWE, are discussed in detail.

Effects of green tea leaf, lotus leaf, and kimchi powders on quality characteristics of chicken liver sausages

  • Choe, Juhui;Kim, Gye-Woong;Kim, Hack-Youn
    • Journal of Animal Science and Technology
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    • v.61 no.1
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    • pp.28-34
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    • 2019
  • Liver sausage is flavorful and highly nutritious. However, liver has a relatively short shelf life due to acceleration of oxidation in the presence of endogenous enzymes and metals. Powders derived from natural sources, including plants or fruits, are applied to meat products for inhibiting oxidation without adverse effects on their quality. Hence, this study investigated the effects of natural powders derived from green tea leaf (GTL), lotus leaf (LL), and kimchi (KC) on the quality and change in lipid oxidation and freshness of chicken liver sausages during two weeks of storage. Chicken liver sausages were manufactured with chicken breast (70%) and liver (20%), pork back fat (5%), iced water (5%), various additives, and GTL, LL, and KC [0 (control) or 1%]. They were processed in three batches. For determination of the quality characteristics of chicken liver sausages with various plant powders, pH, color, and texture properties were assessed. In addition, lipid oxidation and freshness using thiobarbituric acid reactive substances (TBARS) and total volatile basic nitrogen (TVBN) were analyzed at day 0 and week 2 of refrigerated storage. Higher values were obtained for pH and cooking yield in sausage samples with LL and KC powders than in samples with the other treatments. For a* values, the sausage samples with KC showed similar (p > 0.05) values, whilst others had significantly lower values than the control. The addition of the three powders to sausage samples induced an increase (p < 0.05) in hardness, gumminess, and chewiness. The addition of plant powders did not influence TBARS and TVBN of sausage samples at the initial stage. However, after two weeks of storage, significantly lower TBARS and TVBN values were observed, and the sausage with KC (p < 0.05) showed the lowest values of both TBARS and TVBN. The results showed the potential ability of the three powders to improve the quality and inhibit lipid oxidation in liver sausages. Particularly, the addition of KC did not adversely affect the $a^*$ values of sausage samples. The effects on sensory properties and inhibition mechanisms of GTL, LL, and KC in meat products should be further studied.

Experimental and Numerical Study on the Structural Stiffness of Composite Rotor Blade (복합재 로터 블레이드의 구조 강성도에 대한 실험적/수치적 연구)

  • Jeon, Hyeon-Kyu;Jeon, Min-Hyeok;Kang, Min-Song;Kim, In-Gul;Park, Jae-Sang;Seok, Jin-Young
    • Composites Research
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    • v.32 no.4
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    • pp.191-198
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    • 2019
  • The basic mechanical properties of helicopter rotor blade are important parameters for the analysis of helicopter performance. However, it is difficult to estimate these properties because the most of rotor blades consist of various materials such as composite materials and metals, etc. In this paper, the bending/torsional stiffness for composite rotor blade of unmanned helicopter were evaluated through experimental and analytical studies. In finite element analysis, the bending/torsional stiffness were evaluated through the relationship of load-displacement and element stiffness matrix. The evaluated stiffness from the measured strains and displacements in bending and torsional test agreed well with the derived results of FEA.

Effects of Scalp Management using SUKI on Heavy Metal Discharge (SUKI(silver tools)를 활용한 두피 관리가 중금속 배출에 미치는 영향)

  • Lee, Jun-Suk;Hong, Seong-Gyun
    • Journal of Convergence for Information Technology
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    • v.10 no.12
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    • pp.208-215
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    • 2020
  • The purpose of this study was to access the effects of detoxification of hair by SUKI(silver tools). The subjects of this study participated 26 persons(EG 13 and CG 13), Experimental group was performed SUKI programs combined with scalp and hair for two times per week, during 8 weeks. The results was of comparison of variations in each groups showed that there was a significant difference(6items) in the experimental group(p<.05). But 2items(Pb, Cs) was not showed it. Among the hazardous heavy metals in research, Al, Ba and Hg showed the greatest reduction rate of difference. Thus, the using of the SUKI tool has been shown to affect some heavy metal emissions (p<.05). In conclusion, it is thought that it can be used as basic data for heavy metal discharge of scalp through continuous research in the future.