• Title/Summary/Keyword: Base Rate

Search Result 2,266, Processing Time 0.027 seconds

A Study on Stress Corrosion Behaviors in Welded Zone of the API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG YOO-SIK;KIM YUONG-DAI
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
    • /
    • 2004.05a
    • /
    • pp.401-407
    • /
    • 2004
  • This study is on the constant-current stress corrosion test related to the load stress in welded zone and non-welded zone of high tensile strength steel for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed global corrosion and narrow pitting, and the pitting was increased by increasing the load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel for natural gas transmission specimens was decreased suddenly, and the average relative electrode potential was higher and the average relative current was lower in welded zone than base metal. and the average relative electrode potential was decreased by increasing the load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone than base metal, and the corrosion rate was decreased by increasing the load stress.

  • PDF

On Corrosion Behaviors in Welded Zone of API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG Yu-SIK;KIM YOUNG-DAI
    • Journal of Ocean Engineering and Technology
    • /
    • v.18 no.5
    • /
    • pp.50-56
    • /
    • 2004
  • This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

Kinetics and Mechanism of Nucleophilic Addition of Sodium Thiophenoxide to ${\alpha}-Phenyl-N-iso-Propylnitrone$ derivatives ((${\alpha}-Phenyl-N-iso-propylnitrone$유도체에 대한 Sodium Thiophenoxide의 친핵성 첨가반응 메카니즘과 그의 반응 속도론적 연구)

  • Lee, Kwang-Il;Kim, Young-Ju;Kqak, Chun-Geun;Jang, Buyng-Man;Lee, Ki-Chang
    • Journal of the Korean Applied Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.93-98
    • /
    • 1995
  • The rate constant of Nucleophilic addition of sodium thiophenoxide to nitrone were determined by UV Spectrophotometry and a rate equation which can be applied over wide pH range was obtained. Base on the rate equation, general base effect, substituent effect and final product, plausible mechanism of addition reaction have been proposed. Blow pH 3.0, the reaction was initiated of thiophenol, and in the range of pH $3.0{\sim}10.0$, proceeded by the competitive addition of thiophenol and thiophenoxide anion. Above the pH 10.0, the reaction proceeded through the addition of a thiophenoxide anion.

A Study on the Kinetics and Mechanism of Nucleophilic Addition of 1-Propanethiol to ${\alpha}-Phenyl-N-iso-propylnitrone$ Derivatives. ((${\alpha}-Phenyl-N-iso-propylnitrone$유도체에 대한 1-Propanethiol의 친핵성 첨가반응에 관한 연구)

  • Lee, Kwang-Il;Kwak, Chun-Geun;Jang, Byung-Man;Kim, Young-Ju;Ji, Yun-Seup;Lee, Ki-Chang
    • Journal of the Korean Applied Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.85-92
    • /
    • 1995
  • The rate constant of the nucleophilic addition of 1-propanethiol to ${\alpha}-phenyl-N-iso-propylnitrone$ derivatives were determined at various pH and a rate equation which can be applied over wide pH range is obtained. Final product of the addition reaction was ${\alpha}-thiopropyl-p-phenylbenzylideneamine$. Base on the rate equation, general base effect, substituent effect and final product, plausible mechanism of addition reaction have been proposed. Below pH 3.0, the reaction was initiated by the addition of 1-propanthiol, and in the range of pH 3.0-10.0, proceeded by the competitive addition of 1-propanethiol and propanethiolate. Above the pH 10.0, the reaction proceeded through the addition of propanethiolate.

Investment for Farm Land Development and Analysis of It's Effects on Rice Production in Korea - New Farm Land Development Policy with Respect to UR Problems - (한국(韓國)의 농지개발투자(農地開發投資)가 미곡생산(米穀生産)에 미친 효과분석(效果分析) - UR문제(問題)에 관(關)한 신농지개발정책(新農地開發政策) -)

  • Lim, Jae Hwan
    • Korean Journal of Agricultural Science
    • /
    • v.21 no.1
    • /
    • pp.67-80
    • /
    • 1994
  • Farm land is considered the most important production factor in farm production. Land is not only one of the most scarce resource but also the size of land holding is the key factor in determining the size of farm income in Korea. To increase farm productivity by accepting bio-chemical and mechnical technology, the qualitative improvement of farm land through land consolidation and on-farm development have been carried out by the Korean government. Land consolidation with water resource development makes possible the high-tech-capital intensive farming, internal expansion of farm land and hightening the rate of land intensity in connection with UR problems. This paper contained the present status of farm land base development, allocation of investment by types of farm land development and the econome-trical analysis on the effects of the investment on rice productivity during the past 27 years since 1965. The rate of irrigated paddy area had been increased from 42% in 1965 to 74% in 1991. Land consolidated area out of the total paddy area had been achieved 44.9% and the improved rate of poor drained paddy area was shown 43.5% in 1991. To carry out the above farm land base development projects, the government had procured financial budgets consisting of the G't subsidy, long term loan, foreign loan, the provincial G't subsidy, WFP counter fund and farmer's burden.

  • PDF

A Study on Thermal Performance of Microchannel Waterblock for Cooling of CPU in Desktop (컴퓨터 CPU 냉각용 미세채널 워터블록의 열성능에 관한 연구)

  • Choi, Mi-Jin;Kwon, Oh-Kyung;Cha, Dong-An;Yun, Jae-Ho
    • Proceedings of the SAREK Conference
    • /
    • 2007.11a
    • /
    • pp.264-269
    • /
    • 2007
  • The microchannel waterblock has a good capability in the cooling of electronic devices. The object of this paper is to study on thermal performance of microchannel water block for cooling of CPU in desktop. The effects of header shape, liquid flow rate, and inlet temperature on the thermal performances of microchannel waterblock are investigated experimentally. Three types of waterblock with different header shape are manufactured from the micro milling and brazing processing. The experiments are conducted using water, over a liquid flow rate ranging from 0.7 to 2.0 LPM and inlet temperature ranging from 20 to $35^{\circ}C$. Waterblocks are attached both horizontally and vertically on the test section to anticipate a performance of waterblock under the actual state in computer. The base temperature and thermal resistance decrease with increasing of liquid flow rate. It was found that the sample #1 was appropriate for the prototype of liquid cooling system.

  • PDF

Mechanism of the Hydrolysis of 2-Phenyl-4H,5H,6H-3-methyl-3-thiazinium Perchlorate Derivatives

  • 김태린;이소영;변상용;김주창;한만소
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.10
    • /
    • pp.1213-1217
    • /
    • 1999
  • Hydrolysis reactions of 2-phenyl-4H,5H,6H-3-methyl-3-thiazinium perchlorate (PTP) and its derivatives at various pH have been investigated kinetically. The hydrolysis is quantitative, producing N-3-mercaptopropyl-N-methylbenzamide as the only product in the all pH ranges. The observed rate of hydrolysis of PTP was always of the first-order. For hydrolysis from PTP, Hammett ρvalues were 0.53, 0.84 and 1.13 for pH 5.0, 8.0, and 10.0, respectively. Bronsted βvalue was 0.53 for general base catalysis. This reaction is catalyzed by general w acetate concentration. However, as the amount of base becomes larger, the rate of hydrolysis reaction approaches the limiting values. The plot of log k vs. pH shows that the rate constants (kt) are two different regions in the profile; one part is directly proportional to hydroxide ion concentration and the other is not. On the bases of these result, the plausible hydrolysis mechanism and a reaction equation were proposed: Below pH 4.5, the hydrolysis was initiated by the addition of water to α-carbon. Above pH 9.0, the hydrolysis was proceeded by the addition of hydroxide ion to α-carbon. However, in the range of pH 4.5-8.0, these two reactions occured competitively.

Optimization of chemical cleaning of discarded reverse osmosis membranes for reuse

  • Jung, Minsu;Yaqub, Muhammad;Lee, Wontae
    • Membrane and Water Treatment
    • /
    • v.12 no.1
    • /
    • pp.1-9
    • /
    • 2021
  • This study optimized the chemical cleaning process of discarded RO membranes for reuse in less demanding separation processes. The effect of physicochemical parameters, including the temperature, cleaning time, pH of the cleaning solution, and addition of additives, on the cleaning process was investigated. The membrane performance was evaluated by testing the flux recovery rate and salt rejection before and after the cleaning process. High temperatures (45-50 ℃) resulted in a better flux recovery rate of 71% with more than 80% salt rejection. Equal time for acid and base cleaning 3-3 h presented a 72.43% flux recovery rate with salt rejection above 85%. During acid and base cleaning, the best results were achieved at pH values of 3.0 and 12.0, respectively. Moreover, 0.05% concentration of ethylenediaminetetraacetic acid presented 72.3% flux recovery, while 69.2% flux was achieved using sodium dodecyl sulfate with a concentration of 0.5%; both showed >80% salt rejection, indicating no damage to the active layer of the membrane. Conversely, 0.5% concentration of sodium percarbonate showed 83.1% flux recovery and 0.005% concentration of sodium hypochlorite presented 85.2% flux recovery, while a high concentration of these chemicals resulted in oxidation of the membrane that caused a reduction in salt rejection.

Analysis of the Relationship between a Batter's Performance and Discomfort Index using Big Data: focusing on the Number of Pitches and On Base Percentage (빅데이터를 활용한 타자의 출루 관련 경기력과 불쾌지수의 관계 분석 : 투구 수 유도와 출루율을 중심으로)

  • Kim, Semin;You, Kangsoo
    • Journal of Industrial Convergence
    • /
    • v.18 no.4
    • /
    • pp.61-66
    • /
    • 2020
  • Recently, attempts have been made to use data to operate games, seasons, and teams in professional baseball. Therefore, in this study, we collected baseball game records and analyzed the relationship between on-base rate and pitching count induction, and this was defined as the third record for non-game factors such as discomfort index, which includes the weather application data. When the discomfort index was over 75, the pitcher's induction of pitching was high, and when the discomfort index was less than 69.9, the on-base rate was high, but when the discomfort index was 70 or more and less than 75, the batter's on-base performance was the lowest. Through the results of the study, it could be inferred that the discomfort index, the batter's on-base rate, and the number of induction pitches are related, and that it is highly likely to be related to the pitcher's performance. Through this study, we could see the possibility of defining a cumulative/ratio record defined as the primary record and a saver metric defined as the secondary record, and a third, tertiary record linking data outside the game.

Effects of Numerical Formats and Frequency ranges on Judgment of Risk and Inference in the Bayesian InferenceTask (숫자양식과 빈도범위가 베이스 추론 과제에서 위험판단과 추론에 미치는 영향)

  • Lee, Hyun-Ju;Lee, Young-Ai
    • Korean Journal of Cognitive Science
    • /
    • v.20 no.3
    • /
    • pp.335-355
    • /
    • 2009
  • We examined risk judgment and the accuracy of inference based on two kinds of probabilities in a Bayesian inference task: the death probability from a disease (base rates) and the probability of having a disease with positive results in the screening test (posterior probabilities). Risk information were presented in either a probability or a frequency format. In Study 1, we found a numerical format effect for both base rate and posterior probability. Participants rated information as riskier and inferred more accurately in the frequency condition than in the probability condition for both base rate and posterior probability. However, there was no frequency range effect, which suggested that the ranges of frequency format did not influence risk ratings. In order to find out how the analytic thought system influences risk ratings, we compared the ratings of a computation condition and those of a no-computation condition and still found the numerical format effect in computation condition. In Study 2, we examined the numerical format effect and frequency range effect in a high and a low probability condition and found the numerical format effect at each probability level. This result suggests that people feel riskier in the frequency format than in the probability format regardless of the base rates and the posterior probability. We also found a frequency range effect only for the low base rate condition. Our results were discussed in terms of the dual process theories.

  • PDF