• Title/Summary/Keyword: Basalts

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Geophysical well logs in basaltic area, Jeju Island (제주 현무암 지역의 용암분출에 따른 물리검층 반응의 특성 고찰)

  • Hwang Seho;Shim Jehyun;Park Inhwa;Choi Sun Young;Park Ki Hwa;Koh Gi Won
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.09a
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    • pp.55-71
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    • 2005
  • Jeju Island is mainly composed of basaltic lava flows and subordinate amounts of volcaniclastic sedimentary rocks. Jeju Province operates the monitoring wells for seawater intrusion problems around Jeju Island to evaluate of groundwater resources in coastal area. Various surveys and monitoring have been performed in boreholes, and also conventional geophysical well loggings conducted to identify basalt sequences and assess seawater intrusion problems. Various conventional geophysical well logs, including radioactive logs, electrical log, caliper log, and temperature and conductivity log and heat-pulse flowmeter log were obtained in 29 boreholes. The results of geophysical well loggings for saturated rocks are interesting and consistent. Natural gamma logs are useful in basalt sequences to sedimentary interbeds, unconsolidated U formation, and seoguipo formation with higher natural gamma log regardless of saturated or unsaturated basalts. Neutron logs are very effective to discriminate among individual lava flows, flow breaks, and sedimentary interbeds in saturated formation. In hyalocastite, porosity is high and resistivity is low, and we think that hyalocastite is a major pathway of fluid flow. In trachybasalt, porosity has a wide range and resistivity is high. In sedimentary interbeds, unconsolidated U formation and seoguipo formation, porosity is high and resistivity is low. The temperature logs in eastern area in Jeju are useful to interpret the hydrogeological unit and evaluate seawater intrusion in Suan area.

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Study on the Geochemical Characteristics of the Mesozoic Volcanic Rocks in Da Hinggan Ling Area, Northeast China (중국 북동부 대흥안령 지역 중생대 화산암류에 대한 암석화학적 특성 연구)

  • Yun, Sung-Hyo;Won, Chong-Kwan;Lee, Moon-Won;Lin, Qiang
    • Journal of the Korean earth science society
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    • v.21 no.1
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    • pp.67-80
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    • 2000
  • We studied petrological and geochemical characteristics of the Mesozoic volcanic rocks in the Da Hinggan Ling area northeast China, and discussed tectonic settings and origin of the Mesozoic volcanic rocks in northeast Asia. Volcanic rocks in Da Hinggan Ling area are composed of alkaline to subalkaline basalt-basaltic andesite-andesite-dacite-rhyolite, showing typical BAR(basalt-andesite-rhyolite) association. However, most of the volcanic rocks are basaltic and rhyolitic in composition, and andesitic rocks are relatively rare, which shows bimodal characteristics. Rb, Ba, Th and other incompatible element contents in the volcanic rocks are enriched, but the contents decrease with increasing the compatibility. REEs are fractionated and REE patterns of volcanic rocks are characterized by a high LILE/HFSE. On the tectonomagmatic discriminant diagram of Hf-Th-Nb, they fall into the fields for subduction-related destructive plate margin basalts and its differentiates. We suggest that the tectonomagmatic setting of Da Hinggan Ling area was located at the continental margin arc related with subduction environment during the Mesozoic time or may be derived from mantle plume contaminated geochemically from subducting slabs, although it is, at present within the Asia continent.

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Characteristics of Vanadium Leaching from Basaltic Soils of Jeju Island, Korea (제주도 현무암 기원 토양의 바나듐 용출 특성)

  • Hyun, Ik-Hyun;Yang, Cheol-Shin;Yun, Seong-Taek;Kim, Horim;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.25 no.11
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    • pp.1541-1554
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    • 2016
  • To understand the characteristics of vanadium leaching from soils formed by the weathering of basalts, paleo soil at Gosan, Jeju Island, Korea, and several present-day soils from neighboring areas were collected. Leaching experiments were carried out by two approaches: 1) batch experiments under various geochemical conditions (redox potential (Eh) and pH) and 2) continuous leaching experiments under conditions similar to those of natural environments. From the batch experiments, leached vanadium concentrations were highest under alkaline (NaOH) conditions, with a maximum value of $2,870{\mu}g/L$, and were meaningful (maximum value, $114{\mu}g/L$) under oxidizing ($H_2O_2$) conditions, whereas concentrations under other conditions (acidic-HCl, $neutral-NaHCO_3$, and $reducing-Na_2S_2O_3$) were negligible. This indicated that the geochemical conditions, in which soil-water reactions occurred to form groundwater with high vanadium concentrations, were under alkaline-oxidizing conditions. From the continuous leaching experiments, the pH and leached vanadium concentrations of the solution were in the ranges of 5.45~5.58 and $6{\sim}9{\mu}g/L$, respectively, under $CO_2$ supersaturation conditions for the first 15 days, whereas values under $O_2$ aeration conditions after the next 15 days increased to 8.48~8.62 and $9.7{\sim}12.2{\mu}g/L$, respectively. Vanadium concentrations from the latter continuous leaching experiments were similar to the average concentration of groundwater in Jeju Island ($11.2{\mu}g/L$). Furthermore leached vanadium concentrations in continuous leaching experiments were highly correlated with pH and Al, Cr, Fe, Mn and Zn concentrations. The results of this study showed that 1) alkaline-oxidizing conditions of water-rock (soil) interactions were essential to form vanadium-rich groundwater and 2) volcanic soils can be a potential source of vanadium in Jeju Island groundwater.

Hydrous Minerals (Phlogopite and Amphibole) from Basaltic Rocks, Jeju Island: Evidences for Modal Metasomatism (제주도 현무암에 산출되는 함수광물(금운모와 각섬석): 모달교대작용의 증거)

  • Heo, Seo-Young;Yang, Kyoung-Hee;Jeong, Hoon-Young
    • The Journal of the Petrological Society of Korea
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    • v.21 no.1
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    • pp.13-30
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    • 2012
  • Phlogopite and kaersutite, showing distinctively different textural characteristics compared to the common phenocrysts, are observed in alkali basalt from Jeju Island. They occur as large crystals (2-10 mm) in host basalts, whereas fine-grained phlogopite and kaersutite occur in ultramafic mantle xenoliths and mafic gabbroic xenoliths, respectively, as an interstitial and microvein phases, or in corona textures (<1 mm). This textural characteristics of fine-grained grains clearly indicates secondary in origin. Phlogopite contains high $TiO_2$(4.1-6.9 wt%) and F(2.8-4.6 wt%) and relatively high mg#[=100Mg/(Mg+$Fe^t$) in mols, where $Fe^t$ is total iron](88-80), whereas kaersutite has high $TiO_2$(5.6-6.11 wt%) and much lower mg#s(68-64). Our textural observations and the geochemical character of these hydrous minerals suggest that they were unrelated to each other and mica formation happened early in the upper mantle before the mantle xenoliths had been trapped. In contrast, kaersutite formation has happened later, probably during the late stage of crystallization as intracrustal processes. The presence of phlogopite and kaersutitic amphibole is a direct evidence for K-, Ti-, F- and $H_2O$-bearing fluid/melt percolation in the lithosphere beneath Jeju Island, indicating that they are product of interaction between host rock/peridotite/fluid-melt. Thus, the upper mantle/lower crust beneath Jeju Island are metasomatized to various extents, characterized by a change in major metasomatic hydrous minerals from phlogopite to amphibole with decreasing depth.

Buffer Capacity of So Horizon Soils of Andisols from Jeju Island: Solubility Effect of Mineral Phases (제주도 Andisols Bo층 토양의 산성화에 대한 완충능력: 광물상 용해도 특성의 영향)

  • 이규호;송윤구;문지원;문희수
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.2
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    • pp.114-121
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    • 2002
  • Buffer capacities for two Bo horizon soils or Andisols developed from different parent materials have been investigated. The titration curves from column leaching experiment show that buffering occurred at pH 4.0 and 6.0. The buffer intensity or soil developed from pyroclastic materials (P-soil) is higher than that from basalts (B-soil). From batch test we have found that proto-imogolite and/or imogolite may control Al solubility as well as $Al(OH) _3$in the moderate acid condition. The buffer intensities ($\beta$) of P-soils were plotted on the theoretical buffering curve of $Al(OH)_3$, while $\beta$ of B-soils approached to that of proto-imogolite, which shows the solubility of short-range-order materials in P-soil control the buffer capacity. Buffering at pH 6.0 is thought to be the result of dissolution of some silicate clays and exchange reactions between $H^{+ }$and base-forming cations. Considering the amount of annual acid precipitation, aluminum solubility of Andisols, and the low BS (Base Saturation percentage), it can be predicted that prolonged acid precipitation will reduce the buffer capacity of soils and lead to soil acidification.

Petrological study on the intermediate to mafic lavas distributed in Janggi area (1): General geology and petrochemical characteristics (장기 지역에 분포하는 중성~염기성 용암에 관한 암석학적 연구(1): 일반 지질 및 암석화학적 특징)

  • 박주희;김춘식;김진섭;성종규;김인수;이준동;백인성
    • The Journal of the Petrological Society of Korea
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    • v.8 no.3
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    • pp.149-170
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    • 1999
  • The volcanic lavas in the Janggi area are plotted on basalt, basaltic andesite and andesite field (SiO$_2$; 48-61 wt.%) in the TAS diagram and belong to subalkaline series. Nineteen chenmical analyses of lavas show two distinct differentiation trends; tholeiitic and calc-alkaline. Calc-alkaline basaltic andesites composed of plagioclase and two-pyroxenes (cpx, opx) in their phenocrysts. Tholeiitics basaltic lavas can be classified into two sub-types. The one is porphyritic basalts composed of plagioclase, clinopyroxene and olivine phenocryst, and the other is aphyric basalt and more evolved lavas (aphyric basaltic andesite) with the same mineral phases. Incompatible elements and REE patterns show the enrichment of LILE and depletion of HFSE. This characteristics indicate that these lavas are evolved from the magmas related to subduction. Howeverm calc-alkaline basaltic andesite lavas show that slightly higher enrichment of LILE and the depletion of HFSE than those of tholeiitic basaltic lavas. On the tectonic discriminant diagram such as Ba/Th and La/Th ratios, calc-alkaline basaltic andesite lavas belong to orogenic medium to high-K suites, whereas tholeiitic basaltic lavas belong to medium-K suites and MORB. On the other diagram, such as La/Yb vs. Th/Yb, the volcanic lavas in the study area plotted in the field of oceanic arc basalt. Tholeiitic basaltic lavas are located in more prinitive environment than calc-alkaline andesitic lavas.

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Engineering Geological Characteristics of volcanic rocks of the Northwestern Cheju Island, Korea (제주도 북서부 지역 화산암체의 지질공학 특성)

  • 김영기;최옥곤
    • The Journal of Engineering Geology
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    • v.1 no.1
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    • pp.19-37
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    • 1991
  • The geology of the northwestern Cheju Island consist of Pleistocene to Holocene volcanic rocks which could be devided into basalt layers, the Sungsan Formation composed mainly of volcaniclastic debris exposed along the shoreline, and more than 30 cinder cones. Columnar joints and vesicles are dominant in the basalts of the Pyeosunri and the Sihungri basalt Formations. Volcaniclast and clay layers are intercalated in basaltic layers. When volcaniclast of the interlayers would be swept away by ground water and some caves of channel shape would be formaed. Overlying lavas cracked by columnar joints could be easily destroyed, collapsed and/or sunk. Geomechananical nature of the rocks such as strength may be controlled by the vesicularity(size, shape, and orientation of the vesicles) of the rocks. On the basis of vesicularity as a factor of strength, the effective strength ratio(Ke) could be calculated as Ke=0.3-0.72, in which the smaller Ke value reflects the lower in internal stress. In the studied area, the strength of the rocks tends to decrease as increasing in altitude of provenance of the rocks. The rocks in the area show relatively low values in angle of failure strength($\phi$) ranging from 10$^{\circ}$ to 30$^{\circ}$. In conclnsion, the rocks in question, majority of which the critical value exceeds 0.33, belong to the unstable rocks in the aspect of engineering geology.

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Origins of Clinopyroxenes in Alkaline Basalts from Jeju Island (제주도 알칼리 현무암에 산출되는 단사휘석의 기원)

  • Yang Kyounghee;Hwang Byoung-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.33-43
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    • 2005
  • Three types of clinopyroxenes in alkali basaltic rocks from Jeju Island can be identified on the basis of geochemical and textural data. Type Ⅰ is Cr-rich diopside in spinel peridotites from the upper mantle. Type Ⅱ is augite in fine-grained pyroxenites which are possibly either magmatic vein or metamorphic segregations owing to anatexis of the upper mantle. The augite of Type Ⅱ contains high Ca and Mg and relatively low Ti. Type Ⅲ is thought to be either cumulates or cognate phenocrysts and can be subdivided into Ⅲa, Ⅲb, and Ⅲc based on their occurrence mode. Clinopyroxenes of Type Ⅰ have the highest Mg# and Si and the lowest Ti, whereas those of Type Ⅲhave lower Mg#와 Si and higher Ti. These geochemical characteristics indicate that (Ti+Al/sup Ⅵ/)/Si and Al/sup Ⅵ//Al/sup Ⅵ/ increase from Type Ⅰ to Type Ⅲ. It is possibly interpreted that Type Ⅰ is of the highest pressure origin and Type Ⅲ of the lowest. Fractionation of high-pressure clinopyroxenes would result in evolved undersaturated alkali-enriched liquids, probably producing the alkali-enriched host basaltic rocks in Jeju Island.

보은 지역의 온천 변성염기성암에 대한 암석.지구화학적 연구

  • 권성택;이동호
    • The Journal of the Petrological Society of Korea
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    • v.1 no.2
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    • pp.104-123
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    • 1992
  • We present petrography, mineral chemistry of amphibole and plagioclase, and major and trace element chemistry for the Ogcheon metabasites occurring in the Poun and Mungyong areas to understand metamorphism, and to define chemical characteristics of parental rocks and their implication for tectonic environment. The Ogcheon metabasites often preserve relict igneous textures, although no primary phases are observed. They are mainly composed of amphibole (actinolite+hornblende)+plagioclase+epidote+chlorite+sphene+opaque oxides, indicating epidote amphibolite facies metamorphism. Coarse-grained amphiboles frequently have actinolitic composition in the core, and hornblende along the margin and cleavage, which can be interpreted either as miscibility gap or as result of polymetamorphism. Although presumed polymetamorphic events in the Ogcheon supergroup favor the latter possibility, further metamorphic studies are necessary to solve the problem. Amphibole and plagioclase chemistries suggest greenschist (epidote-amphibolite, if miscibility gap is present) to amphibolite facies metamorphism of possibly medium pressure. The major and trace element data of whole rocks indicate that the Ogcheon metabasites are transitional to tholeiitic basalts belonging to within-plate environment. Absence of evidences indicating deep sea environment suggests that the Ogcheon metabasites emplaced in an intra-cratonic, possibly rift environment which failed to proceed to an oceanic rift. Chemical variation of the metabasites toward a granitic pluton indicates K loss closer to the pluton, suggesting that caution should be taken when K is involved in a discussion.

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Composition and Evolution of Lithosphere Beneath the Jeju Island Region (I): A Review (제주도 암석권의 성분과 진화(I): 리뷰)

  • Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
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    • v.25 no.3
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    • pp.261-281
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    • 2016
  • Our knowledge of the lithosphere beneath the Korean Peninsula has been improved through petrologic and geochemical studies of upper mantle xenoliths hosted by Quaternary intraplate alkali basalts from Jeju Island. The xenoliths are mostly spinel lherzolites, accompanied by subordinate harzburgite and pyroxenites. The mantle xenoliths represent residual mantle material showing textural and geochemical evidence for at least a three-stage evolution, fractional partial melting, recrystallization, and metasomatism. Their composition primarily controlled by early fractional melt extraction and porphyroclastic and mylonitic fabrics formed in a shear-dominated environment, which was subsequently modified by residual slab-derived fluids (or melts). Modal metasomatic products occur as both anhydrous phase(orthopyroxene) and hydrous phase (phlogopite). Late-stage orthopyroxene is more common than phlogopite. However, chemical equilibrium is evident between the primary and secondary orthopyroxene, implying that the duration of post-metasomatic high temperatures enabled complete resetting/reequilibration of the mineral compositions. The metasomatic enrichment pre-dates the host Jeju Quaternary magmatism, and a genetic relationship with the host magmas is considered unlikely. Following enrichment in the peridotite protolith in the mantle wedge, the upper mantle beneath proto-Jeju Island was transformed from a subarc environment to an intraplate environment. The Jeju peridotites, representing old subarc fragments, were subsequently transported to the surface, incorporated into ascending Quaternary intraplate alkali basalt. The result of this study implies that long term material transfer in the transformation of geotectonic setting from a subarc to intraplate may have played a significant role in the evolution of lithospheric mantle, resulting in the enriched mantle domains, such as EM I or EM II in the lithospheric mantle beneath East Asia.