• 제목/요약/키워드: Backward curve

검색결과 33건 처리시간 0.017초

전산모델링을 통한 투과증발-촉진 에스테르화 반응에 대한 연구 (A Parametric Study of Pervaporation-facilitated Esterification)

  • 염충균;최승학;박유인;장성순
    • 멤브레인
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    • 제17권2호
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    • pp.146-160
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    • 2007
  • 본 연구에서는 불과 함께 에스테르화 반응물 및 생성물 일부가 친수성 막을 투과하는 비완전 분리를 고려한 투과증발-촉진 에스테르화 반응모델을 확립하였으며, 이 모사모델에 막 분리 효율 및 물 제거능력을 설명하는 항들을 포함시킴으로써 막 투과분리가 에스테르화 반응에 어떻게 영향을 끼치는가를 공정모사를 통해서 체계적으로 살펴보았다. 모사결과 막을 통한 비완전 분리 즉, 분리막을 통한 반응물의 투과는 역반응을 유발시켜 전체 반응을 지연시키며 그 결과 반응 전 환율은 투과증발 공정을 사용하지 않은 반응보다는 높으나 물에 대한 완전한 투과선택도를 갖는 투과증발 공정을 사용하는 반응시스템보다는 낮음을 알 수가 있었다. 반응 시스템 내에서 장착된 막을 통한 투과로 인한 반응부피의 변화가 반응 속도에 끼치는 영향을 살펴보았는데 반응 초기에는 반응물 농축효과가 지배적이어서 반응을 촉진시키며, 반응이 진행되어 생성물이 형성됨에 따라 생성물 농축효과가 점점 중요해지고 이 효과가 반응의 속도를 감소시킴을 알 수가 있었다. 에스테르화 반응공정 중에 투과증발공정을 적용하는 시점에 따라 반응속도, 반응 전화율이 달라짐을 공정모사를 통해 관찰하였다. 반응 모델 식으로부터 분리막의 성능과 반응 인자들 간의 상관관계는 확립하고 이 상관관계를 주어진 막 분리능력 하에서 반응 인자 조건 설정, 혹은 주어진 반응조건 하에서 막 분리능력을 설계하는 도구로 사용할 수 있다.

선행강우와 현장 모관흡수력을 고려한 산사태 해석 방법 제안 (Proposal of Design Method for Landslides Considering Antecedent Rainfall and In-situ Matric Suction)

  • 김정환;정상섬;김용민;이광우
    • 한국지반공학회논문집
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    • 제29권12호
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    • pp.11-24
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    • 2013
  • 본 연구에서는 전형적인 산사태 발생 메커니즘인 강우침투현상과 현장 모관흡수력을 고려한 산사태 해석 방법을 제시하였으며, 실제 산사태가 발생된 지역을 선정하여 그 적용성을 검토하였다. 이를 위해 대상지역의 시료를 채취하여 함수특성곡선(SWCC) 실험을 수행하였으며, 불포화 투수계수를 산정하였다. 또한 초기 모관흡수력과 강우발생에 따른 모관흡수력 변화를 관측하기 위해 현장계측을 수행하였으며, 그 결과를 산사태 해석에 적용하였다. 그리고 국내 강우특성을 고려한 비탈면 설계를 위하여, 강우패턴에 따른 습윤대 깊이와 안전율 변화를 분석하였다. 특히, 선행강우 효과를 고려한 매개변수 해석을 수행하여 비탈면 안정성에 어떠한 영향을 주는지 습윤대 깊이 변화를 통해 분석하였다. 그 결과, 본 연구에서 제안한 산사태 해석 방법은 지반의 불포화 특성과 선행강우 효과를 고려할 수 있으며, 산사태 발생 위치를 적절히 예측하는 것으로 나타났다. 그리고 강우발생 시, 강우량이 후반부에 집중된 강우패턴에서 비탈면의 안전율이 가장 낮게 나타났다. 또한, 선행강우는 비탈면의 모관흡수력을 감소시켜 불안정성을 증가시키고, 이후 발생된 강우로 인해 습윤대가 깊어지면서 비탈면 파괴 위험이 증가한다.

한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割) (The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea)

  • 윤석규
    • 자원환경지질
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    • 제18권1호
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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