• Title/Summary/Keyword: Ba/F3

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Microwave Dielectric Properties of the $0.98MgTiO_3-0.02BaTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 $0.98MgTiO_3-0.02BaTiO_3$ 세라믹스의 마이크로파 유전특성)

  • Choi, Eui-Sun;Lee, Moon-Kee;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.123-126
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    • 2001
  • The $0.98MgTiO_3-0.02BaTiO_3$ ceramics were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature and composition ratio by XRD, SEM and EDS. According to the X-ray diffraction patterns of the $0.98MgTiO_3-0.02BaTiO_3$ ceramics, the hexagonal $BaMg_6Ti_6O_{19}$ and ilmenite $MgTiO_3$ structures were coexisted. The dielectric constant$({\varepsilin}_r)$ and quality factor$(Q{\times}f_r)$ were decreased with increasing the sintering temperature in the range of $1275^{\circ}C{\sim}1350^{\circ}C$. In the case of the $0.98MgTiO_3-0.02BaTiO_3$ ceramics sintered at $1275^{\circ}C$, dielectric constant, quality factor and temperature coefficient of resonant frequency were 20.27, 76,845, $-46.6ppm/^{\circ}C$, respectively.

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Increased HoxB4 Inhibits Apoptotic Cell Death in Pro-B Cells

  • Park, Sung-Won;Won, Kyung-Jong;Lee, Yong-Soo;Kim, Hye-Sun;Kim, Yu-Kyung;Lee, Hyeon-Woo;Kim, Bo-Kyung;Lee, Byeong-Han;Kim, Jin-Hoi;Kim, Dong-Ku
    • The Korean Journal of Physiology and Pharmacology
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    • v.16 no.4
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    • pp.265-271
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    • 2012
  • HoxB4, a homeodomain-containing transcription factor, is involved in the expansion of hematopoietic stem cells and progenitor cells in vivo and in vitro, and plays a key role in regulating the balance between hematopoietic stem cell renewal and cell differentiation. However, the biological activity of HoxB4 in other cells has not been reported. In this study, we investigated the effect of overexpressed HoxB4 on cell survival under various conditions that induce death, using the Ba/F3 cell line. Analysis of phenotypical characteristics showed that HoxB4 overexpression in Ba/F3 cells reduced cell size, death, and proliferation rate. Moreover, the progression from early to late apoptotic stages was inhibited in Ba/F3 cells subjected to HoxB4 overexpression under removal of interleukin-3-mediated signal, leading to the induction of cell cycle arrest at the G2/M phase and attenuated cell death by Fas protein stimulation in vitro. Furthermore, apoptotic cell death induced by doxorubicin-treated G2/M phase cell-cycle arrest also decreased with HoxB4 overexpression in Ba/F3 cells. From these data, we suggest that HoxB4 may play an important role in the regulation of pro-B cell survival under various apoptotic death environments.

The Effect of Mg Deficiency on the Microwave Dielectric Characteristics of (Mg1/2Nb2/3)O3 Ceramics (Mg 결핍에 따른 Ba(Mg1/2Nb2/3)O3 세라믹스의 마이크로파 유전특성)

  • Paik, Jong-Hoo;Lee, Mi-Jae;Choi, Byung-Hyun;Kim, Hyo-Tae;Jee, Mi-Jung;Lim, Eun-Kyeong;Nahm, Sahn;Lee, Hwack-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.384-389
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    • 2004
  • Crystal structure and microwave dielectric properties of Ba(Mg1/3Nb2/3) $O_3$ (BMN) ceramics were investigated. Ba(Mg1/3Nb2/3) $O_3$ has the 1:2 ordered hexagonal structure. The 1:2 ordering and relative density of specimens increased with small Mg deficiency(x). The variation of Q${\times}$ $f_{0}$ with Mg deficiency is very similar to that of 1:2 ordering and relative density. The highest Q${\times}$ $f_{0}$ achieved in this investigation is about 96,000 for Ba(Mg1/3Nb2/3) $O_3$. The improvement of Q${\times}$ $f_{0}$ with Mg-deficiency is related to the increase of degree of ordering and relative density of the specimen.

Fabrication of Flexible Energy Harvester Based on BaTiO3 Piezoelectric Nanotube Arrays (BaTiO3 압전 나노튜브 어레이 기반의 플렉서블 에너지 하베스터 제작)

  • Seo Young Yoon;Cheol Min Kim;Bitna Bae;Yujin Na;Haksu Jang;Kwi-Il Park
    • Journal of Powder Materials
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    • v.30 no.6
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    • pp.521-527
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    • 2023
  • Piezoelectric technology, which converts mechanical energy into electrical energy, has recently attracted drawn considerable attention in the industry. Among the many kinds of piezoelectric materials, BaTiO3 nanotube arrays, which have outstanding uniformity and anisotropic orientation compared to nanowire-based arrays, can be fabricated using a simple synthesis process. In this study, we developed a flexible piezoelectric energy harvester (f-PEH) based on a composite film with PVDF-coated BaTiO3 nanotube arrays through sequential anodization and hydrothermal synthesis processes. The f-PEH fabricated using the piezoelectric composite film exhibited excellent piezoelectric performance and high flexibility compared to the previously reported BaTiO3 nanotube array-based energy harvester. These results demonstrate the possibility for widely application with high performance by our advanced f-PEH technique based on BaTiO3 nanotube arrays.

Electronic structures of Ba-on-Alq3 interfaces and device characteristics of organic light-emitting diodes based on these interfaces - Device characteristics of Ba-on-Alq3 interfaces of OLEDs

  • Park, Jin-U;Im, Jong-Tae;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.123-124
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    • 2011
  • Tris(8-quinolinolato)aluminum(III) (Alq3)와 Cathode 사이에 Ba o f 1nm를 삽입함으로써 OLED device의 성능이 향상되었다. 이 소자에 삽입된 Ba는 electron-injection barrier height를 낮추어서 전자주입에 영향을 주었다. 그러나 Ba 의 두께가 1nm이상일 경우에는 특성이 안 좋은 소자 성능을 보여줌을 알 수 있었다.

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A study on the dielectric properties of the $Pb(Fe_{1/2}Nb_{1/2})O_3-Pb(Fe_{2/3}W_{1/3})O_3-Ba(Cu_{1/2}W_{1/2})O_3$ ceramics ($Pb(Fe_{1/2}Nb_{1/2})O_3-Pb(Fe_{2/3}W_{1/3})O_3-Ba(Cu_{1/2}W_{1/2})O_3$세라믹의 유전특성에 관한 연구)

  • 정장호;류기원;이영희
    • Electrical & Electronic Materials
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    • v.4 no.2
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    • pp.150-158
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    • 1991
  • 본 연구에서는 0.80Pb(F $e_{1}$2/N $b_{1}$2/) $O_{3}$-(0.20-x)Pb(F $e_{2}$3/ $W_{1}$3/) $O_{3-x}$Ba(C $u_{1}$2/ $W_{1}$2/) $O_{3}$ (x=0.01, 0.02, 0.03) 세라믹을 소결온도 및 시간을 각각 860~960[.deg.C], 2시간으로 하여 일반 소성법으로 제작하였다. 시편의 조성비와 소결온도에 따른 구조적, 유전적 특성을 조사하였으며 유전손실 특성의 개선을 위해 조성 0.80Pb(F $e_{1}$2/N $b_{1}$2/) $O_{3}$-0.18Pb (F $e_{2}$3/ $W_{1}$3/) $O_{3}$-0.02Ba(C $u_{1}$2/ $W_{1}$2/) $O_{3}$시편에 Mn $O_{2}$를 0~1.25[wt%]로 첨가한 후 유전특성의 변화를 관찰하였다. Mn $O_{2}$의 첨가량이 증가함에 따라 결정립의 크기와 유전상수는 점차 감소하였다. 소결밀도는 900[.deg.C]에서 소결시킨 시편의 경우 최대값을 나타내었다. Ba(C $u_{1}$2/ $W_{1}$2/) $O_{3}$의 양이 0.01에서 0.03[mol]로 증가함에 따라 상전이온도는 38[.deg.C]에서 2[.deg.C]로 감소하였다. 조성 0.80Pb(F $e_{1}$2/N $b_{1}$2/) $O_{3}$0.18Pb(F $e_{2}$3/ $W_{1}$3/) $O_{3}$-0.02Ba(C $u_{1}$2/ $W_{1}$2/) $O_{3}$에 Mn $O_{2}$가 0.25[wt%] 첨가된 시편의 20[.deg.C]에서의 유전상수는 16,700으로 최대값을 유전손실을 1.28[%]로 최소값을 나타내었다. 또한 모든 시편은 온도 및 주파수에 따라 유전상수가 완만하게 변화하는 유전이완 특성을 나타내었다.다.

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Microwave Dielectric Properties of Sr-Substituted Ba(Mg0.5W0.5)O3 Ceramics

  • Yoon, Sang-Ok;Choi, Dong-Kyu;Oh, Jun-Hyuk;Kim, Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.364-367
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    • 2018
  • The phase evolution, microstructure, and microwave dielectric properties of Sr-substituted $Ba(Mg_{0.5}W_{0.5})O_3$ ceramics, i.e., $(Ba_{1-x}Sr_x)(Mg_{0.5}W_{0.5})O_3$ ($0{\leq}x{\leq}0.30$), sintered at $1700^{\circ}C$ for 1 h were investigated. All compositions showed a 1 : 1 ordered perovskite structure. In all the compositions, $BaWO_4$ was detected as the secondary phase. With increasing x in ($Ba_{1-x}Sr_x$) $(Mg_{0.5}W_{0.5})O_3$, the lattice parameter increased linearly, indicating that a substitutional solid solution occurred. All compositions exhibited a dense microstructure. The value of ${\varepsilon}_r$ increased slightly with increasing x. The value of $Q{\times}f_0$ increased with the increase in x up to x = 0.10 and reached a saturated value of about 100,000 GHz. The composition for x = 0.20, i.e., $(Ba_{0.80}Sr_{0.20})(Mg_{0.5}W_{0.5})O_3$, sintered at $1700^{\circ}C$ for 1 h exhibited superior microwave dielectric properties of ${\varepsilon}_r=19.6$, $Q{\times}f_0=99,358GHz$, and ${\tau}_f=0.0ppm/^{\circ}C$, respectively.

Recovery of Zirconium from Spent Pickling Acid through Precipitation Using BaF2 and Electrowinning in Fluoride Molten Salt (BaF2 침전 및 불화물 용융염 전해 제련을 통한 폐 산세액 내 지르코늄 회수)

  • Han, Seul Ki;Nersisyan, Hayk H.;Lee, Young Jun;Choi, Jeong Hun;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.681-687
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    • 2016
  • Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and $HNO_3$ mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding $BaF_2$, which reacted with the Zr ion involved in the waste acid; $Ba_2ZrF_8$ was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered $Ba_2ZrF_8$ because its melting temperature is $1031^{\circ}C$. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding $ZrF_4$ to $Ba_2ZrF_8$ to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.

Sequential Formation of Multiple Gap States by Interfacial Reaction between Alq3 and Alkaline-earth Metal

  • Kim, Tae Gun;Kim, Jeong Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.129.2-129.2
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    • 2013
  • Electron injection enhancement at OLED (organic light-emitting diodes) cathode side has mostly been achieved by insertion of a low work function layer between metal electrode and emissive layer. We investigated the interfacial chemical reactions and electronic structures of alkaline-earth metal (Ca, Ba)/Alq3 [tris(8-hydroxyquinolinato)aluminium] and Ca/BaF2/Alq3 using in-situ X-ray & ultraviolet photoelectron spectroscopy. The alkaline-earth metal deposited on Alq3 generates two energetically separated gap states in sequential manner. This phenomenon is explained by step-by-step charge transfer from alkali-earth metal to the lowest unoccupied molecular orbital (LUMO) states of Alq3, forming new occupied states below Fermi level. The BaF2 interlayer initially prevents from direct contact between Alq3 and reactive Ca metal, but it is dissociated into Ba and CaF2. However, as the Ca thickness increases, the Ca penetrates the interlayer to directly participate in the reaction with underlying Alq3. The influence of the multiple gap state formation by the interfacial chemical reaction on the OLED performance will be discussed.

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Regeneration Studies in Grateloupia filicina (J.V. Lamouroux) C. Agardh - An Important Carrageenophyte and Edible Seaweed

  • Baweja, Pooja;Sahoo, Dinabandhu
    • ALGAE
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    • v.24 no.3
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    • pp.163-168
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    • 2009
  • Grateloupia filicina (J.V. Lamouroux) C. Agardh (Halymeniaceae, Cryptonemiales, Rhodophyta) is an edible seaweed as well as an important source of carrageenan. In the present study, attempt has been made to develop a suitable protocol for effective regeneration of the seaweed and the rapid multiplication of the desired varieties. The young upright thallus of G. filicina was grown in axenic culture using both solid and liquid media. The various media tested were f/2, Provasoli’s Enriched Seawater (PES) and Enriched Seawater (ESW). The effect of glycerol (as a carbon source) and various plant growth regulators i.e. auxin (NAA) and cytokinins (Kinetin and BA) were tested. Although, regeneration of young thalli was observed from the cut ends in all the media, better growth was found in f/2, PES, f/2 (0.5% Glycerol), f/2 (NAA ${10^{-5}}_M)\;and\;f/2\;(BA\;{10^{-6}}_M$). On the other hand callusing was observed only in solid media supplemented with low concentration of Glycerol (0.5%) in f/2, NAA ${10^{-5}}_M\;in\;f/2,\;PES\;and\;BA\;{10^{-5}}_M$ in f/2. Young thalli were developed from the callus sub culture after 40 days of inoculation.