• Title/Summary/Keyword: Ba/F3

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Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area (지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석)

  • Lee Sa-Ro;Oh Hyun-Joo;Min Kyung-Duck
    • Spatial Information Research
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    • v.14 no.1 s.36
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    • pp.129-150
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    • 2006
  • Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

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Isolation of Isoflavones and Soyasaponins from the Germ of Soybean (콩 배아로 부터 Isoflavone과 Soyasaponin의 동시 분리)

  • Kim, Sun-Lim;Lee, Jae-Eun;Kim, Yul-Ho;Jung, Gun-Ho;Kim, Dea-Wook;Lee, Choon-Ki;Kim, Mi-Jung;Kim, Jung-Tae;Lee, Yu-Young;Hwang, Tae-Young;Lee, Kwang-Sik;Kim, Wook-Han;Kwon, Young-Up;Kim, Hong-Sig;Chung, Ill-Min
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.2
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    • pp.149-160
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    • 2013
  • The objective of present study was to simultaneously isolate of isoflavone and soyasaponin compounds from the germ of soybean seeds. Soy germ flours were defatted with hexane for 48h at room temperature, and methanolic extracts were prepared using reflux apparatus at $90^{\circ}C$ for 6h, two times. After extraction, extracts were separated with preparative RP-$C_{18}$ packing column ($125{\AA}$, $55-105{\mu}m$, $40{\times}150mm$), and collected 52 fractions were identified with TLC plate (Kieselgel 60 F-254) and HPLC, respectively. Among the identified isoflavone and soyasaponin fractions, isoflavone fractions were re-separated using a recycling HPLC with gel permeation column (Jaigel-W252, $20{\times}500mm$). Final fractions were air-dried, and the purified compounds of two isoflavones (ISF-1-1, ISF-1-2) and four soyasaponins (SAP-1, SAP-2, SAP-3, SAP-4) were obtained. Two isoflavone compounds (ISF-1-1, ISF-1-2) were acid-hydrolyzed for the identification of their aglycones, and confirmed by comparing with 12 types of isoflavone isomers. While the four kinds of soyasaponins were identified by using a micro Q-TOF mass spectrometer in the ESI positive mode with capillary voltage of 4.5kV, and dry temperature of $200^{\circ}C$. Base on the obtained results, it was conclude that ISF-1-1 is the mixture isomers of daidzin (43.4%), glycitin (47.0%), and genistin (9.6%), but ISF-1-2 is the single compound of genistin (99.8% <). On the other hand, soyasaponin SAP-1 is the mixture compounds of soyasaponin A-group (Aa, Ab, Ac, Ae, Af); SAP-2 is soyasaponin B-group (Ba, Bb, Bc) and E-group (Bd, Be); SAP-3 is soyasaponin B-group (Ba, Bb, Bc), E-group (Bd, Be), and DDMP-group (${\beta}g$); SAP-4 is soyasaponin B-group (Ba, Bb, Bc), E-group (Bd, Be), and DDMP-group (${\beta}g$, ${\beta}a$), respectively.

Melting Characteristics for Radioactive Aluminum Wastes in Electric Arc Furnace (아크 용융로에서 방사성 알루미늄 폐기물의 용융특성)

  • Min, Byung-Youn;Song, Pyung-Seob;Ahn, Jun-Hyung;Choi, Wang-Kyu;Jung, Chong-Hun;Oh, Won-Zin;Kang, Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.1
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    • pp.33-40
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    • 2006
  • The characteristics of the aluminum waste melting and the distribution of the radioactive nuclides have been investigated for the estimation on the volume reduction and the decontamination of the aluminum wastes from the decommissioning of the TRIGA MARK it and III research reactors at the Korea Atomic Energy Research Institute(KAERI). The aluminum wastes were melted with the use of the fluxes such as flux $A:NaCl-KCl-Na_3AlF_6$, flux B:NaCl-NaF-KF, flux $C:CaF_2$, and flux $D:LiF-KCl-BaCl_2$ in the DC graphite arc furnace. For the assessment of the distribution of the radioactive nuclides during the melting of the aluminum, the aluminum materials were contaminated by the surrogate nuclides such as cobalt(Co), cesium(Cs) and strontium(Sr). The fluidity of aluminum melt was increased with the addition of the fluxes, which has slight difference according to the type of fluxes. The formation of the slag during the aluminum melting added the flux type C and D was larger than that with the flux A and B. The rate of the slag formation linearly increased with increasing the flux concentration. The results of the XRD analysis showed that the surrogate nuclide was transferred to the slag, which can be easily separated from the melt and then they combined with aluminum oxide to form a more stable compound. The distribution ratio of cobalt in ingot to that in slag was more than 40% at all types of fluxes. Since vapor pressures of cesium and strontium were higher than those that of the host metals at the melting temperature, their removal efficiency from the ingot phase to the slag and the dust phase was by up to 98%.

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Microstructure and Microwave Dielectric Properties of Glass $(La_2O_3-B_2O_3-TiO_2)$/Ceramic Composites ($(La_2O_3-B_2O_3-TiO_2)$ 세라믹 조성에서의 미세 조직 과 마이크로 유전체 특성)

  • Jung, Byung-Hae;Hwang, Seong-Jin;Han, Tae-Hee;Kim, Hyung-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.138-138
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    • 2003
  • Low temperature co-fired ceramic (LTCC) technology offers significant benefits over the other established packaging technologies for high density, high microwave frequency, and fast signal application. Most conventional electroceraramics do not meet the basic requirements in respect of sinterability for LTCC technology. Attention is, therefore, focused on the role of glasses because of the capability they supply with lower sintering temperatures. In this study, commercial ceramic (MBRT-90) in the system BaO-N $d_2$ $O_3$-Ti $O_2$ (BNT: 40 ~ 80 wt%) and L $a_2$ $O_3$- $B_2$ $O_3$-Ti $O_2$ glass (LBT;60 ~ 20 wt%) were prepared. These glass/ceramic composites were evaluated for sintering behavior, phase evaluation, densities, interface reaction, crystallinity, microstructure and microwave dielectric properties. It was found that the addition LBT glass frits significantly lowered the sintering temperature to below 90$0^{\circ}C$ and as temperature increased (750~90$0^{\circ}C$) densification developed dynamically which was meant to be as over 95% of relative density. It is supposed that in the microstructure, the grain size was increased accompanying with the formation of different phases such as LaB $O_3$ and Ti $O_2$ under the condition of increasing sintering temperature. The sintered bodies represented applicable dielectric properties, namely 20 ~ 40 for $\varepsilon_{{\gamma}}$, ~ 10000 GHz for Q* $f_{0}$ and 10~80 ppm/$^{\circ}C$ for $\tau$$_{f}$. The results suggest that the composite is one of feasible candidates for the microwave use in LTCC technology.y.e use in LTCC technology.y.

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Effects of composition of preannealed Y-Ba-Cu-0 thin films deposited by sputtering on the superconducting properties and microstructure of post-annealed thin films (스퍼터링 증착된 Y-Ba-Cu-O계 박막의 열처리 전 조성이 열처리 후 박막의 초전도특성 및 미세구조에 미치는 영향)

  • Cho, Hae-Seok;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.1 no.1
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    • pp.54-61
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    • 1991
  • YBCO films deposited on MgO(100) and Si(100) by rf-magnetron sputtering using stoichiometric single target were annealed under oxygen atmosphere at $880^{\circ}C$ for 1 hr. The microstructure and superconducting properties of YBCO thin films depended on the composition of pre-annealed thin films. Basal planesuperconducting particles grown on MgO(100) substrate had small and rod-like shade due to preferred orientation, while superconducting film grown on the basal plane-superconducting particles showed round-shape particles. If pre-annealed thin film had nonstoichiometric composition, liquid phase was formed during the heat treatment, which made it easy for particles to grow in the preferred orientation and thus to form textured structure. But the thin films with the textured structure did not show good superconducting properties, especially $T_c$, since the liquid phase transformed into second phase in the grain boundary during the cooling. The effect of the second phase on $T_{c, \;zero}$ was greater than that on $T_{c, \;on}$.

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The fabrication and analysis of BSCT thick films for uncooled infrared detectors (비냉각 검출기를 위한 BSCT 후막의 제작과 특성 분석)

  • Noh, Hyun-Ji;Lee, Sung-Gap;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.171-172
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    • 2008
  • $(Ba_{0.57}Sr_{0.33}Ca_{0.10})TiO_3$ (BSCT) thick films doped with 0.1 mol% $MnCO_3$ and $Yb_2O_3$ ($0.1{\sim}0.7$ mol%) were fabricated by the screen printing method on the alumina substrate. And the structural and electrical properties as a function of $Yb_2O_3$ amount were investigated. The lattice constants of the BSCT thick film doped with 0.1 mol% is 0.3955 nm. The specimen doped with 0.7 mol% $Yb_2O_3$ showed dense and uniform grains with diameters of about 6.3 mm. The thickness of all BSCT thick films was approximately 60 mm. The Curie temperature of the BSCT specimen doped with 0.1 mol% $Yb_2O_3$ was $18^{\circ}C$, and the dielectric constantand dielectric loss at this temperature was 4637 and 4.2%, respectively. The BSCT specimen doped with 0.1 mol% $Yb_2O_3$ showed the maximum value of $349{\times}10^{-9}C/cm^2K$ at Curie temperature. The figure of merit $F_D$ for specific detectivity of the specimens doped with 0.1 mol% $Yb_2O_3$ showed the highest value of $10.9{\times}10^{-9}Ccm/J$.

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Fabrication of Barium Oxide Ferrite Magnet-II (바리움 훼라이트 자석의 시작 - II)

  • 백용현
    • 전기의세계
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    • v.21 no.6
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    • pp.17-20
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    • 1972
  • The magnetic properties of Ba-Ferrite ( $M^{+2}$O.nF $e_{2}$ $O_{3}$ is highly improved under the condition of composition ratio n=4.4 when B $i_{2}$ $O_{3}$ is added to Ferrite, the adding amount and sintering temperature which affect the magnetic properties were investigated and the following results; were obtained; 1. Magnetic properties are varied with B $i_{2}$ $O_{3}$ content and singering temperature, and coercive force and residual induction can be improved with B $i_{2}$ $O_{3}$. 2. The optimal content of B $i_{2}$ $O_{3}$ amount is about 4 mol %, 3. Without the addition of B $i_{2}$ $O_{3}$, the optimal sintering temperature is about 1300.deg. C, but when 4 mol % of B $i_{2}$ $O_{3}$ is added, the optimal sintering temperature falls to the range of 900.deg. C to 1100.deg. C and it also improves magnetic properties. 4. Residual induction increases as the singering temperature is raised to 1100.deg. C. Coercive force also increased as the sintering temperature is raised to 1000.deg. C, but it rapidly decreases when sintering temperature goes beyond 1000.deg. C. 5. Only a negligible change may be noticed in the decrease of Curie temperature by the addition of about 4 mol % of B $i_{2}$ $O_{3}$.

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Elastic Property Extraction System of Polycrystalline Thin-Films for Micro-Electro-Mechanical System Device and Application to Polycrystalline Materials (MEMS 부품을 위한 다결정 박막의 탄성 물성치 추출 시스템과 다결정 재료의 적용)

  • Jung H. N.;Choi J. H.;Chung H. T.;Lee J. K.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.19-22
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    • 2004
  • A numerical system to extract effective elastic properties of polycrystalline thin-films for MEMS devices is already developed. In this system, the statistical model based on lattice system is used for modeling the microstructure evolution simulation and the key kinetics parameters of given micrograph, grain distributions and deposition process can be extracted by inverse method proposed in the system. In this work, the effective elastic properties of polysilicon, $BaTiO_3\;and\;ZrTiO_4$ are extracted using this system and by employing the fraction of the potential site($f_P$) as a kinetics parameter for the microstructure evolution, the statistical tendency of these materials is studied.

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An Analysis on the Water Quality of Limestone Cave System in Danyang region (단양지역에 분포한 석회암동굴계의 수질에 대한 분석)

  • 임종호;홍시환
    • Journal of the Speleological Society of Korea
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    • v.33 no.34
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    • pp.7-22
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    • 1993
  • 본 연구에서는 단양지역에 분포한 석회암동굴계의 수질에 대한 주요 원소와 미량 원소 그리고 오염실태를 살펴보았다. 풍화물에 존재하는 미량 원소가 기반암보다 수 배 내지 수 백배 이상 부하되어 있었다. TSD와 EC 등은 화강암의 지하수 보다 높은 경향이 있었고 pH는 중성 내지 알칼리성이었다. Ca와 Mg은 기반암에서 용탈되어 지하수로 용존된 것으로 50ppm이상을 함유하고 있다. Fe과 K은 다른 주요 원소보다 현저히 낮은 경향이 있었다. 주요 음이온인 F$^{-}$ , Cl$^{-}$ , NO$_3$$^{-}$ , SO$_4$$^{-}$ 등은 환경기준치 보다도 현저히 낮은 상태이며, 따라서 오염이 안된 상태로 볼 수 있다. 미량 원소중 Al, Sr, Ba등이 높은 반면에 Co, Mo, Sb, Cs, W, Pb, U, Mn 등은 매우 극소량으로 존재하는 것으로 나타났다. 연구지역 중 온달굴, 고수굴, 천동, 노동 등지는 오염이 거의 안된 상태로 매우 양호한 편이나 천동굴은 관광객으로 인하여 일부 원소가 오염되어 있는 실정이다.

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Preparation and Its Properties of YBCO Superconductor Induced by Seeds

  • Shan, Y.Q.;Soh, D.W.;Fan, Z.G.;Men, M.F.;Wang, W.H.;Zhao, Z.X.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.371-373
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    • 1998
  • The SmBa$_2$Cu$_3$O$\sub$x/ single crystals were used as seeds to induced YBCO growth in MTG process. As the result, the large bulk oriented YBCO superconductors were prepared with dimension of plane 21mm and 32mm in diameter and 10mm in height. The typical Jc value of the sample is 6.5${\times}$10$^4$A/$\textrm{cm}^2$ and its flux float force is 4.6N/$\textrm{cm}^2$. The oxygen absorption in large bulk textured YBCO samples in pure oxygen was studied at several constant temperatures. It can be divided into two steps: a chemical reaction step and a diffusion step.

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