• Title/Summary/Keyword: B2B2C

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Effect of Transition Metal on Properties of SiC Electroconductive Ceramic Composites (SIC 도전성 세라믹 복합체의 특성에 미치는 천이금속의 영향)

  • 신용덕;오상수;주진영
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.352-357
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    • 2004
  • The composites were fabricated, respectively, using 61vol.% SiC - 39vol.% TiB$_2$ and using 61vo1.% SiC - 39vo1.% WC powders with the liquid forming additives of 12wt% $Al_2$O$_3$+Y$_2$O$_3$ by pressureless annealing at 180$0^{\circ}C$ for 4 hours. Reactions between SiC and transition metal TiB$_2$, WC were not observed in this microstructure. The result of phase analysis of composites by XRD revealed SiC(6H), TiB$_2$ and YAG(Al$_{5}$Y$_3$O$_{12}$) crystal phase on the SiC-TiB$_2$, and SiC(2H), WC and YAG(Al$_{5}$Y$_3$O$_{12}$) crystal phase on the SiC-WC composites. $\beta$\$\longrightarrow$$\alpha$-SiC phase transformation was ocurred on the SiC-TiB$_2$, but $\alpha$\$\longrightarrow$$\beta$-SiC reverse transformation was not occurred on the SiC-WC composites. The relative density, the vicker's hardness, the flexural strength and the fracture toughness showed respectively value of 96.2%, 13.34GPa, 310.19Mpa and 5.53Mpaㆍml/2 in SiC-WC composites. The electrical resistivity of the SiC-TiB$_2$ and the SiC-WC composites is all positive temperature coefficient resistance(PTCR) in the temperature ranges from $25^{\circ}C$ to 50$0^{\circ}C$. 2.64${\times}$10-2/$^{\circ}C$ of PTCR of SiC-WC was higher than 1.645${\times}$10-3/$^{\circ}C$ of SiC-TiB$_2$ composites.posites.

A Study on C2B2C Business Integration Model Design Focusing On the Fashion Clothes Business

  • Cheng, Zhi-Chao;Kwon, Donghwoon;Jin, Chang-Hai;Kwon, YoungJik
    • Journal of Multimedia Information System
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    • v.3 no.3
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    • pp.85-90
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    • 2016
  • We firstly tried to understand consumers' purchasing tendencies and mainly focused on designing a platform model that offers integrated support. C2B (Customer to Business) orders integrate with a consumption platform of a B2C (Business to Customer) model, and integrated support aims at design, supply, processing, and distribution of a fashion business. All the information such as orders, sales, production, supply, and settlement of accounts is synchronized under the C2B, B2C, and O2O (Online to Offline) environment so that accurate information can be shared in real time. Our platform automatically handles with a net income of a product designer, manufacturer, and shipping company once shipping is confirmed.

방전플라즈마 소결에 의한 SiC-$ZrB_2$ 복합체 개발

  • Kim, Cheol-Ho;Sin, Yong-Deok;Ju, Jin-Yeong;Lee, Jeong-Hun;Lee, Hui-Seung;Kim, Jae-Jin;Lee, Jong-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.87-87
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    • 2009
  • The composites were fabricated by adding 30, 40, 50, 60[vol.%] Zirconium Diboride(hereafter, $ZrB_2$) powders as a second phase to Silicon Carbide(hereafter, SiC) matrix. SiC-$ZrB_2$ composites were sintered by Spark Plasma Sintering(hereafter, SPS) in argon gas atmosphere. The relative density SiC+30[vol.%]$ZrB_2$, SiC+40[vol.%]$ZrB_2$, SiC+50[vol.%]$ZrB_2$ and SiC+60[vol.%]$ZrB_2$ composites are 94.98[%], 99.57[%], 96.58[%] and 93.62[%] respectively.

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Effects of neutron irradiation on superconducting critical temperatures of in situ processed MgB2 superconductors

  • Kim, C.J.;Park, S.D.;Jun, B.H.;Kim, B.G.;Choo, K.N.;Ri, H.C.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.9-13
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    • 2014
  • Effects of neutron irradiation on the superconducting properties of the undoped $MgB_2$ and the carbon(C)-doped $MgB_2$ bulk superconductors, prepared by an in situ reaction process using Mg and B powder, were investigated. The prepared $MgB_2$ samples were neutron-irradiated at the neutron fluence of $10^{16}-10^{18}n/cm^2$ in a Hanaro nuclear reactor of KAERI involving both fast and thermal neutron. The magnetic moment-temperature (M-T) and magnetization-magnetic field (M-H) curves before/after irradiation were obtained using magnetic property measurement system (MPMS). The superconducting critical temperature ($T_c$) and transition width were estimated from the M-T curves and critical current density ($J_c$) was estimated from the M-H curves using a Bean's critical model. The $T_cs$ of the undoped $MgB_2$ and C-doped $MgB_2$ before irradiation were 36.9-37.0 K and 36.6-36.8 K, respectively. The $T_cs$ decreased to 33.2 K and 31.6 K, respectively after irradiation at neutron fluence of $7.16{\times}10^{17}n/cm^2$, and decreased to 22.6 K and 24.0 K, respectively, at $3.13{\times}10^{18}n/cm^2$. The $J_c$ cross-over was observed at the high magnetic field of 5.2 T for the undoped $MgB_2$ irradiated at $7.16{\times}10^{17}n/cm^2$. The $T_c$ and $J_c$ variation after the neutron irradiation at various neutron fluences were explained in terms of the defect formation in the superconducting matrix by neutron irradiation.

Significant enhancement of critical current density by effective carbon-doping in MgB2 thin films

  • Ranot, Mahipal;Lee, O.Y.;Kang, W.N.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.2
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    • pp.12-15
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    • 2013
  • The pure and carbon (C)-doped $MgB_2$ thin films were fabricated on $Al_2O_3$ (0001) substrates at a temperature of $650^{\circ}C$ by using hot-filament-assisted hybrid physical-chemical vapor deposition technique. The $T_c$ value for pure $MgB_2$ film is 38.5 K, while it is between 30 and 35 K for carbon-doped $MgB_2$ films. Expansion in c-axis lattice parameter was observed with increase in carbon doping concentration which is in contrast to carbon-doped $MgB_2$ single crystals. Significant enhancement in the critical current density was obtained for C-doped $MgB_2$ films as compared to the undoped $MgB_2$ film. This enhancement is most probably due to the incorporation of C into $MgB_2$ and the high density of grain boundaries, both help in the pinning of vortices and result in improved superconducting performance.

Protection of aquo/hydroxocobalamin from reduced glutathione by a B12 trafficking chaperone

  • Jeong, Jin-Ju;Ha, Tal-Soo;Kim, Ji-Hoe
    • BMB Reports
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    • v.44 no.3
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    • pp.170-175
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    • 2011
  • We identified a bovine $B_{12}$ trafficking chaperone bCblC in Bos taurus that showed 88% amino acid sequence identity with a human homologue. The protein bCblC was purified from E. coli by over-expression of the encoding gene. bCblC bound cyanocobalamin (CNCbl), methylcobalamin (MeCbl) and adenosylcobalamin (AdoCbl) in the base-off states and eliminated the upper axial ligands forming aquo/hydroxocobalamin ($OH_2$/OHCbl) under aerobic conditions. A transition of $OH_2$/OHCbl was induced upon binding to bCblC. Interestingly, bCblC-bound $OH_2$/OHCbl did not react with reduced glutathione (GSH), while the reaction of free$OH_2$/OHCbl with GSH resulted in the formation of glutathionylcobalamin (GSCbl) and glutathione disulfide (GSSG). Furthermore we found that bCblC eliminates the GSH ligand of GSCbl forming $OH_2$/OHCbl. The results demonstrated that bCblC is a $B_{12}$ trafficking chaperone that binds cobalamins and protects $OH_2$/OHCbl from GSH, which could be oxidized to GSSG by free $OH_2$/OHCbl.

Sintering and Mechanical Properties of Chromium Boride-chromium Carbide Composites

  • Matsushita, Jun-Ichi;Shimao, Kenji;Machida, Yoshiyuki;Takao, Takumi;Iizumi, Kiyokata;Sawada, Yutaka;Shim, Kwang-Bo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1104-1105
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    • 2006
  • Several boride sintered bodies such as $TiB_2$, $ZrB_2$, and $SiB_6$ were previously reported. In the present study, the sinterability and physical properties of chromium boride $(CrB_2)$ containing chromium carbide $(Cr_3C_2)$ sintered bodies were investigated in order to determine its new advanced material. The samples were sintered at desired temperature for 1 hour in vacuum under a pressure by hot pressing. The relative density of sintered bodies was measured by Archimedes' method. The relative densities of $CrB_2$ addition of 0, 5, 10, 15 and 20 mass% $Cr_3C_2$ composites were 92 to 95%. The Vickers hardness of the $CrB_2$ with 10 and 15 mass% $Cr_3C_2$ composites were about 14 and 15 GPa at room temperature, respectively. The Vickers hardness at high temperature of the $CrB_2$ addition of 10 mass% $Cr_3C_2$ composite decreased with increasing measurement temperature. The Vickers hardness at 1273 K of the sample was 6 GPa. The Vickers hardness of $CrB_2$ addition of $Cr_3C_2$ composites was higher than monolithic $CrB_2$ sintered body. The powder X-ray diffraction analysis detected CrB and $B_4C$ phases in $CrB_2$ containing $Cr_3C_2$ composites.

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Densification and Properties of ZrB2-based Ceramics for Ultra-high Temperature Applications (초고온용 ZrB2-계 세라믹스의 치밀화와 물성)

  • Kim, Seong-Won;Kim, Hyung-Tae;Kim, Kyung-Ja;Seo, Won-Seon
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.3
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    • pp.273-278
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    • 2012
  • $ZrB_2$ has a melting temperature of $3245^{\circ}C$ and a low density of $6.1\;g/cm^3$, which makes this a candidate for application to ultra-high temperature over $2000^{\circ}C$. Beside these properties, $ZrB_2$ has excellent resistance to thermal shock and oxidation compared with other non-oxide engineering ceramics. This paper reviewed briefly 2 research examples, which are related to densification and properties of $ZrB_2$-based ceramics for ultra-high temperature applications. In the first section, the effect of $B_4C$ addition on the densification and properties of $ZrB_2$-based ceramics is shown. $ZrB_2$-20 vol.% SiC system was selected as a basic composition and $B_4C$ or C was added to this system in some extents. With sintered bodies, densification behavior and hightemperature (up to $1400^{\circ}C$) properties such as bending strength and hardness are examined. In the second section, the effect of the SiC size on the microstructures and physical properties is shown. $ZrB_2$-SiC ceramics are fabricated by using various SiC sources in order to investigate the grain-growth inhibition and the mechanical/thermal properties of $ZrB_2$-SiC.

Improvement of a Nitrogen Fertilizer Recommendation Model by introducing a Concept of the Mitscherlich-Baule-Spillman Equation (토양검정에 의한 질소시비량 결정에 Mitscherlich-Baule-Spillman 개념의 응용)

  • Kwak, Han-Kang;Song, Yo-Sung;Yeon, Byeong-Yeol;Oh, Wang-Keun;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.5
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    • pp.311-315
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    • 2001
  • In order to improve a soil test-based fertilization model for nitrogen, the Mitscherlich-Baule-Spillman equation modified by Bray and his coworkers was introduced and tested for its possibility of application. The coefficients $C_1$ and $C_2$ in the equation A were calculated by applying 10 pot experimental results done by the National Institute of Agricultural Sciences and Technology. Then, a regression(B) between C_1 and x, the fertilizer level was estimated. log(Ymax-Y) = logYmax-$C_1x-C_2b$ (A) where Ymax : maximum yield. Y : yield without or with a limited amount of fertilizer applied, x : application level of fertilizer, b : content of a nutrient in soil, $C_1$ and $C_2$ : coefficients of x and b, respectively. log(0.05)=$-C_1x-C_2b$ (B) Fertilizer requirement calculated by the equation B was significantly correlated with the real level of fertilizer applied for 95 percentage of the maximum yield. A more extensive and precise study on $C_1$ and $C_2$ in the equation A in expected to improve significantly the fitness of soil analysis to the fertilizer recommendation.

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Reaction Parameters on the Reactivity in the Preparation of B4C by SHS (자전연소합성법에 의한 B4C분말의 제조에 있어 반응성에 대한 반응변수의 고찰)

  • Shin, Chang-Yun;Yun, Ki-Seok;Park, Yeong-Cheol;Hayk, Nersisyan;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.22-27
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    • 2005
  • The preparation of B4C by SHS in $B_{2}O_{3}-Mg-C$ system was investigated in this study. In the preparation of B4C, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and C in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 25 atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 25 atm, the optimum composition for the preparation of pure B4C was $2B_{2}O_{3}+6.3Mg +0.94C$. The B4C synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.