• 제목/요약/키워드: B&BR

검색결과 310건 처리시간 0.036초

분자동역학을 이용한 [C10mim][Br] 의 응집에 관한 연구 (Molecular Dynamics Study of [C10mim][Br] Aggregation)

  • 윤홍민;이준상
    • 대한기계학회논문집B
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    • 제36권8호
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    • pp.873-876
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    • 2012
  • Ionic Liquids (ILs) 는 표준상태에서 액체이온으로 존재하는 물질로 여러 가지 방법으로 다양한 특성을 띄게 할 수 있다. 이런 성질을 적절하게 이용하여 계면활성제 등 다양한 분야로의 응용이 가능하다. ILs의 한 종류인 1-10-alkyl-3-methylimidazolium bromide([C10mim][Br]) 은 특정한 환경에서 양친매성을 가진다. 이번 논문에서 우리는 분자동역학을 이용하여 수용액에서의 [C10mim][Br]의 응집 거동에 대한 연구를 진행하였다. 정준모듬(canonical ensemble)을 이용하여 모사 간 시스템의 부피와 온도를 일정하게 유지시키고 5ns 동안의 전산모사를 통하여 얻은 radial distribution function(RDF)을 이용하여 [C10mim][Br]과 물 분자간의 상호작용 및 그 분포의 특성에 대하여 논의하였다. 분자동역학적 계산을 위하여 LAMMPS 코드를 사용하였고, VMD 코드를 이용하여 후처리(post processing)을 진행하였다.

Co-Mn-Br계 균일촉매를 이용한 2,6-Dimethylnaphthalene의 산화반응 (Oxidation of 2,6-Dimethylnaphthalene by Co-Mn-Br Based Homogeneous Catalyst)

  • 김동범;박승두;차운오;노항덕;곽규대
    • 공업화학
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    • 제10권6호
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    • pp.863-870
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    • 1999
  • 본 연구에서는 촉매로 Co-Mn-Br계를 사용하고, 상대적으로 온화한 반응조건에서 2,6-Dimethylnaphthalene(DMN)의 산화 반응 특성과 촉매가 반응에 미치는 영향을 고찰하였다. 이를 위해 $2{\ell}$의 회분식 반응기를 이용하여 촉매의 농도를 조절하며 실험하였다. 먼저 반응시간에 따른 반응중간생성물의 농도변화를 분석하여 반응경로를 확인하였고, 그 결과 2-formyl-6-naphthoic acid, 2-methyl-6-naphthoic acid, 그리고 2-hydroxymethyl-6-methylnaphthalene이 반응중간물임을 확인할 수 있었다. 또한, 2,6-naphthalene dicarboxylic acid(NDA)의 수율은 Co와 Br의 농도에 많은 영향을 받는다는 것을 알 수 있었고, 제품의 품질 척도 중 하나인 color-b는 Mn의 농도와 밀접한 관련이 있는 것으로 나타났으며, 용매연소는 Mn과 Br의 농도조절로 줄일 수가 있었다. 조촉매로 Ce/Cu 화합물을 첨가함으로 NDA의 수율을 증가시키고 용매연소를 줄이는 결과를 얻을 수 있었다.

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H2O/LiBr+HO(CH2)3OH계 공냉형 이중효용 흡수식 냉방시스템의 사이클 해석 (Cycle Analysis of Air-Cooled Double-Effect Absorption Cooling System Using H2O/LiBr+HO(CH2)3OH)

  • 권오경;문춘근;윤정인
    • 대한기계학회논문집B
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    • 제23권2호
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    • pp.272-280
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    • 1999
  • A cycle analysis was achieved to predict the characteristics by comprehensive modeling and simulation of an air-cooled, double-effect absorption system using a new $H_2O/LiBr+HO(CH_2)_3OH$ solution. The simulation results showed that the new working fluid may provide the crystallization limit 8% higher than the conventional $H_2O/LiBr$ solution. With a crystallization margin of 3wt%(weight%), the optimal solution distribution ratio was found in the range of 36 to 40%. Variation of cooling air Inlet temperature has a sensitive effect on the cooling COP and corrosion problem. The simulation of heat exchangers with UA value revealed that the absorber and the evaporator are relatively important for an air-cooled system compared with the condenser and the low temperature generator. The effect of cooling air flow rate, circulation weak solution flow rate and chilled water inlet temperature were also examined. The new working fluid may provide the COP approximately 5% higher than the conventional $H_2O/LiBr$ solution.

Effect of Blade Materials on Wear Behaviors of Styrene-Butadiene Rubber and Butadiene Rubber

  • Lee, Gi-Bbeum;Shin, Beomsu;Han, Eunjung;Kang, Dawon;An, Dae Joon;Nah, Changwoon
    • Elastomers and Composites
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    • 제56권3호
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    • pp.172-178
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    • 2021
  • The wear behavior of styrene-butadiene rubber (SBR) and butadiene rubber (BR) was investigated using a blade-type abrader with a steel blade (SB), Ti-coated tungsten carbide blade (TiB), or zirconia blade (ZB). The wear rate of SBR against SB and TiB decreased with increasing number of revolutions because of the blunting of the blades during wear. However, the wear rate of SBR against ZB remained nearly constant with little blade blunting. Generally, the wear rate of BR was largely unaffected by the blade material used for abrasion. The wear rate and frictional coefficient of SBR were found to be higher than those of BR at similar levels of frictional energy input. A power-law relationship was found between the wear rate and frictional energy input during abrasion. A well-known Schallamach pattern was observed for SBR, while a much finer pattern was observed for BR. The blade material affects the wear rate of the rubbers because the macromolecular free radicals and blade tend to undergo mechano-chemical reactions. The inorganic ZB was found to be the most inert for such a mechanism.

The Brassica rapa Rubber Elongation Factor Promoter Regulates Gene Expression During Seedling Growth in Arabidopsis thaliana and Brassica napus

  • Hong, Joon Ki;Lim, Myung-Ho;Kim, Jin A;Kim, Jung Sun;Lee, Seung Bum;Suh, Eun Jung;Lee, Soo In;Lee, Yeon-Hee
    • Plant Breeding and Biotechnology
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    • 제2권3호
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    • pp.289-300
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    • 2014
  • A tissue-specific and developmentally expressed gene was isolated from Chinese cabbage (Brassica rapa L. ssp. pekinensis), designated BrREF (B. rapa Rubber elongation factor). BrREF transcripts were expressed at high levels in seedlings and at low levels in flower buds and roots. To study the activity of this promoter, the 2.2 kb upstream sequence of BrREF gene was fused to a β-glucuronidase (GUS) reporter gene and was introduced into Arabidopsis thaliana and B. napus by Agrobacterium-mediated transformation. Strong expression of GUS driven by the BrREF promoter was detected in the cotyledons and hypocotyls of transgenic plant seedlings, but GUS expression was weak in roots, excluding the root tips. GUS expression in the cotyledons and hypocotyls decreased dramatically as the seedlings matured and was not detected in the tissues of mature plants. During floral development, GUS expression was observed in immature anthers. These findings suggest that the BrREF promoter can modulate the tissue-specific and developmental expression of gene at the early stages of growth and development.

LiBr계 용액을 사용한 수직관 흡수기의 열 및 물질 전달에 관한 연구 (A Study on Heat and Mass Transfer in a Vertical Tube Absorber Using LiBr Family Solutions)

  • 조현철;김종보;정시영;강상우;이춘식
    • 설비공학논문집
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    • 제7권2호
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    • pp.196-206
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    • 1995
  • Experimental investigations on heat and mass transfer characteristics in a vertical tube absorber have been carried out. Three different copper tubes with a length of 1.5m have been tested using LiBr solution and LiBr-$CaCl_2$ solution. The effects of solution flow rate, cooling water temperature, solution inlet temperature and evaporation temperature have been investigated in detail. It is found that heat transfer coefficient increases gradually with the increase of solution flow rate, but decreases rapidly for the flow rates less than 0.02kg/ms. The grooved tube generally shows better heat transfer performances than the smooth tube. LiBr solution shows almost no absorption capability for the cooling water temperatures over $40^{\circ}C$. LiBr-$CaCl_2$ gives less decreasing rate in absorption capability at these temperatures and the heat transfer coefficient becomes less dependent on the types of tubes in use. Considering heat and mass transfer rates, LiBr-$CaCl_2$ solution is found to be more suitable than LiBr solution for air cooled absorber, which operates at higher temperature than water cooled absorber.

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시호(柴胡)가 MC 및 Mouse의 염증관련 cytokine 분비에 미치는 영향 (Effect of Bupleuri Radix on Inflammatory Cytokine Secretion to HMC and Mouse Immmune Cells)

  • 최성우;강희;심범상;김성훈;최승훈;안규석
    • 동의생리병리학회지
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    • 제23권1호
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    • pp.150-157
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    • 2009
  • This research was performed in order to investigate the anti-inflammatory effects of Bupleuri Radix(BR) on the Immune response in vitro. Cellular proliferation and cytokine production were measured in mast cells or mouse B cells or CD4 Th cells. BR water extract inhibited the secretions of TNF-$\alpha$ and IL-6 in PMA/A23187 stimulated HMC-1 cells. It increased proliferation but did not affect the expressions of CD69 or CD23 in rIL-4/anti-CD40 activated S cells. BR reduced surface IgE expression and secreted IgE but increased the production of IL-4, IFN-$\gamma$ and IgG1 in the same cells. BR caused an increase in proliferation in anti-CD3/anti-CD28 stimulated CD4 Th cells but it did not affect the differentiation of Th1 or Th2 cells. However, IL-2 was increased in BR treated Th2 cells. Considering the above-mentioned results, BR can be applied to a broad range of anti-inflammatory reactions, but our data suggest that it will not be likely to exert any effects on type 1 allergic response.

Genetic mapping and sequence analysis of Phi class Glutathione S-transferases (BrGSTFs) candidates from Brassica rapa

  • Park, Tae-Ho;Jin, Mi-Na;Lee, Sang-Choon;Hong, Joon-Ki;Kim, Jung-Sun;Kim, Jin-A;Kwon, Soo-Jin;Zang, Yun-Xiang;Park, Young-Doo;Park, Beom-Seok
    • Journal of Plant Biotechnology
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    • 제35권4호
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    • pp.265-274
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    • 2008
  • Glutathione S-transferases (GSTs) are multifunctional proteins encoded by a large gene family divided into Phi, Tau, Theta, Zeta, Lambda and DHAR classes on the basis of sequence identity. The Phi(F) and Tau(U) classes are plant-specific and ubiquitous. Their roles have been defined as herbicide detoxification and responses to biotic and abiotic stresses. Fifty-two members of the GST super-family were identified in the Arabidopsis thaliana genome, 13 members of which belong to the Phi class of GSTs (AtGSTFs). Based on the sequence similarities of AtGSTFs, 11 BAC clones were identified from Brassica rapa. Seven unique sequences of ORFs designated the Phi class candidates of GST derived from B. rapa (BrGSTFs) were detected from these 11 BAC clones by blast search and sequence alignment. Some of BrGSTFs were present in the same BAC clones indicating that BrGSTFs could also be clustered as usual in plant. They were mapped on B. rapa linkage group 2, 3, 9 and 10 and their nucleotide and amino acid sequences were highly similar to those of AtGSTFs. In addition, in silico analysis of BrGSTFs using Korea Brassica Genome Project 24K oligochip and microarray database for cold, salt and drought stresses revealed 15 unigenes to be highly similar to AtGSTFs and six of these were identical to one of BrGSTFs identified in the BAC clones indicating their expression. The sequences of BrGSTFs and unigenes identified in this study will facilitate further studies to apply GST genes to medical and agriculture purposes.

산란노계와 육계의 이화학적 품질특성 평가 (Physico-Chemical Characteristics Evaluation of Spent Hen and Broiler)

  • 전기홍;황윤선;김영붕;최윤상;김병목;김동욱;장애라
    • 한국식품영양학회지
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    • 제28권4호
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    • pp.527-532
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    • 2015
  • This study was performed to investigate the phyico-chemical characteristics of breast meat from spent hens (SP) in comparison with the same part from the broilers (BR). The moisture and crude protein contents for SP were 72.56% and 24.26%, which were lower than 75.87% and 24.64% for BR. Crude fat and crude ash contents in SP were 0.45% and 1.00%, which were higher than the BR contents of 0.41% and 0.51%. The respective L, a and b value for SP were 48.61, 2.40 and 2.42, which were lower than the BR values of 49.41, 1.45 and 3.06 respectively. The pH for SP was 5.89, which was higher than pH 5.79 for BR. The WHC for SP was 50.29%, which was lower than that of BR at 62.31%. SP scored 28.04% in the heating loss test, which was significantly higher than 19.09% for BR. The shear forces for SP and BR were 4.86 kg and 1.36 kg respectively, which meant that the texture of SP was much tougher than that of BR. Hardness for SP was 8.89 kg while that of BR was 3.92 kg indicating that the SP texture is firmer than that of BR. Oleic acid was most abundant fatty acid in both samples and was at 44.15% in SP and 27.68% in BR.

백미와 현미의 첨가비율을 달리하여 제조한 모닝빵의 품질 특성 (Quality Characteristics of Morning Bread containing with Different Ratios of Rice and Brown Rice Flour)

  • 주신윤;최해연
    • 한국식품영양학회지
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    • 제30권6호
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    • pp.1252-1259
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    • 2017
  • The objective of this study was to examine the effects of rice (R) and brown rice (BR) flour on the quality characteristics of morning bread. The quality characteristics of morning bread were determined by measuring the pH of the dough, dough raising power, moisture content, baking loss rate, specific volume, height, color value, texture analysis and sensory evaluations. The pH of the bread dough was highest on R1:BR2 and R0:BR3. The dough raising power and moisture content steadily and significantly decreased as the amount of added brown rice flour increased. The baking loss rate was highest on R3:BR0. The specific volume and height of morning bread were highest on R3:BR0 and R2:BR1. In color value, the L value decreased significantly as the amount of added brown rice flour increased, while a value and b value increased. The hardness, gumminess and chewiness of morning bread increased with an increase in brown rice flour. In consumer acceptability, R3:BR0, R2:BR1 and R1:BR2 showed the highest scores in all parameters. Characteristic intensity rating of roasted taste was lowest on R3:BR0. These results indicate that R2:BR1 showed similar quality characteristics as compared to morning bread without brown rice flour, with the optimal results appreciated with a 2:1 ratio of rice flour to brown rice flour.