• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2014년도 추계학술대회 논문집
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• pp.43-43
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• 2014

본 연구에서는 AZ31 마그네슘 합금의 부식특성을 살펴보고, AZ31 마그네슘 합금의 내식성을 향상시킬 수 있는 효과적이며 경제적인 표면처리 방법을 모색하였으며, AZ31 마그네슘 합금의 부식이 일어나는 이유 및 부식을 억제하기 위하여 사용가능한 방법에 대하여 토의하고자 한다.

• 천문학회보
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• 제31권2호
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• pp.58.2-58.2
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• 2006

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.194.1-194.1
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• 2016

The present study investigated the effect of zincate treatment time on the dissolution behavior and the deposition of copper by immersion process and electroplating process on AZ31 Mg alloy substrate in a copper pyrophosphate bath. Without zincate pretreatment, the AZ31 Mg substrate quickly dissolved in the copper pyrophosphate solution although an external cathodic current was applied. The copper layers deposited on non-zincate treated AZ31 Mg alloy substrate by both immersion and electroplating processes showed very porous structure and very poor adhesion. With increasing zincate treatment time up to 2 min, the dissolution of AZ31 substrate in pyrophosphate solution rapidly decreased and the deposited copper layer was less porous and exhibited stronger adhesion. The immersion of AZ31 Mg sample in zincate solution for 5 min was found as a critical time for producing a non-porous and adherent electrodeposited copper layer on AZ31 Mg alloy. The optimum zincating time can be determined by observing the open circuit potential (OCP) of AZ31 Mg alloy samples in a copper pyrophosphate electroplating bath. The OCP reached a stable value of about -0.10 V (vs. SCE) after 5 min of immersion in the copper pyrophosphate electroplating solution.

• 한국군사과학기술학회지
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• 제15권3호
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• pp.315-321
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• 2012

In the study, corrosion characteristics of AZ31 magnesium alloy under various environments exposed during machining(immersion in cutting oil, 5 % cutting oil aqueous solution and distilled water & contact with dissimilar metals, SPC4 and A5052-H32) were investigated. A corrosion test was performed AZ31 magnesium alloy was immersed in each electrolyte solution after contacting with each dissimilar metals, and the results were observed by an electron microscope. In immersion tests, corrosion of AZ31 magnesium alloy showed to be in the sequence of distilled water> 5 % cutting oil aqueous solution> cutting oil> air, and in the test of contact with dissimilar metals, corrosion showed to be in the sequence of SPC4> A5052-H32> AZ31. It can be concluded that to prevent corrosion during machining, AZ31 magnesium alloy must prevent contacting water and use magnesium alloy for raw material of Jig & Fixture.

• 한국주조공학회지
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• 제32권2호
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• pp.75-80
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• 2012

In this study, we are aimed to prevent grain growth of semi-solid AZ31 magnesium alloys during reheating process. The semi-solid AZ31+(Ca) billets were investigated by using metallographic analysis, X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy in order to elucidate the effect of Ca addition during reheating process. The grain growth of semi-solid AZ31+(Ca) billet was reduced with increasing Ca content during reheating. The grain size of AZ31+(Ca) billet decreased with increasing volume fraction of Al2Ca particles. The grain growth rate constant K calculated by Oswald ripening LSW theory in AZ31+1.5wt.% Ca billet was the lowest 129.

• 열처리공학회지
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• 제33권2호
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• pp.49-56
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• 2020

Magnesium alloy is a metal with high specific strength and light weight, and is attracting attention as a next generation metal for environmentally friendly automobiles and transportation equipment. However, magnesium alloys have a problem of degrading formability due to the basal texture developed during processing, and their application is limited. Although active researches on the control of textures have been conducted in order to minimize this problem, there is a lack of research on the formation of microstructures and textures according to elemental differences. In this study, AZ61 and AZ80 magnesium alloys were selected to investigate the effects of aluminum addition on the microstructure development of magnesium alloys. This research has proven that the increase of the rolling rate results in the decrease of the average grain size of the two alloys, the increase of the hardness, and the increase of the fraction of twins. As shown on this research below, the basal texture developed strongly as the rolling ratio increased. On the other hand, this research also has proven that the two alloys exhibited different texture strength and distribution tendencies, which could be due to the effects of aluminum addition on work hardening, grain size, and twin behavior.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.281-284
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• 2007

The effect of Ca addition on the microstructure evolution and deformation behavior of AZ31 magnesium alloy produced by hot extrusion was investigated. For this purpose, Ca was added into AZ31 melts to the level of 0.7 and 2.0 wt.% Ca. Then, AZ31 base alloy and Ca modified AZ31 alloys were extruded at $383^{\circ}C$. Ca added alloys showed finer grain size and increased hardness value rather than AZ31 base alloy. After isothermal hot compression, the shape of tested specimen exhibited a noticeable anisotropy due to the crystallographic texture effect. The ratio of major and minor axes of ovality was not directly related to test condition and Ca amount. Flow stress level increases with the increase of Ca addition at temperature below $300^{\circ}C$ because of fine microstructure. However, at high temperature and low strain rate region ($400^{\circ}C$ and $10^{-3}s^{-1}$), reverse tendency was observed since main deformation mechanism changes from dislocation slip to grain boundary sliding or diffusional process at high temperature.

• 소성∙가공
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• 제31권3호
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• pp.117-123
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• 2022

In this study, a commercial AZ61 magnesium alloy is extruded at 300 ℃ and 400 ℃ and the microstructures, mechanical properties, and high-cycle fatigue properties of the extruded materials are investigated. Both extruded materials have a fully recrystallized microstructure with no Mg₁₇Al₁₂ precipitates. The average grain size and maximum basal texture intensity of the extruded material increase with increasing extrusion temperature. The material extruded at 400 ℃ (AZ61-400) has higher tensile yield strength and lower compressive yield strength than the material extruded at 300 ℃ (AZ61-300) because of the stronger basal texture of the former. Because of coarser grain size, the tensile elongation of AZ61-400 is lower than that of AZ61-300. Despite the differences in microstructures and tensile/compressive properties, the two extruded materials have the same fatigue strength of 110 MPa. This is because the finer grain size of AZ61-300 causes an increase in fatigue strength, but its weaker texture causes a decrease in fatigue strength. In both extruded materials, fatigue cracks initiate at the surface of fatigue specimens at all stress amplitudes tested.

• 한국표면공학회지
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• 제55권1호
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• pp.24-31
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• 2022

This study investigated the effect of pre-treatment on the PEO film formation of AZ91 Mg alloy. The pre-treatment was conducted for 10 min at room temperature in 0.5 M oxalic acid (C₂H₂O₄) solution containing various ammonium fluoride (NH₄F) concentrations. The pre-treated AZ91 Mg specimens were anodized at 100 mA/cm² of 300 Hz AC for 2 min in 0.1 M NaOH + 0.4 M Na₂SiO₃ solution. When AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with NH₄F concentration less than 0.3 M, continuous dissolution of the AZ91 Mg alloy occurred together with the formation of black smuts and arc initiation time for PEO film formation was very late. It was noticed that corrosion rate of the AZ91 Mg alloy became faster if small amount of NH₄F concentration, 0.1 M, is added. The fast corrosion is attributable to fast formation of porous fluoride together with porous oxides in the reaction products. On the other hand, when AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with sufficient NH₄F more than 0.3 M, a thin and dense protective film was formed on the AZ91 Mg alloy surface which resulted in faster initiation of arcs and formation of PEO film.

• 한국융합학회논문지
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• 제12권5호
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• pp.17-22
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• 2021

환경 친화적인 마그네슘-공기 전지는 이론적 방전용량이 매우 높은 1차전지로 알려진 금속-공기 전지이며 대기 중 산소를 양극 활물질로 사용하고 마그네슘 합금을 연료로 사용하는 관점에서 금속-연료전지로도 불리고 있다. 음극으로 사용하는 마그네슘합금의 성능에 따라 전지 전체 성능이 결정되므로 고성능 전지로 상용화하기 위해서는 음극 재료인 마그네슘 합금 전극의 성능에 대한 연구와 개선이 필요하다. 본 연구는 상용화된 마그네슘 합금(AZ31, AZ61)을 선택하여 마그네슘-공기 전지용 전극재료로서 가능성을 평가하기 위하여 전기화학적인 측정을 실시하고 방전 특성을 조사하였다. 개방회로전위 변화, Tafel 곡선 변화, 순환전류전압곡선 측정을 통해 마그네슘합금들의 전기화학적 특성을 조사하였고 정전류 방전 실험을 통해 AZ61 합금의 우수한 방전 용량(1410mAhg^-1)과 가능성을 평가하였다.