• Corrosion Science and Technology
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• 제6권2호
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• pp.56-61
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• 2007

Carbide dissolution during heating processes can change chemical composition of martensitic stainless steel in its austenitic phase. Although the austenitizing treatments were carried out at a homogeneous austenite region, the amount of carbon atom in the matrix differs. Increase in the amount of carbon contents in the matrix resulted in decreasing MS temperature, which consequently causes the volume fraction of the retained austenite to increase. This study reveals the effects of the austenitizing treatment on the properties of Fe - 0.3C - 14Cr - 3Mo martensitic stainless steel change with different austenitizing temperatures.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.407-408
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• 2006

Dimensional precision is a critical parameter in net shape processing of ferrous PM components. Sinter-hardening alloys undergo a transformation from austenite to martensite. Martensite formation expands the sintered compact, while tempering hardened steels results in shrinkage. In addition, martensitic regions with high Cu and C contents may contain large amounts of retained austenite. The presence of martensite and retained austenite, in addition to the tempering step, all play a role in the final dimensions of a component. This paper investigates the dimensional and microstructural changes to two sinter-hardening grades through different post-sintering thermal treatments.

• 한국정밀공학회지
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• 제19권10호
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• pp.52-59
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• 2002

The thermo-mechanical characteristics of high temperature NITINOL shape memory alloy were evaluated using DSC with small samples and DMA with three-point bending specimens. The shape memory alloy of 54.4Ni/45.5Ti wt.% was used so that the phase transformation temperatures were in the range of 50~11$0^{\circ}C$. Two types of sample were tested in the experiments corresponding to as-received and annealed conditions. Simple beam bending theory was used to calculate the dynamic moduli of the shape memory alloy. According to the results, a large discrepancy in transformation temperatures was found between DSC and DMA techniques. Annealing treatment was found to suppress the R-phase transformation during cooling and the secondary plateau in the austenite transformation. Such a heat treatment was also significantly influenced to raise the transformation temperatures and the moduli of the shape memory alloy.

• 열처리공학회지
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• 제29권3호
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• pp.103-108
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• 2016

In recent years, TRIP steels which are composed of ferrite, bainite, and retained austenite have drawn much attention for automotive sheets due to excellent combination of strength and ductility. The effect of two-step isothermal heat treatment of bainitic transformation on microstructures, especially retained austenites and tensile properties in the conventional TRIP steel was investigated. A two-step isothermal heat treatment, in which 50% bainitic transformation occurred at high temperature, followed by bainitic transformation at low temperature, improves tensile properties, resulting from enhanced mechanical stability of retained austenite against external plastic deformation due to refinement of retained austenites, compared to single-step isothermal heat treatment.

• 열처리공학회지
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• 제16권1호
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• pp.10-15
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• 2003

In Nb, V and Ti added steels, carbo-nitrides are formed due to their strong interaction with C and N. The formation of carbo-nitrides has an important role to control the microstructure as well as mechanical properties by grain size refinement and precipitation hardening. However, the quantitative analysis of distribution of precipitates and the effect of precipitates on the phase transformation and mechanical properties are still far from satisfactory. In this study, the quantitative analysis of precipitates in austenite was investigated using the fact that the formation of precipitates in Nb, V and Ti added steels accelerates austenite/ferrite transformation. The formation of precipitates was controlled by adjusting holding temperature and time in austenite region, transformed Volume fractions were measured by dilatometer during slow cooling, Iso-precipitation kinetics were determined by comparing 5% and 50% volumes transformed at various conditions respectively. The result was compared with the calculated.

• 한국재료학회지
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• 제25권11호
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• pp.577-582
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• 2015

The present study is concerned with the influence of niobium(Nb) addition and austenitizing temperature on the hardenability of low-carbon boron steels. The steel specimens were austenitized at different temperatures and cooled with different cooling rates using dilatometry; their microstructures and hardness were analyzed to estimate the hardenability. The addition of Nb hardly affected the transformation start and finish temperatures at lower austenitizing temperatures, whereas it significantly decreased the transformation finish temperature at higher austenitizing temperatures. This could be explained by the non-equilibrium segregation mechanism of boron atoms. When the Nb-added boron steel specimens were austenitized at higher temperatures, it is possible that Nb and carbon atoms present in the austenite phase retarded the diffusion of carbon towards the austenite grain boundaries during cooling due to the formation of NbC precipitate and Nb-C clusters, thus preventing the precipitation of $M_{23}(C,B)_6$ along the austenite grain boundaries and thereby improving the hardenability of the boron steels. As a result, because it considerably decreases the transformation finish temperature and prohibits the nucleation of proeutectoid ferrite even at the slow cooling rate of $3^{\circ}C/s$, irrespective of the austenitizing temperature, the addition of 0.05 wt.% Nb had nearly the same hardenability-enhancing effect as did the addition of 0.2 wt.% Mo.

• 열처리공학회지
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• 제16권4호
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• pp.205-210
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• 2003

Various types of high strength steel sheets were usually used for improving the automobile safety and fuel efficiency by reducing the vehicle weight. The present study aimed to develop the TRIP (transformation induced plasticity) aided high-strength low carbon steel sheets by using a reverse transformation process. The 0.1C-4~8Mn steels were reverse-transformed by slow heating to intercritical temperature region and then furnace cooled to the room temperature. Granular type retained austenite was observed in 4Mn steel and lath type retained austenite was also observed in 6~8Mn steel. The results show that the 6Mn steel under reverse transformed at $625^{\circ}C$ for 6 hrs has maximum elongation up to 39%. The optimum strength-elongation combination was 3,888 ($kg/mm^2{\times}%$) when the 8Mn steel was reverse transformed at $625^{\circ}C$ for 12 h.

• Archives of Metallurgy and Materials
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• 제65권4호
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• pp.1249-1254
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• 2020

The effect of TiC content on the microstructure and mechanical properties of a nanocrystalline Fe-Mn alloy was investigated by XRD analysis, TEM observation, and mechanical tests. A sintered Fe-Mn alloy sample with nano-sized crystallites was obtained using spark plasma sintering. Crystallite size, which is used as a hardening mechanism, was measured by X-ray diffraction peak analysis. It was observed that the addition of TiC influenced the average size of crystallites, resulting in a change in austenite stability. Thus, the volume fraction of austenite at room temperature after the sintering process was also modified by the TiC addition. The martensite transformation during cooling was suppressed by adding TiC, which lowered the martensite start temperature. The plastic behavior and the strain-induced martensite kinetics formed during plastic deformation are discussed with compressive stress-strain curves and numerical analysis for the transformation kinetics.

• 한국재료학회지
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• 제26권11호
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• pp.583-589
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• 2016

In this study, recrystallization behaviors in the two-phase (${\alpha}+{\gamma}$) region of micro-alloyed steels such as Base, Nb, TiNbV and CAlN were investigated in terms of flow stress, microstructure and associated grain boundary characteristics. The flow stress of all specimens reached peak stress and gradually decreased, which means that recrystallization or recovery of proeutectoid deformed ferrite and recovery or transformation to ferrite of deformed austenite occurred by thermal activation. The precipitation of carbide or nitride via the addition of micro-alloying elements, because it reduced prior austenite grain size upon austenitization, promoted transformation of austenite to ferrite and increased flow stress. The strain-induced precipitation under deformation in the two-phase region, on the other hand, increased the flow stress when the micro-alloying elements were dissolved during austenitization. The recrystallization of the Nb specimen was more effectively retarded than that of the TiNbV specimen during deformation in the two-phase region.

• Journal of Welding and Joining
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• 제24권1호
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• pp.77-87
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• 2006

Considering ferrite grain size in the base metal, the prediction model for $A_{c3}$ temperature and prior austenite grain size at just above $A_{c3}$ temperature was proposed. In order to predict $A_{c3}$ temperature, the Avrami equation was modified with the variation of ferrite grain size, and its kinetic parameters were measured from non-isothermal data during continuous heating. From calculation using a proposed model, $A_{c3}$ temperatures increased with increasing ferrite grain size and heating rate. Meanwhile, by converting the phase transformation kinetic model that predicts the ferrite grain size from austenite grain size during cooling, a prediction model for prior austenite grain size at just above the $A_{c3}$ temperature during heating was developed.