• 한국표면공학회지
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• 제53권1호
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• pp.36-42
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• 2020

In this study, two novel methods to measure the surface hardness of anodic oxide films on aluminum alloys are reported. The first method is to impregnate oil-based ink into pores in the anodic oxide film and then to clean the ink on the surface using ethanol, resulting in an impregnation of inks only inside of the pores in anodic oxide film. The second method is to coat the anodic oxide film surface with thin Au layer less than 0.1 ?. Both the ink-impregnating method and Au-coating method provided clear indentation marks on the anodic oxide film surface when it was indented using a pyramidal-diamond penetrator. Thus, Vickers hardness of anodic oxide films on aluminium alloy could be measured successfully and precisely from the anodic film surface. In addition, advantages and disadvantages of the ink-impregnating method and Au-coating method for the measurement of surface hardness of anodic oxide films are discussed.

• 한국광학회지
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• 제19권6호
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• pp.416-421
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• 2008

본 논문에서는 복수 개의 측정 광파장 대역에서의 글루코스 수용액의 상대적인 흡광 특성을 이용한 글루코스 농도 예측 방법을 제안하고 검증하였다. 각 측정 파장에서의 상대적인 흡광도는 기준 파장에서의 흡광도를 기준하여 얻어진다. 선정된 기준 파장(1310 nm)과 네 개의 측정 파장(1064, 1550, 1685, 1798 nm) 대역에서는 글루코스에 대한 흡광도가 서로 반대의 부호를 갖도록 하였으며, 이 특성은 측정 정확도를 높이는데 도움이 된다. 최종적인 글루코스 수용액의 예측 농도는 각 측정 파장에서 얻어진 예측 값의 평균으로 결정된다. 5 mm의 광경로와 $0{\sim}1000mg/dL$ 농도 범위에서 실제로 측정된 글루코스의 흡광도를 살펴보면, 기준 파장 1310 nm에서는 $-1.42{\times}10^{-6}\;AU$/(mg/dL), 측정 파장 1685 nm에서는 $+8.12{\times}10^{-6}\;AU$/(mg/dL)로 최대였다. 그리고 제안된 방법을 이용하여 글루코스 용액의 농도를 예측할 경우 얻어진 표준예측오차(SEP: standard error of prediction)는 ${\sim}28\;mg/dL$였다. 또한, 온도와 지방층이 글루코스 농도 측정에 미치는 영향을 조사하였다. 먼저 $26{\sim}40^{\circ}C$ 온도 범위에서 측정된 흡수량 변화율은 기준 파장 1310 nm에서 $-9.1{\times}10^{-5}\;AU/^{\circ}C$였고, 측정 파장 1550 nm에서 $-2.08{\times}10^{-2}\;AU/^{\circ}C$였다. 그리고 글루코스 수용액에 존재하는 지방층 두께에 따른 흡수량 변화율은 1685 nm 파장 대역에서 +1.093 AU/mm로 측정되었다.

• 한국산학기술학회논문지
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• 제18권11호
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• pp.88-93
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• 2017

다양한 응용분야를 가진 국부적인 표면플라즈몬 공명 특성을 손쉽게 제어할 수 있는 기술 개발은 매우 중요하다. 또한, 금속 나노입자의 형태, 크기, 그리고 조합에 관한 세심한 조사는 공명특성과 금속 나노구조의 관계를 이해하는데 매우 유용하다. 본 논문은 블록공중합체 마이셀 박막필름으로부터 얻어진 금속나노입자 배열에 따른 국부적인 표면플라즈몬의 공명특성에 관한 연구이다. 우선 전통적인 방법의 블록공중합체 리소그라피를 통해 두 가지 다른, 점 형태 및 링 형태, 금 나노입자를 제조하였다. 그 다음 은거울 반응을 통하여 금 나노입자위에 은이 둘러 쌓이도록 금/은 이중금속 나노구조를 구현했다. 금속 나노 구조체 조절을 위해 에탄올 전처리, 은거울 반응 시간, 블록공중합체의 제거 유무 등의 공정변수를 변화시켰다. 초기 금 나노입자가 잘 제조된 경우 항상 금나노입자 표면에 적절히 은이 잘 형성되었고, 이는 UV-Vis 실험에서 각 금속나노 입자의 고유 플라즈몬 밴드인 금 525nm, 은 420nm에서 각각 나타났다. 하지만 최초 적은 양의 금 나노입자가 제조되었을 경우 은 도금 속도가 빨라져서, 초기 금 나노입자의 표면을 은이 완전히 덮었으며, 이는 UV-Vis 실험에서 금의 플라즈몬 밴드는 나타나지 않고, 은의 고유 플라즈몬 밴드만 420nm에서 나타났다. 블록공중합체로부터 미리 합성된 금나노입자 위에 은을 도금하는 방법은 국부적인 표면플라즈몬 특성을 면밀히 조사하는데 매우 유용하다.

• 한국공간구조학회논문집
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• 제18권3호
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• pp.57-66
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• 2018

Recently various composite beams in which concrete is filled in the U-shaped steel plate have been developed for saving story height and reducing construction period. Due to the high flexural stiffness and strength, they are widely being used for the building with large loads and long spans. The semi-slim AU composite beam has proven to take highly improved stability compared to the existing composite beams, because it consists of the closed steel section by attaching cap-type shear connectors to the upper side of U-shaped steel plate. In this study the finite element analyses were performed to evaluate the safety of the AU composite beam with unconsolidated concrete which were sustained through the closed steel section during the construction phase. The analyses were performed on the two types of cross section applied to the fabrication of AU composite beams, and the results were compared to the those of 2-point bending tests. In addition, the flexural performance according to the space of intermittent cap-type shear connectors and the location of reinforcing steel bars for compression was comparatively investigated. Through the results of analytical studies, it is preferable to adopt the yield moment of AU composite beam for evaluating the safety in the construction phase, and to limit the space of intermittent shear connectors to 400 mm or less for the construction load.

• 한국산학기술학회논문지
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• 제19권3호
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• pp.130-140
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• 2018

U형 강재보를 근간으로 콘크리트 슬래브와 합성을 위하여 A형의 덮개형 강재앵커를 검토하여 AU합성보를 연구하였다. 이는 노출형의 H형강 강재보에 비해 내부 평면의 자율성을 높일 수 있고 공기 단축과 더불어 층고 절감이 가능하며 튜브구조로서 내부에 콘크리틀 충전하여 휨 강도과 휨 강성를 높였다. 본 연구에서는 AU합성보의 휨실험을 통해 성능을 평가하였다. 실험 결과, 하중 초기에 선형적으로 하중이 증가하면서 콘크리트 슬래브의 파괴에 의해 최대 강도에 도달하고 최대 내력의 85% 이상을 발휘하며 연성적 거동을 하였다. 또한, 덮개형 강재앵커를 통해 합성효과를 발휘하였으며 모든 실험체가 최대 내력에 도달할 때까지 완전 합성거동으로 안정적이었다. 그리고 U형 단면의 강판 두께를 증가시켰을 경우에도 휨 강도와 휨 강성이 증가하였고, U형 단면의 하부에 고강도 강판을 용접 부착하였을 경우에도 성능이 개선되었다. AU합성보의 휨강도는 건축구조기준에 따라 제안된 휨 강도식을 적용할 수 있을 것으로 판단되었다.

• Journal of Magnetics
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• 제11권1호
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• pp.36-42
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• 2006

In this report, we demonstrate a comprehensive analysis of the effects of Au addition on the microstructure and magnetic properties of $Fe_{73.5}Si_{13.5}B_{9}Nb_{3}Au_1$ Finemet-type alloy. It was found that the as-quenched alloys were the amorphous state and turned into nanocrystalline state under heat treatments. The DSC analysis indicates that the sharply exothermal peak corresponding to the crystallization of the $\alpha-Fe(Si)$ was observed at $547-579^{\circ}C$ depending on the heating rates, which is little higher than that of original Finemet (542-$570{^{\circ}C}$, respectively). Besides, the thermomagnetic result confirmed that the full substitution of Cu by Au with the single phase structure in the M(T) curve along cooling cycle. Ultrasoft magnetic properties of the nanocrystallized samples were significantly enhanced by the proper annealing such as the increase of permeability and the decrease of the coercivity. The optimum annealing condition was found at the annealing temperature of $540^{\circ}C$ and the increase of the annealing time up to 90 min.

• Bulletin of the Korean Chemical Society
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• 제29권6호
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• pp.1229-1232
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• 2008

The surface structure, electrochemical behavior, and wetting property of self-assembled monolayers (SAMs) formed by dioctyl diselenide (DODSe) on Au(111) were investigated by scanning tunneling microscopy (STM), cyclic voltammetry (CV), and contact angle measurements. In contrast to the formation of well-ordered SAMs by octanethiol on Au(111), the SAMs formed by DODSe have a disordered phase and many unusual vacancy islands (VIs). In addition, the formation of DODSe SAMs is largely influenced by the solution concentration used. DODSe SAMs formed in 5 $\mu$ M and 50 $\mu$ M solutions have two mixed domains consisting of missing-row ordered phases and disordered phases, while DODSe SAMs formed in 1 mM and 5 mM solutions have only disordered phases with an abnormally high VI fraction of 22-24%. We also found that the wetting property and electrochemical behavior of DODSe SAMs on Au(111) are markedly influenced by the formation of ordered SAMs and the density of VIs.

• 한국전기전자재료학회논문지
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• 제18권7호
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• pp.622-627
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• 2005

In this study, electrical properties of self-assembled dipyridinium dithioacetate molecule onto the Au(111) substrate is observed using Scanning Tunneling Microscopy(STM) by vortical structure of STM probe. At first, the Au(111) substrate is cleaned by piranha solution$(H_2SO_4:H_2O_2\;=\;3:1)$. Subsequently, 1 mM/ml of dipyridinium dithioacetate molecule is self-assembled onto the Au(111) surface. Using STM, the images of dipyridinium dithioacetate molecule which is self-assembled onto the Au(111) substrate, can be observed. In addition, the electrical properties(I-V) of dipyridinium dithioacetate can also be examined by using Scanning Tunneling Spectroscopy(STS). From the results of the measurement of the current-voltage(I-V), the property of Negative Differential Resistance(NDR) that shows the decreases of current according to the increases of voltage is observed. We found the NDR voltage of the dipyridinium dithioacetate is -1.42 V(negative region) and 1.30 V(positive region), respectively.

• Bulletin of the Korean Chemical Society
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• 제33권4호
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• pp.1128-1134
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• 2012

We investigated a new method for patterning organic field-effect transistors (OFETs) using a photopatternable conducting polymer nanocomposite, consisting of poly(3-hexylthiophene) (P3HT)-coated gold nanoparticles (AuNPs) that had been modified with a photoreactive cinnamate group, to form P3HT-AuNP-CI. We found that the addition of the cinnamate group to the nanoparticle surface assisted the preparation of a solvent-resistive semiconducting film and preserved the P3HT ordering, which was interrupted by Au-P3HT interactions, as well as provided UV-controllable electrical properties. The P3HT-AuNPs-CI films could be microscale-patterned via a UV crosslinking photoreaction, represented as a promising photopatternable semiconductor material for use in advanced applications, with tunable electrical properties for fabrication of sub-micron and microscale electronic devices.

• Journal of Korean Vacuum Science & Technology
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• 제6권3호
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• pp.133-138
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• 2002

The growth of Au films grown on a Si(100)-2x1 surface and Si films on a Ge(100)-2x1 substrate is studied using Positron-annihilation induced Auger Electron Spectroscopy(PAES), Electron induced Auger Electron Spectroscopy(EAES), and Low Energy Electron Diffraction(LEED). Previous work has shown that PAES is almost exclusively sensitive to the top-most atomic layer due to the trapping of positrons in an image potential well just outside the surface before annihilation. This surface specificity is exploited to profile the surface atomic concentrations during the growth of Au on Si(100) and Si on Ge(100) and EAES provides concentrations averaged over the top 3-10 atomic layers simultaneously. The difference in the probe-depth makes us possible to use PAES and EAES in a complementary fashion to estimate the surface and near surface concentration profiles. The results show that (i) the intermixing of Au and Si atoms occurs during the room temperature deposition, (ii) the segregated Ge layer is observed onto the Si layers deposited at 300k. In addition, the prior adsorption of hydrogen prevents the segregation of Ge on top of the deposited Si and that the hydrogen adsorption is useful in growing a thermally stable structure.