• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.6
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• pp.558-561
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• 2004

The morphology of silica supported $MoO_{3}$ catalysts, which was prepared by impregnation of ammonium heptamolybdate(AHM) with various surface loadings up to 4 atoms $Mo/nm^{2}$, was studied using x-ray diffraction(XRD). All morphologies of silica supported $MoO_{3}$ appear to be thermodynamically driven. For high loaded catalysts there appeared three states: a sintered and well-dispersed hexagonal state at moderate temperature calcination($300^{\circ}C$), and a sintered orthorhombic state at high temperature calcination($500^{\circ}C$). Whereas the sintered orthorhombic phase is detected by XRD at loadings in excess of 1.1 atom $Mo/nm^{2}$, the well-dispersed hexagonal phase is not detected even until 4.0 $atomsMo/nm^{2}$. The higher apparent dispersion of the hexagonal phase may arise from some role of ammonia which results in a stronger $MoO_{3}-SiO_{2}$ surface interaction.

• Korean Journal of Crystallography
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• v.7 no.1
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• pp.81-87
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• 1996

The mechanism of silicon incorporation has been analyzed for the boat-grown GaAs crystals on the basis of phase equilibrium in the Ga and As system. Comparison was made between silicon concentrations calculated from the thermodynamics of incorporation reaction and carrier concentrations measured from van der Pauw method. For the 1-T HB(single temperature zone horizontal Bridgman) crystals, calculated concentrations were 5.3 ×10 15 (atoms/cm3), measured as 9.8 ×10 15(/cm3) at the seed part. They were calculated to be 1.1 ×10 16(atoms/cm3) and measured as 1.5 ×10 16(/cm3) for the 2-T(double temperature zone) HB crystals. On the other hand, it was found to be closer between the calculated and measured silicon concentrations for the VGF(vertical gradient freeze) crystals, which were grown within half the run time compared with 1-T or 2-T HB method.

• Nuclear industry
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• v.37 no.7
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• pp.79-82
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• 2017

군사적인 공격을 하지 않는다는 약속과 함께 핵무기와 미사일을 개발하지 않는 조건으로 원전을 통한 전력 생산에 도움을 주겠다고 약속하는 것이 북한이 이웃나라에 대한 핵 위협을 중단할 수 있는 명분을 제공하고, 미사일이나 그 밖에 교역이 금지된 군수품의 수출을 중단하는 데 대한 확실한 보상책이 될 수 있을 것이다. 건설적 개입이야말로 한반도에 평화를 정착시키고 나아가 북한 인민들에게 자유를 가져다주는 데 결정적인 정책이다. 트럼프 대통령에게는 북한과 'Atoms for Peace' 협상의 물꼬를 트는 과정에서 핵전쟁의 위협을 줄임으로써 인류애를 실현시킬 수도 있는 기회가 있다. CIA는 현재 30개 이상의 나라가 핵무기를 개발할 수 있는 기술적인 능력을 보유하고 있다고 추정하고 있는데, 그 가운데 단지 9개 나라만 핵무기를 개발할 수 있게 허용되어 있다. 요컨대 70년이 넘는 세월 동안 핵능력을 보유한 나라들이 핵무기를 실전에 사용하지 않는 데 성공한 것이다. 따라서 지금 우리에게 가장 필요한 것은 'Atoms for Peace'라는 정책 비전을 한반도 문제의 해결 방식에 적용하는 한편 계속 확대시켜 나가는 것이다.

• Bulletin of the Korean Chemical Society
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• v.25 no.4
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• pp.452-459
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• 2004

The geometrical structures of various isomers of hexafluoro-1,3-butadiene (HFBD), tetrafluoro-1,3-butadiene (TFBD), and difluoro-1,3-butadiene (DFBD) have been studied theoretically. Natural steric and natural resonance theory (NRT) analyses indicate that the lower energy of skew s-cis conformer of hexafluoro-1,3-butadiene than that of the s-trans conformer is originated from the strong steric repulsions between fluorine atoms particularly in the s-trans conformer. The resonance structures generated by NRT also show that the lone electron pairs of fluorine atoms effectively extend the conjugation, and the large differences in energy among the structural isomers of tetrafluoro-1,3-butadiene and difluoro-1,3-butadiene are in part attributed to the differences in the delocalization energies, in addition to the steric repulsion between fluorine atoms. Other interatomic interactions, such as hydrogen bonding, also play important roles in determination of the structures of isomers of tetrafluoro-1,3-butadiene and difluoro-1,3-butadiene.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.5
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• pp.211-216
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• 2003

The $Cu[SO_3(CH_2)_4SO_3$］ㆍ$4H_2O$ compound was synthesized. The three-dimensional structure of $Cu[SO_3(CH_2)_4SO_3$］ㆍ$4H_2O$ compound was determined. The copper atom is bridged by 4 oxygen atoms of 4 water molecules and 2 oxygen atoms of butanedisulfonate. The butyl chain in the plane of four copper atoms is oriented parallel and perpendicular to the one of plane axis, alternatively. Magnetic data indicate that this compound behaves a typical paramagnetic.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.127-129
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• 1997

The high pretilt angles in nematic liquid crystals (NLCs) have been generated on robbed polythiophene (PTP) surfaces with alkyl chain lengths. The pretilt angle of the NLC was observed on unidirectionally rubbed PTP surfaces with alkyl chains with more than 9 carbon atoms. We obtained the Pretilt angle of 15~40$^{\circ}$ on rubbed PTP surfaces with 10 carbon atoms in the a1ky1 chain. Also, the pretilt angles of 65~80$^{\circ}$ of NLC were obtained on rubbed PTP surfaces with 11 and 12 carbon atoms in the alkyl chain. We suggest that this high pretilt angle generation in NLC is due to the surface-excluded volume effect by the alkyl chain lengths between. the LCs and the PTP surfaces. Finally, we conclude the odd-even effect on rubbed PTP surfaces is clearly contributed to the pretilt angle generation.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.11 no.4
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• pp.160-165
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• 2001

The effects of various metals on Field Aided Lateral Crystallization (FALC) behaviors of amorphous silicon (a-Si) were investigated. Under an influence of electric field, metals such s Cu, Ni and Co were found to fasten the lateral crystallization toward a metal-free region, exhibiting a typical FALC behavior while the lateral crystallization of a-Si was not obvious for Pd. However, Au, Al and Cr did not induce the lateral crystallization of a-Si in metal-free region. Such phenomenological differences in various metals were studied in terms of dominant diffusing species (DDS) in the reaction between metal and Si. It was judged that the applied electric field enhanced the crystallization velocity by accelerating the diffusion of metal atoms since the occurrence of lateral crystallization would be strongly dependent on the diffusion of metal atoms than that of Si atoms. Therefore, it was concluded that he only metal-dominant diffusing species in the reaction between metal and Si results in the crystallization of a-Si in metal-free region.

• Proceedings of the Korean Magnestics Society Conference
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• 2009.12a
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• pp.74-75
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• 2009

First-principles calculations were carried out to investigate the crystal stability and magnetism of $Fe_{16}C_2$ and $Fe_{16}C_2$. Our precise calculations show that the structure of high carbon phase is $Fe_{16}C_2$ and this structure is more stable in the ferromagnetic state than the nonmagnetic state. The Fe atoms induced negative magnetic moment at the C atoms, which interact with the nearest Fe atoms.

• Bulletin of the Korean Chemical Society
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• v.28 no.3
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• pp.421-426
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• 2007

A linking ligand containing sulfur donor atoms in the terminal thiophene rings, 1,2-bis(thiophen-2-ylmethylene) hydrazine (L), was prepared by Schiff-base condensation. Ligand L reacted with [PdCl2(NCPh)2] to produce a molecular Pd compound [PdL2Cl2] (1). On the other hand, it reacted with AgNO3 and AgClO4 to produce a 2-D network [AgL0.5(NO3)] (2) and a 1-D polymer [AgL]ClO4 (3), respectively, whose structures are based on secondary intermolecular forces such as H-bonding, van der Waals interaction, and π-π stacking. Polymer 2 exhibited photoluminescence at room temperature in the solid state.

• Proceedings of the Optical Society of Korea Conference
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• 2000.02a
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• pp.126-127
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• 2000

Resonance fluorescence is the manifestation of the interaction between the physical system under consideration and the vacuum-field fluctuation. The fluorescence spectrum provides such physical informations as the energy-level structure of the system, instabilities and relative populations of the energy levels, etc.. One of the typical fluorescence spectra is the Mollow triplet appearing when two-level atoms are driven by a strong coherent field in free space$^{(1)}$ . In the weak field limit, the singlet instead of the triplet is obtained with a reduced linewidth due to the squeezing of one quadrature phase of the induced atomic dipole$^{(2)}$ . On the other hand, when the atoms are put inside a cavity rather than in free space, a doublet spectrum due to the vacuum Rabi-splitting is achieved, showing clearly the coupling of atoms and the cavity in the single-quantum limit$^{(3)}$ . (omitted)