• Title/Summary/Keyword: Atmospheric pollutants concentration

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Atmospheric Concentration of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Suspended Particulate (大氣浮遊粉塵中 多環芳香族炭火水素 및 重金屬의 濃度)

  • 손동헌;권창호;정원태;허문영
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.17-22
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    • 1991
  • Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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An Investigation of Flow and Pollutant Dispersion in Three-Dimensional Asymmetric Street Canyons Using a CFD Model (CFD 모형을 이용한 3차원 비대칭 도로 협곡에서의 흐름 및 오염물질 분산 연구)

  • Park, Seung-Bu;Baik, Jong-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.214-224
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    • 2007
  • A three-dimensional computational fluid dynamics (CFD) model with the renormalization group (RNG) $k-{\varepsilon}$ turbulence model is used to examine the effects of difference in building height on flow and pollutant dispersion in asymmetric street canyons. Three numerical experiments with different street canyons formed by two isolated buildings are performed. In the experiment with equal building height, a portal vortex is formed in the street canyon and a typical recirculation zone is formed behind the downwind building. In the experiment with the downwind building being higher than the upwind building, the ambient flow comes into the street canyon at the front of the downwind building and incoming flow diverges strongly in the street canyon. Hence, pollutants released therein are strongly dispersed through the lateral sides of the street canyon. In the experiment with the upwind building being higher than the downwind building, a large recirculation zone is formed behind the upwind building, which is disturbed by the downwind building. Pollutants are weakly dispersed from the street canyon and the residue concentration ratio is largest among the three experiments. This study shows that the difference in upwind and downwind building height significantly influences flow and pollutant dispersion in and around the street canyon.

Comparison of the Concentration of Ambient Volatile Organic Compounds at an Ulsan Industrial Site in 1997 and 1998 (울산 공단 대기에서 측정한 휘발성 유기화합물의 1997년과 1998년 결과 비교)

  • 나광삼;김용표;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.567-574
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    • 1999
  • Volatile organic Compounds(VOC) were measured at an industrial site in Ulsan in 1997 and 1998. Twenty-four hour integrated ambient air samples were collected in 6 L SUMMA canisters during the periods of June 3 to 8, 1997 and June 12 to 17, 1998. The daily mean concentrations of the total $C_2-C_9$ VOC in 1998 were about one third of those in 1997. This decrease of VOC levels may be attributable to the measures to control the emissions of VOC and the decrease of the plant operation. The decrease in the concentrations of oxygenated hydrocarbons and alkenes, especially, contributed to the decrease of the total VOC concentrations in 1998. Lowever concentrations of alkenes compared to aromatics in 1998 were due to the decrease of ethylene and propylene. In the present study, methanol (12.0 ppb) was the most abundant species, followed by acetone (10.1 ppb), propane (6.0 ppb), and vinyl chloride (5.9 ppb). The total concentrations of hazardous air pollutants (HAPs) in 1998 were reduced compared to those in 1997. However, this decrease is due to the drastic decrease of the concentration of methanol. Except methanol, the concentrations of HAPs have not varied much. It is suspected that the VOC control strategy for the Ulsan industrial area has been successful for reducing the total VOC levels but might not be effective in reducing the concentrations of HAPs.

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On the Origin of Visibility Degradation in Seoul (서울지역의 시정 장애 요인에 관한 연구)

  • 윤순창;이강웅
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.3
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    • pp.229-236
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    • 1998
  • Visibility is a good indicator of comprehensive alto quality. The prevailing visibility in Seoul is no better than the past although the average concentration of SO2 and TSP (total suspended particulate) has decreased quite significantly in the past decade, owing to the government efforts to reduce the emission. Then, a question arises why visibility has not been improved. In order to answer this question we have investigated which components of air pollutants are most responsible for the visibility degradation in Seoul. Analysis on the visibility vs the aerosol sixte distribution measured by an optical particle counter shows that the particles of the size interval between 0.5mm and 2.5mm are most responsible for the visibility degradation. Among the criteria air Pollutants, NOB concentration is found to be moot responsible, rather than PM10. ton analysis of the particulate collected by a high volume sampler shows that the nitrate component increases more significantly than other ions when visibility becomes very poor. Therefore, we conclude that the major causes of visibility degradation in Seoul are the increase of NOB, nitrates and the particles of the size range between 0.5mm and 2.5mm.

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Measurements of Gaseous Pollutants in Major Tunnels in Seoul (서울시 주요 터널내 기체상 오염물질 농도 측정)

  • 김영성;경남호;손재익;문길주;김용표;백남준;김태오
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.4
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    • pp.320-328
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    • 1993
  • Gaseous pollutants in Namsan Nos. 1, 2, and 3 tunnels and Pukak tunnel were measured along the road by an air-monitoring van from the evening of February 9 to the morning of February 12 in 1993. Average concentrations of pollutants in Namsan tunnels were 9.2-13.5 ppm CO and 0.037-0.047 ppm SO$_{2}$. Average concentrations of SO$_{2}$ in Pukak tunnel was 0.79 ppm, higher than those in Namsan tunnels, due to the traffic of heavy-duty buses and trucks. The pollutant concentrations in Namsan tunnesl could be explained by emission of passenger cars using unleaded gasolin and LPG taxies. Average concentration of NO$_{x}$ in Namsan tunnels was at least 1.1 ppm, estimated from the emission factor of pasenger cars using unleaded gasoline. Pollutant concentrations in Namsan No. 3 tunnel were higher at the exit because of the piston action of air mass in the tunnel provided by the traffic. Fans installed at Namsan and Pukak tunnes could be useful, but their flushing action of ambient air in the tunnel was not clearly observed.d.

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Evaluation of Air Quality with and without Vapor Recovery Systems of Stage II (주유소 Stage II의 유증기회수설비 가동에 따른 대기질 평가)

  • Kim, Jae Hyuck;Jung, Seok Hyeon;Kim, Hyung-Seok;Jang, Tae-Hyuk;Yoo, Kyung Seun
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.801-810
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    • 2013
  • A field study was conducted to evaluate air quality from gas stations with and without Stage II vapor recovery systems that are currently used to reduce VOCs. The THC and VOCs levels were monitored for the test at three locations (inside office, around refueling area, site boundary) from a total of five gas stations. The results showed a considerable reduction in THC concentration which ranged from 48.7% to 81.8% with and without the operation of the Stage II VRS. Acoording to our comparative analysis, BTEX and other 19 VOCs levels were also significantly reduced with Stage II vapor recovery systems.

Modeling Study on Dispersion and Scavenging of Traffic Pollutants at the Location Near a Busy Road

  • Ma, Chang-Jin
    • Asian Journal of Atmospheric Environment
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    • v.9 no.4
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    • pp.272-279
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    • 2015
  • The information about the dispersion and scavenging of traffic-related pollutants at the locations near busy expressways is very helpful to highway planners for developing better plans to reduce exposures to air pollution for people living as well as children attending schools and child care centers near roadways. The objective of the current study was to give information in the dispersion and scavenging of vehicle-derived pollutants at the region near a busy urban expressway by a combination of two different model calculations. The modified Gaussian dispersion model and the Lagrange type below-cloud scavenging model were applied to evaluate $NO_x$ dispersion and DEP (Diesel exhaust particles) wet removal, respectively. The highest $NO_x$ was marked 53.17 ppb within 20-30 meters from the target urban expressway during the heaviest traffic hours (08:00AM-09:00AM) and it was 2.8 times higher than that of really measured at a nearby ambient measuring station. The calculated DEP concentration in size-resolved raindrops showed a continuous decreasing with increasing raindrop size. Especially, a noticeable decrease was found between 0.2 mm and 1.0 mm raindrop diameter.

The Need for QA/QC in the Measurements of Airborne Pollutants - Conduction of and Directions towards an Interlaboratory Comparison Test in 1998 by the Measurement and Analysis Division of KOSAE (대기오염측정에 대한 정도관리의 필요성 - 1998년도 한국대기환경학회 측정분석분과회의 실험실간 비교분석사업 시행과 전개방향)

  • 김기현;이강웅;김조천;서영화;이종해;허귀석
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.1
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    • pp.63-69
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    • 1999
  • To offer a general guideline for the quantitative analysis of airborne pollutants, we designed and conducted a comprehensive QA/QC test using two different strategic approaches, namely (1) field-based comparative measurement and (2) laboratory-based comparative analysis. The former task was performed to make meaningful comparison of combined errors occurring from both sampling and analytical techniques in the measurements of such components as: (1) criteria pollutants, (2) volatile organic compounds (VOCs), and (3) particulate matters with the associated metals and ions. The latter task was also conducted to compare various types of bias arising mainly from the laboratory analytical procedures of (1) gaseous standards of VOCs and (2) of aqueous standards of metals and ions. The concentration data derived from each of these two different types of major tasks were evaluated per chemical species categorized as above. While the very details of these studies are to be reported on an individual basis according to the above classification of the project, this paper is presented to provide an overview of the whole project - its aim and direction.

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Aircraft Measurement of SO$_2$, NO$_{x}$ over Yellow Sea Area (항공기를 이용한 서해안에서의 SO$_2$ 및 NO$_{x}$의 측정)

  • 김병곤;차준석;한진석;박일수;김정수;나진균;최덕일;안준영;강창국
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.5
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    • pp.361-369
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    • 1997
  • In order to investigate the abundance and transboundary fluxes of air pollutants over the Yellow Sea, airborne measurements were made aboard the SF-600 aircraft (Pan-Asia Engineering) in March, 1996. The data presented in this paper are preliminary results and airborne experiment will be carried out until 1999. The vertical profile of relevant meteorological parameters such as temperature, water vapor, wind direction and wind speed were also observed at Taean. Mixing layer height was about 1000~1100m during the flights. The SO$_2$ and NO$_{x}$ concentrations were 3~6 ppb and 5~7 ppb below 1000 m, within 1 ppb and 3~5 ppb at 1000~2000m, respectively. Backward trajectory analyses were also carried out. A mathematical method by Lelieveld et al.(1989) was used to estimate the flux of air pollutants through the planetary boundary layer of Yellow Sea area. Transboundary fluxes were calculated using the measurement results with respect to the pollutants concentration, depth of the planetary boundary layer, wind speed and wind direction. The estimated transboundary flux of SO$_2$through the western boundary of Korea was about 39~42 tons/hour.r.

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Analysis of High Concentration Diffusion Pattern by Air Pollutions in Port Industry Interfaces

  • Je-Ho Hwang;Sang-Hyung Park;So-Hyun Yun;Si-Hyun Kim
    • Journal of Korea Trade
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    • v.26 no.3
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    • pp.117-136
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    • 2022
  • Purpose - Port is vital for international trade accounting for approximately 80% of world cargo transportation in the global trade sector. Air pollutants emitted owing to the related industry interfaces developed around the port spread throughout the dense population region can have harmful effects on the nearby residents. This study aims to analyze high-concentration diffusion pattern by air pollutants, considering the main management periods by air pollutants. Design/methodology - Employing the concentration criteria per main air pollutant, the analyses of concentration change patterns per air pollutant, wind characteristics that directly affected the air pollutant diffusion, distribution types per air pollutant, and high-concentration diffusion patterns by season according to time changes were conducted. Findings - The substances that caused harmful levels of air pollution in the hinterland living zone of the Busan New Port were PM_10, PM_2.5, and NO_2. Furthermore, the intensive management periods were as follows: For PM_10, 24-h (spring), 12:00-16:00 (summer), 12:00-16:00 (summer), 20:00-12:00 (fall), and 24:00-20:00 (winter), and for PM_2.5, 24-h (all four seasons), and for NO_2, 23:00-04:00 (spring), 23:00-08:00 (summer), and 20:00-08:00 (fall), and 23:00-04:00 (winter). Originality/value - Research finding indicates that regular monitoring and countermeasures to reduce air pollution for each air pollutant makes it possible to achieve effective air quality control in the port and hinterland living zones.