• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.380-381
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• 2002

한반도를 위시한 동북아 지역은 급속한 산업 및 경제적 활동 증가로 세계의 주요 오염지역으로 대두되고 있다. 대기오염물질의 이동확산은 어느 특정지역에서 광범위하게 확산되기 때문에 이에 따른 오염과 피해 사이에 시간과 공간적인 차이가 존재하고 있으며 인과관계도 불명확한 상황이다. 매년 봄 한반도를 위시한 동북아지역에 중국, 만주 등지를 기원으로 하는 황사가 빈번하게 발생되고 있고 황사와 함께 이동되는 대기오염물질들 역시 강한 서풍기류에 의해 북태평양까지 이동할 만큼 장거리 이동현상도 발생되고 있다. (중략)

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2995-3000
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• 2014

A sensitive concentration method utilising modified gas-purge microsyringe extraction (GP-MSE) was developed. Concentration (reduction in volume) to a microlitre volume was achieved. PAHs were utilised as semivolatile analytes to optimise the various parameters that affect the concentration efficiency. The injection rate and temperature were the key factors that affected the concentration efficiency. An efficient concentration (75.0-96.1%) of PAHs was obtained under the optimised conditions. The method exhibited good reproducibility (RSD values that ranged from 1.5 to 9.0%). The GP-MSE concentration method enhances the volume reduction (concentration factor), leading to a low method detection limit ($0.5-15ngL^{-1}$). Furthermore, this method offers the advantage of small-volume sampling, enabling even the detection of diurnal hourly changes in the concentration of PAHs in ambient air. Utilising this method in combination with GC-MS, the diurnal hourly flux of PAHs from the gas phase of ambient air was measured. Indeed, the proposed technique is a simple, fast, low-cost and environmentally friendly.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.5
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• pp.437-448
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• 2015

The purpose of this study is to present the source contribution of the fine particles ($PM_{2.5}$) in Chungju area using the CMB (chemical mass balance) method throughout the four seasons in Korea. The Chungju's annual average level of $PM_{2.5}$ was $48.2{\mu}g/m^3$, which exceeded two times higher than standard air quality. Among these particles, the soluble ionic compounds represent 54.2% of fine particle mass. Additionally, the OC concentration in Chungju stayed similar to other domestic cities, while the EC concentration decreased significantly compared to other domestic/international cities. The concentration of sulfur represented the highest composition (8%) among the fine particle compounds. According to the CMB results, the general trend of the $PM_{2.5}$ mass contributors was the following: secondary aerosols (50.5%: ammonium sulfate 26.5% and ammonium nitrate 24.0%) > gasoline vehicle (18.3%) > biomass burning (11.0%) > industrial boiler (6.0%) > diesel vehicles (4.4%). The contribution of the secondary aerosols was the main cause than others. This impact is assumed to be emitted from air pollutants of urban cities or neighbor countries such as China.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.1
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• pp.87-97
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• 2004

NMHC (non-methane hydrocarbons) and fine particles such as P $M_{10}$ and P $M_{2.5}$ were measured at KIST (Korea Institute of Science and Technology) in Seoul for a month from the end of May. At the beginning of June, peak ozones exceeded 100ppb both near KIST and in Seoul while ozone and fine particles decreased from the middle of June due to frequent precipitation. Because the measurement site was close to trees on a hill, isoprene concentration went up to 4.1ppb with an average of 0.76ppb. Toluene was the highest all day long, but particularly high concentration in the afternoon implied a contribution of emission from solvent use as well as vehicle exhaust. Eighty-five percent of P $M_{10}$ was P $M_{2.5}$ on an average since major ions except sea salt, including nitrate, were present within P $M_{2.5}$. Daily variations of pollutants were generally similar except for NMHC. One of major differences in NMHC variation was maintenance of a relative high concentration in rainy day, showing that NMHC were not effectively scavenged by precipitation.ion.ion.

• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.1-11
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• 2015

Increasing ozone concentrations are observed over Japan from year to year. One cause of high ozone concentration in the Kanto region, which includes areas inland from large coastal cities such as metropolitan Tokyo, is the transportation of precursors by sea breezes. However, high ozone concentrations are also observed in the morning, before sea breezes approach inland areas. In this point, there would be a possibility of residual ozone existing above the nocturnal boundary layer affects the ozone concentration in the following morning. In this study, we utilized the Weather Research and Forecasting model and the Community Multiscale Air Quality model to evaluate the effect of regional precursors and residual ozone on ozone concentrations over the inland Kanto region. The results show that precursors emitted from non-metropolitan areas affected inland ozone concentrations more than did precursors from metropolitan areas. Moreover, calculated results indicate downward transportation of residual ozone, resulting in increased concentration. The residual ozone was also affected by precursors emitted from non-metropolitan areas.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.5
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• pp.355-362
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• 2002

There has been relatively a few studies that focused on evaluation of uncertainty for standard methods by which criteria pollutants are analyzed in ambient air. Especially, uncertainty evaluation has not been made yet for sampling and analysis of airborne NO$_2$. Ambient NO$_2$ has been thought to be a major criteria pollutant worldwide because of the potential of ozone formation as well as of its own toxicity. In this study, we tried to assess uncertainties associated with the every step of sampling and of analytical procedure of Griess-Saltzman method. Quality assurance (QA) and quality control (QC) were also emphasized with the uncertainty characterization. The use of Griess-Saltzman method for ambient NO$_2$ analysis showed very uniform daily concentration distribution with the mean of 10.8 ppb and the standard deviation of 1.08ppb during the sampling period. However, seven daily samples collected at the same sampling time and place exhibited highly different concentration distribution. Therefore, we evaluated uncertainties associated with sampling and analysis through the precise application of ISO Guide. Estimates of expanded uncertainties for a total of 62 samples fell in a relatively broad range of 5.17% to 11.85%. On the other hand. the expanded uncertainties were smaller for the high concentration range of greater than 15ppb.

• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.42-54
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• 2010

Automobile emissions have caused a major hydrocarbon pollution problem in the ambient air of many cities around the world. This study was conducted to measure the pollution status of volatile organic compounds (VOCs) in some urban residential areas in Seoul, Korea. A total of 20 VOCs (11 aromatic and 9 chlorinated species) were identified at 4 urban residential sites in Seoul, Korea from February 2009 to July 2009. Comparison of total VOC (TVOC) concentration data indicated the dominance of the aromatic species with the maximum (72.2 ppbC) at Jong Ro (JR) and the minimum at Yang Jae (33.4 ppbC). The peak concentration of TVOC occurred during spring at all sites with an exception at Gang Seo (GS), where it was recorded during winter. The distribution of individual VOCs at the study sites was characterized by high toluene concentration. A strong correlation of benzene was also observed with other VOCs and criteria pollutants at all sites (except YJ). The overall results of this study suggest that vehicular emissions have greatly contributed to the increase in VOC pollution at all the study sites.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.574-583
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• 2008

The results of HAPs emission data using TRI (Toxic Release Inventory), SODAM (Source Data Management system) were investigated and the emissions of 7 heavy metals from their sources and emission processes were also analyzed. Questionnaire for source data analysis as well as the stack sampling were carried out for 17 factories among 6 selected industrial types. The annual amount of emissions was estimated based on the measured concentration and flow rates. All sources were operated with high efficiency control devices and the concentration levels of all heavy metals were shown to be below 0.1 to of regulation standard. The highest emission source of heavy metals was steel manufacturing industry with the annual emission of 342.9 kg/yr and followed by hazardous waste incinerator, paint manufacturing, nonferrous metal manufacturing, rolling & press goods manufacturing and storage battery manufacturing. In the case of Hg, the emissions were quite significant from electric acros of steel manufacturing industry, although the concentration level was below the emission standard, showing the necessity of specific care for its management.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2010.04a
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• pp.41-44
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• 2010

Hazardous air pollutants such as benzo[a]pyrene (BaP), benzene, formaldehyde have been concerned about the adverse health effect of long-term exposure. Contour map is useful for finding high-concentration region, emission source, and distributions of HAPs in the ambient air. To make a contour map, we have developed simple analytical method for selected HAPs; polycyclic aromatic hydrocarbons such as BaP, benzene and its derivatives such as toluene and xylene, and aldehydes and ketones. We have applied these methods to investigate air pollution by HAPs in some cities in Japan. The results show that these methods reveal actual emission sources if the PRTR emission report was not submitted.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.574-589
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• 2006

Although concentrations of hazardous air pollutants(HAPs) are very low in the atmosphere, a growing attention has been paid on such compounds due to their high toxicity and bioaccumulation potentials into human body. In order to control and manage the amount of these materials in ambient air, it is necessary to construct monitoring system of them and to know the current concentration level of HAPs above all. In this work, a wide range of HAPs has been measured in metropolitan area to recognize the present state of HAPs in this area. The measured concentration of VOCs was higher in order of Jeonnongdong, Jeongdong, and Yangsuri. The regional difference of VOCs concentration was also highest in spring. Its total VOCs was ranged from $15.17{\sim}41.45$ ppb. Benzene $0.43{\sim}2.32$ ppb showed similar concentration level with the result of previous researches in Seoul. This value is a little higher than the average concentration 0.92 ppb for national ambient air quality standards in Japan. The concentration of aldehydes in this study was lower than those of other researches. Previous works in Seoul metropolitan area showed that the concentration of formaldehyde and acetaldehyde were higher than 5 ppb. The concentration of gaseous and particulate PAHs was high in order of winter, spring, and summer More than 90% of PAHs with low molecular weight such as 2-rings and 3-rings PAHs existed in gas phase. On the other hands, PAHs with high molecular weight more than 5-rings PAHs almost existed in particulate. In spring, the concentration of gaseous PAHs was 24.38 $ng/m^3$ in Jeongdong. Among the particulate PAHs, the concentrations of Naphthalene, Benzo(b)fluoranthene, and Benzo(g, h, i)perylene were higher than others. Especially, the concentration of Benzo(a)pyrene, a important carcinogenic pollutant, was highest in winter 0.5 $ng/m^3$ and ranged from 0.03 to 0.3 $ng/m^3$ in spring and summer, which is lower than the monitoring result in 90's. These components were mainly originated from the vehicle exhaust or heating equipment use.