• 한국대기환경학회지
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• 제25권3호
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• pp.219-236
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• 2009

Particle-phase organic tracers (molecular markers) have been shown to be an effective method to assess and quantify the impact of sources of carbonaceous aerosols. These molecular markers have been used in chemical mass balance (CMB) models to apportion primary sources of organic aerosols in regions where the major organic aerosol source categories have been identified. As in the case of all CMB models, all important sources of the tracer compounds must be included in a Molecular Marker CMB (MM-CMB) model or the MMCMB model can be subject to biases. To this end, the application of the MM-CMB models to locations where reasonably accurate emissions inventory of organic aerosols are not available, should be performed with extreme caution. Of great concern is the potential presence of industrial point sources that emit carbonaceous aerosols and have not been well characterized or inventoried. The current study demonstrates that emissions from industrial point sources in the St. Louis, Missouri area can greatly bias molecular marker CMB models if their emissions are not correctly addressed. At a sampling site in the greater St. Louis Area, carbonaceous aerosols from industrial point sources were found to be important source of carbonaceous aerosols during specific time periods in addition to common urban sources (i.e. mobile sources, wood burning, and road dust). Since source profiles for these industrial sources have not been properly characterized, method to identify time periods when point sources are impacting a sampling site, needs to avoid obtaining biases source apportionment results. The use of real time air pollution measurements, along with molecular marker measurements, as a screening tool to identify when point sources are impacting a receptor site is presented.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 1996년도 한국대기보전학회 춘계학술대회 요지집
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• pp.18-23
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• 1996

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
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• pp.467-470
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• 2006

Geostationary Ocean Color Imager (GOCI) onboard its Communication Ocean and Meteorological Satellite (COMS) is scheduled for launch in 2008. GOCI includes the eight visible-to-near-infrared (NIR) bands, 0.5km pixel resolution, and a coverage region of 2500 ${\times}$ 2500km centered at 36N and 130E. GOCI has had the scope of its objectives broadened to understand the role of the oceans and ocean productivity in the climate system, biogeochemical variables, geological and biological response to physical dynamics and to detect and monitor toxic algal blooms of notable extension through observations of ocean color. To achieve these mission objectives, it is necessary to develop an atmospheric correction technique which is capable of delivering geophysical products, particularly for highly turbid coastal regions that are often dominated by strongly absorbing aerosols from the adjacent continental/desert areas. In this paper, we present a more realistic and cost-effective atmospheric correction method which takes into account the contribution of NIR radiances and include specialized models for strongly absorbing aerosols. This method was tested extensively on SeaWiFS ocean color imagery acquired over the Northwest Pacific waters. While the standard SeaWiFS atmospheric correction algorithm showed a pronounced overcorrection in the violet/blue or a complete failure in the presence of strongly absorbing aerosols (Asian dust or Yellow dust) over these regions, the new method was able to retrieve the water-leaving radiance and chlorophyll concentrations that were consistent with the in-situ observations. Such comparison demonstrated the efficiency of the new method in terms of removing the effects of highly absorbing aerosols and improving the accuracy of water-leaving radiance and chlorophyll retrievals with SeaWiFS imagery.

• 한국대기환경학회지
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• 제16권5호
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• pp.445-451
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• 2000

To estimate dry deposition flux of 12 elements in aerosols, aerosol particles were sampled by a low-pressure impactor(LPI) and a dust jar. The concentrations of 12 elements in aerosol particle and dry deposition were analyzed by a PIXE analysis using as a 2.0 MeV-proton beam. The mean dry deposition velocities of 12 elements were estimated by ranges of 0.74∼2.62 cm/sec. The results showed that the highest value was 3.26 cm/sec for Ca and the lowest value 0.74 cm/sec for Fe. The dry deposition flux for elements was calculated as a function of particle size by 1-step method and 12-step method. In this work, dry deposition velocities were computed with the two existing models; the coarse-particle fraction(4∼30 mm diameter) using the dry deposition velocity model of the Noll and Fang(1998) and the fine-particle fraction (0.05∼4mm diameter) using the Shemel and Hodgson(1980) model. The ratios of the mean calculated/measured fluxes were 3.59 for 1-step method and 0.60 for 12-step method respectively.

• 한국대기환경학회지
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• 제12권4호
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• pp.389-398
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• 1996

In order to understand the relative importance of various pathways leading to the production and transformation of aerosols under different atmospheric conditions, the behavior of atmospheric aerosols have been investigated using a high volume tape sample in Seoul for a week period during August 1990. The concentrations of anion $(SO^{2-}_4, NO^-_3, CI^-)$ and cation $(Ca^{2+}, Na^+, NH^+_4)$ species of aerosol samples were analyzed to identify the ionic composition of aerosols and to estimate their relative contributions to aerosol formation. The concentrations of aerosol species were calculated by a multiple regression model. The results of our calculations indicate the existence of various chemical species such as $(NH_4)_2SO_4, Na_2SO_4, CaSO_4, NH_4NO_3, NaNO_3, Ca(NO_3)_2, NH_4Cl$, and NaCl salts. According to our calculations, the most dominant species of aerosol was $(NH_4)_2SO_4$ with the mean concentration of 23.3 $/mu g/m^3$ (66.9%). The proportion of different componts with aerosol (e.g., $NH_4NO_3$ and $NH_4Cl$) was strongly affected by temperature, relative humidity, and partial presure of gases.

• 한국대기환경학회지
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• 제9권3호
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• pp.230-235
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• 1993

The atmospheric aerosol samples during the Yellow Sand Phenomena in April 1993 were analyzed, and they were compared with those during the normal time. The conclusions are as follows: 1) TSP concentrations in the case of Yellow Sand Phenomena appeared to be 2.2times higher than those of normal conditions. 2) The concentration of aerosols; Inorganic components of soil-originated elements (Ca, Fe, Mn, Mg, K) during the Yellow Sand Phenomena were measured to be 1.9-2.1times higher than those during normal time. 3) During the Yellow Sand Phenomena the EF values of soil-originated metal contents except for elements Cd, Ni, Pb, Zn in the atmospheric aerosol were close to unity. 4) The concentrations of $Ca^{2+}, SO_4^{2-}, F^-$ in water soluble ionic components were higher than those during the normal time. 5) Washout factor by rain fall during the Yellow Sand Phenomena were estimated to 1268. 6) During the Yellow Sand Phenomina average deposition was 37.8ton/$km^2$.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• 제21권1호
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• pp.31-46
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• 1993

대기 가열율과 복사속의 연직 분포를 계산하기 위하여 two-stream/delta-Eddington 근사법을 이용한 복사전달모형이 개발되었다. 이 모형의 결과를 ICRCCM의 결과와 비교하므로써 모형의 완성도를 평가하였다. 이 모형은 정확성 뿐 아니라 경제적인 면에서도 태양복사를 계산하는데 적합한 것으로 증명되었다. 대기 꼭대기에서의 복사속과 지표에서의 복사속 간의 관계를 비교하므로써 자외선 B 영역(UV-B; 280-320nm)의 특징들이 검토되었다. 이 영역에서는 강한 오존 흡수가 있어 UV-B의 관계가 2차 함수로 나타난다. 또한, 성층권 오존 감소와 화산 폭발로 기인한 성층권 에어로졸 안개가 UV-B 복사에 미치는 영향을 다양한 태양의 천정각에서 조사했다. 태양의 천정각이 증가함에 따라 지표 UV-B도 증가하였다. 성층권 에어로졸은 후방 산란을 통해 행성 반사도를 증가시켰다. 행성 반사도는 에어로졸 효과로 인해 태양의 천정각이 증가함에 따라 증가한다. 그러나, 행성 반사도의 변화가 태양의 천정각 변화에 따라 민감하게 나타나지는 않는다. 이것은 태양의 천정각이 클 때 에어로졸의 산란 효과가 상대적으로 긴 복사 경로에서 포화되었기 때문일 것이다. 끝으로, 화산 폭발에서 비롯된 성층권 에어로졸이 지표 UV-B 복사 강도에 미치는 지역적 영향이 추정되었다. 고위도에서는 에어로졸의 광자 포획(photon trap)이나 일몰 효과로 복사 강도가 증가하는 반면 저위도에서는 감소한다. 고위도에서 에어로졸의 산란과 오존 흡수는 지표 UV-B 복사의 최대 증가는 봄 기간 중에 양 반구 모두 중위도에서 나타난다.

• 한국산학기술학회논문지
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• 제9권5호
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• pp.1349-1353
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• 2008

충청남도, 천안시 대기 에어로졸의 입경별 농도 및 이온성분 특성을 분석하고자, 2006년 3월부터 2007년 4월까지 천안시 상명대학교에서 Cascade Impactor를 장착한 High Volume Air Sampler를 이용하여 대기 시료를 채취 분석하였다. 입경별 에어로졸의 일평균농도는 TSP, PM10, PM2.5, PM1이 각각 61.7, 55.2, 43.7, $33.2{\mu}g/m^3$였으며, 직경이 $1{\sim}3{\mu}m$인 영역을 경계로 조대영역과 미세영역으로 나누어지는 전형적인 도심지 특성을 나타냈다. 이 중 미세영역입자인 PM2.5이 전체 에어로졸의 70.8%를 차지하였다. 이들 에어로졸 입자의 성분 분석 결과 양이온은 ${NH_{4}}^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$이, 음이온은 ${SO_{4}}^{2-}$, ${NO_{3}}^-$, $Cl^-$가 주요 성분이었으며, 이들 수용성 이온이 차지하는 비율은 조대입자에서 37.4%, 미세입자에서 46.2%였다.

• 대기
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• 제18권4호
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• pp.459-474
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• 2008

Aerosol scattering coefficients for three different wavelengths ($\lambda$=450,550,700 nm) are measured almost continuously by a nephelometer in Seoul for a period of 13 months (February 2007-February 2008), which includes two weeks break in August 2007 for measurements at Daegwallyeong and YoungJongdo. The mean of the daily average scattering coefficients at $\lambda$=550 nm is $194.1{\pm}144.2Mm^{-1}$ and the minimum and maximum are $14.3Mm^{-1}$ and $998.1Mm^{-1}$, respectively. The scattering coefficient shows a general increasing trend with atmospheric relative humidity (RH). When the data are classified according to weather conditions, the days with no major weather events show the smallest scattering coefficient and also the lowest RH. Surprisingly haze/fog days show the largest scattering coefficient and Asian dust days comes in second. Although the variation is large within a season, winter shows the largest and autumn shows the smallest scattering coefficient. The average ${\AA}ngstr{\ddot{o}}m$ exponent is $1.40{\pm}0.32$ for the entire Seoul measurement. As expected, Asian dust days show the smallest ${\AA}ngstr{\ddot{o}}m$ exponent and haze/fog days are the next, suggesting more efficient hygroscopic growth of aerosols for this weather condition. Aerosol scattering coefficient seems to show better correspondence with CCN concentration rather than total aerosol concentration, which may indicate that CCN active aerosols are also good scattering aerosols.

• 한국대기환경학회지
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• 제26권5호
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• pp.554-566
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• 2010

We present optical and microphysical particle properties of aerosol retrieved by multi-wavelength Raman lidar at Anmyun island ($36.32^{\circ}N$, $126.19^{\circ}E$), Korea. The results present aerosol properties in various height layers of the atmospheric pollution layers observed over the Korean peninsula on eight consecutive days (27, 28, 29, 30 and 31 May, 4, 5 and 7 June) in 2005 at Anmyun island. We found anthropogenic pollution on 27, 28, and 29 May and local haze on other measurement days. The origin of the particle plumes was determined by simulations of FLEXPART. The source regions of the particles resulted in rather clear differences between the optical and microphysical properties of the pollution layers. The single-scattering albedo of anthropogenic aerosols from China ($0.91{\pm}0.01$ at 532 nm) were lower than the single-scattering albedo of local haze aerosols ($0.95{\pm}0.01$ at 532 nm). Local haze aerosols show larger effective radii of $0.24{\pm}0.02\;{\mu}m$ at relative humidity of 55~75%. The effective radii of anthropogenic aerosols are $0.20{\pm}0.2\;{\mu}m$ and $0.27\;{\mu}m$ at relative humidity of 25~50%.