• Asian Journal of Atmospheric Environment
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• v.9 no.2
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• pp.137-145
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• 2015

This study focused on the measurement of the actual charging state of ambient aerosol particles, which is important for understanding the intricate process of adverse health effects caused by particulate matter (PM). The net electrostatic charging state of $PM_{2.5}$ collected on filter media was measured in this study. The Faraday cage method and surface potential measurements were used in this study. The results showed that the polarities of the net charging state measured using these two methods were in agreement for 42 out of 48 samples (87.5%), and 36 samples (75%) were negatively charged. The filters were not significantly charged by friction between the filters and air not containing PM. Charge addition to or leakage from the filters was not observed over a two-month storage period. Net charging state of $PM_{2.5}$ collected on the filters was concluded to be negative in most cases, based on data's support of the assumption that aerosol charging state is not altered by the process of PM collection using filter.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.3
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• pp.191-208
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• 1998

Estimations of dry and wet depositions in Korea and the size distributions of yellow sand above Korea have been carried out using the Eulerian aerosol model with the simulated meteorological data from the SNU mesoscale meteorological model. The estimated particle size distribution in Korea shows a bimodal distribution with peak values at 0.6 pm and 7 pm and a minimum at 2 pm in the lower layer However, as higher up, the bimodal distribution becomes an unimodal distribution with a peak value at 4∼5mm. Among the total amount of yellow sand deflated in the source regions , the dry and wet deposition fluxes were about 92%, and about 1.3∼0.5%, repectively, and the rest(5∼6%) is suspended in the air, Most of dust lifted in the air during the clear weather is deposited in the vicinity of the source regions by dry deposition and the rest undergoes the long -range transport with a gradual removal by the wet deposition processes. Over Korean peninsula, the total amount of yellow sand suspended in the air was about 6∼8% of the emissions in the source region and the dry and wet deposition fluxes were about 0.005∼0.7% and 0.003∼0.051% of the total emitted amount, repectively. It is estimated that 2.7∼8.9 mesa-tons of yellow sand is transported annually over the Korean peninsula with the annual mean dry deposition of 2.1∼490 kilo-tons and the annual mean wet deposition of 1.5∼65 kilo-tons.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.297-305
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• 1996

Aerosol measurements were carried out at Kosan, Cheju Island, Korea for the period from July 20 to August 10, 1994. Total suspended particles were collected by high volume samplers and PM 2.5 particles with gaseous volatile species were collected by a filter pack sampler and their ionic composition are analyzed. The average mass concentration of PM 2.5 particles was comparable to that of PM 3 particles collected during March, 1994 at the same site but the average non sea-salt sulfate concentration was higher that that of PM 3 particles, implying the fraction of anthropogenic air apllutants during this period is higher than that during March, 1994. During the measurement period, two distincitive patterns were observed, high concentrations of mass and water soluble ions were observed between July 20 and August 1 while those during after August 2 were low. Back trajectory analysis results show that air masses arriving at Kosan during the earlier period were mainly from Korea and Japan while those during the later period were from the North Pacific Ocean. It is suggested that the particle ion concentrations during the later period are marine background concentrations at Kosan during the summertime.

• Environmental Engineering Research
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• v.25 no.3
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• pp.439-445
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• 2020

In the estimation of the aerosol single fiber efficiency using fibrous filters, there is a size range, where the particles penetrate most effectively through the fibrous collectors, and corresponding minimum single fiber efficiency. For small particles in which the diffusion mechanism is dominant, the Cunningham slip correction factor (C_c) affects the single fiber efficiency and the most penetrating particle size (MPPS). Therefore, for accurate estimation, C_c is essential to be considered. However, many previous studies have neglected this factor because of its complexity and the associated difficulty in deriving the appropriate parameterization particularly for the MPPS. In this study, the expression for the MPPS, and the corresponding expression for the minimum single fiber efficiency are analytically derived, and the effects of C_c are determined. In order to accommodate the slip factor for all particle-size ranges, C_c is simplified and modified. Overall, the obtained analytical expression for the MPPS is in a good agreement with the exact solution.

• Journal of Environmental Science International
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• v.23 no.2
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• pp.275-289
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• 2014

Asian dust (or yellow sand) occurring mainly in spring in East Asia is affected by the distribution of weather systems. This study was performed to investigate the characteristics of suspended particulate for Asian dust at Busan, Korea in 20 March 2010, which was one of the extreme case for the last 10 years. There was used the data of weather chart, satellite, automatic weather system (AWS), $PM_{10}$, laser particle counter (LPC), and backward trajectories model. In synoptically, the high pressure was located in the northwestern part and low pressure was located in the northeastern part of Korea. The strong westerly winds from surface to upper layer makes it possible to move air masses rapidly. Air masses passing through Gobi Desert in Mongolia and Inner Mongolia plateau covered the entire Korean peninsula. As the results of aerosol analysis, $PM_{10}$ concentration at Gudeok mountain in Busan was recorded $2,344{\mu}g/m^3$ in 2300 LST 20 March 2010 and their concentration was markedly increased at coarse mode particle. In surface condition, westerly wind about 3 ~ 5 m/s was dominant and small particles of $0.3{\sim}0.5{\mu}m$ were distributed on the whole. In heavy metal components analysis, the elements from the land was predominated.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.3
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• pp.353-363
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• 2007

To differentiate temperature effect from the light intensity effect on the formation of secondary products during the photooxidation of toluene-$NO_x$-air mixtures, steady-state air temperature was changed from $20^{\circ}C\;to\;33^{\circ}C$ at the same light intensity of $0.39min^{-1}$ in an indoor smog chamber. Smog chamber consisted of 64 blacklights and a $5.8m^3$ reaction bag made of Teflon film. Air temperature was controlled by an air-conditioning system. The starting time for rapid conversion of NO to $NO_2$ was slightly delayed with decreasing air temperature. In contrast to light intensity effect, the ozone formation time and the ozone production rate were insensitive to air temperature. Although the formation time for secondary organic aerosols was not changed, the particle number concentration increased with temperature. However, the newly formed secondary organic aerosol mass at lower temperature was higher than that at higher temperature. Since light intensity significantly affected the starting time and quantity of ozone and aerosol formation, it is considered that the temperature could contribute partly the quantity of aerosol formation during the photooxidation of toluene-$NO_x$-air mixtures.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.3
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• pp.347-357
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• 2011

The TSP aerosols were collected at Gosan site of Jeju Island between 2003 and 2007, and their aerosol components were analyzed to examine the variations of chemical compositions with the corresponding pathways of inflowing air parcels. According to the comparison of seasonal aerosol compositions, the soil-originated components showed remarkably high concentrations during spring season. On the other hand, the concentrations of anthropogenic components were somewhat high in spring and summer seasons, but low in fall season. Based on the comparison of TSP compositions in relation to the pathways of inflowing air mass, the concentrations of anthropogenic components (nss-$SO_4^{2-}$, S, $NO_3^-$), soil-originated components (nss-$Ca^{2+}$, Al, Fe, Ca), and the heavy metals (e,g., Mn, Zn, Cr, Pb, Cu, Cd, etc.) have relatively increased with the air mass moving from China continent into Jeju area. Meanwhile, the marine-originated components showed an increasing trend with the air mass coming from North Pacific Ocean. In the seasonal and sectional comparison, the nss-$SO_4^{2-}$, $NO_3^-$, nss-$Ca^{2+}$, and Al showed comparatively high concentrations when the air mass moved from China continent during all seasons. Especially, the $NO_3^-$, nss-$Ca^{2+}$, and Al concentrations were somewhat high when the air mass moved from Korean Peninsula during summer season. It was also recognized that the Na+ concentration were high, when the air mass moved from Pacific Ocean through all seasons.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.2
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• pp.143-152
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• 1998

The aerosol concentrations of ionic components were measured on a daily basis from a coastal monitoring site located at Kosan, Cheju Island from 26 September to 5 October 1997 as a field-intensive for a LRTAP project The chemical species we investigated include most of important inorganic species (i.e., Cl-, NO3-, F-, SO42-, Na+, NH4+, and K+) and some organic species (i.e. formats, acetate, and methanesulfonate (MSA) ions). The concentration data of those important inorganic and organic species obtained during this study were evaluated to properly address their chemical and physical characteristics. Most of major inorganic components including sulfate, sodium, chloride, and potassium ions exhibited very conservative relationships with each other such that the concentration ratios of any pair are quite analogous to that of seawater ratio. Since the oceans serve as the major sources of ionic constituents, their concentration changes appear to be senstively reflected by the factors affecting air-sea processes such as an increase in wind speed or changes in wind direction. A comparative analysis of sulfur-containing species such as seasalt (SS) and nonseasalt (NSS) sulfate and MSA were also made to assess the factors influencing the S cycling. An evaluation of NSS/SS ratios suggests that most of sulfate be associated with NSS fraction rather than 55 one. The finding of lower MSA/NSS-SO42- ratio along with a line of physical evidence such as intrusion of anthropogenically affected air mass suggests that the oxidation of S species have been promoted under the conditions encountered during the study period. Finally, the concentration data of carboxylic species (such as formats and acetate ions) were also analyzed. Although the existence of temporal trends were difficult to assess, these data indicate that their contribution to the precipitation acidity may not be significant enough.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.594-603
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• 2008

A single particle analytical technique, named low-Z particle electron probe X-ray microanalysis, was applied to characterize four samples collected at an underground shopping area connected to Dongdeamun subway station, in January and May 2006. Based on the analysis of their chemical compositions of the samples, many distinctive particle types are identified and the major chemical species are observed to be soil-derived particles, iron-containing particles. sulfates. nitrates, and carbonaceous particles. which are encountered both in coarse and fine fractions. Carbonaceous particles exist in carbon-rich and organic. Soil derived particles such as aluminosilicates, AlSi/C, $CaCO_3\;and\;SiO_2$ are more frequently encountered in spring samples than winter samples. Nitrate- and sulfate-con taming particles are more frequently encountered in winter samples, and those nitrate- and sulfate-containing particles mostly exist in the chemical forms of $Ca(CO_3,\;NO_3),\;Ca(NO_3,\;SO_4),\;(Na,\;Mg)NO_3\;and\;(Mg,\;Na)(NO_3,\;SO_4)$. Fe-containing particles which came from nearby subway platform are in the range of about 10% relative abundances for all the samples. It is observed that nitrate- and sulfate-containing particles and carbonaceous particles are much more frequently encountered in indoor aerosol samples than in outdoor aerosols, implying that $NO_x,\;SO_x$, and VOCs at the underground shopping area were more partitioned into aerosol phase.

• Asian Journal of Atmospheric Environment
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• v.7 no.1
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• pp.1-7
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• 2013

To establish the method for investigating the behavior of aerosol particles deposited on the leaf surface against fog water under natural conditions, scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analysis and wash water analysis by ion chromatography after the washing treatment were performed using leaves of white birch collected from low part of the tree crown and the top of the tree in Sapporo City, Hokkaido, northern Japan. Each of collected leaves was divided into two parts according to the treatment performed: leaf surface (adaxial side) was 1) untreated, and 2) washed with deionized water with a pipette. In untreated samples, many particles of various shapes, including soil particles and organic debris, were deposited on the surface. Particles containing S were found on the surface of samples collected from only low part of the tree crown. After the washing treatment, SEM-EDX analysis revealed that soil particles and particles containing S had been washed off with water, although some particles such as soil particles and organic debris still remained on the leaf surface. The major anion such as $SO{_4}^{2-}$ was detected in wash water of all samples, although the peak of S in X-ray spectra was not detected from samples collected at top of the tree. The combination of SEM-EDX analysis with wash water analysis indicated that $SO{_4}^{2-}$ was deposited on the leaf surface in dissolved state and/or in state of submicron particles. These results suggested that fog water could remove soil particles and particles containing S and $SO{_4}^{2-}$ from the leaf surfaces, but not all particles. There was no difference in sampling position in the tree crown. Our study suggested that combination with SEM-EDX analysis and wash water analysis would be effective for investigation of the behavior of particles on the leaf surface against fog water.