• Wind and Structures
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• 제17권1호
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• pp.1-19
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• 2013

A multiscale finite element method is applied to the Spalart-Allmaras turbulence model based detached-eddy simulation (DES). The multiscale arises from a decomposition of the scalar field into coarse (resolved) and fine (unresolved) scales. It corrects the lack of stability of the standard Galerkin formulation by modeling the scales that cannot be resolved by a given spatial discretization. The stabilization terms appear naturally and the resulting formulation provides effective stabilization in turbulent computations, where reaction-dominated effects strongly influence near-wall predictions. The multiscale DES is applied in the context of high-Reynolds flow over the Commonwealth Advisory Aeronautical Council (CAARC) standard tall building model, for both uniform and turbulent inflows. Time-averaged pressure coefficients on the exterior walls are compared with experiments and it is demonstrated that DES is able to resolve the turbulent features of the flow and accurately predict the surface pressure distributions under atmospheric boundary layer flows.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
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• pp.150-155
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• 2010

액체로켓 분사기는 추진 성능과 연소 안정성, 그리고 열유속 특성을 지배하는 가장 중요한 요소이다. 그러나 분사기 근방에서 일어나는 고압 연소 현상에 대한 근본적인 이해의 부족으로 분사기의 개발 과정은 대부분 경험적 설계방법과 고비용의 연소시험에 의존해 왔다. 본 연구는 액체로켓 연소 모델링과 관련된 최근 연구 동향들을 토대로 시작되었다. 층류화염편 기반의 난류연소모델을 초임계 압력 조건에서 나타나는 실제유체 거동을 고려할 수 있도록 확장하였으며, 극저온 질소분사, 상압 조건하의 난류제트화염, 그리고 고압의 기체수소/액체산소 동축 분사기에 적용하여 해석모델의 효용성을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.493-502
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• 2012

Syngas laminar burning velocity measurements were carried out at atmospheric pressure and ambient temperature using the Bunsen flame configuration with nozzle burner as a fundamental study on flame stability of syngas fuel. Representative syngas mixture compositions ($H_2$:CO) such as 25:75%, 50:50% and 75:25% and equivalence ratios from 0.5 to 1.4 have been conducted. Average laminar burning velocities have been determined by the stabilized nozzle burner flames using the angle method, radical surface area method and compared with the data obtained from the other literatures. And the results of each experimental methodologies in the various composition ratios and equivalence ratios were coincided with the result of numerical simulation. Especially, it was confirmed that there was necessary to choice a more accurate measurement methodology even the same static flame method for the various composition ratios of syngas fuel including hydrogen. Also, it was reconfirmed that the laminar burning velocities gradually increased with the increasing of hydrogen content in a fuel mixture.

• 한국수소및신에너지학회논문집
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• 제21권5호
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• pp.412-418
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• 2010

Steam reforming of n-hexadecane, a major component of diesel over Ni-based hydrotalcite-like catalyst was carried out at $900^{\circ}C$ at atmospheric pressure with space velocity of $10,000h^{-1}$ and feed molar ratio of steam/carbon=3.0. Ni-based hydrotalcite catalyst was prepared by a solid phase crystallization (spc) method and characterized by $N_2$-physisorption, CO chemisorption, TPR., XRD, and TEM techniques. It was found that spc Ni/MgAl catalyst showed higher catalytic stability and inhibition of carbon formation than Ni/$\gamma-Al_2O_3$ catalyst under the tested conditions. The results suggest that the modified spc-Ni/MgAl catalyst after optimization may be applied for the SR reaction of diesel.

• 한국가스학회지
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• 제8권1호
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• pp.13-17
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• 2004

무거운 독성가스의 소규모 누출에 대한 가우시안 연속모델의 적용성을 평가하기 위하여 염소가스의 소규모 누출에서 염소농도의 실험값과 여러 가지 분산계수를 사용한 가우시안 연속모델에 의해 산출한 이론값을 비교하였다. 그 결과, 염소가스 분산은 분산계수와 대기안정도에 따라 상당히 차이가 있었으며, 염소농도는 Briggs의 분산계수와 유효 누출높이를 사용한 가우시안 연속모델에 의해 비교적 정확하게 산출할 수 있었다.

• Environmental Engineering Research
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• 제10권3호
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• pp.131-137
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• 2005

The catalytic activity of precious metals(Rh, Pd, Pt) and nickel catalysts supported on ${\gamma}-Al_2O_3\;and\;CeO_2$ in the partial combustion of methane(PCM) to syngas was investigated based on the product distribution in a fixed bed now reactor under atmospheric condition and also on analysis results by SEM, XPS, TPD, BET, and XRD. The activity of the catalysts based on the syngas yield increased in the sequence $Rh(5)/CeO_2{\geq}Ni(5)/CeO_2>>Rh(5)/Al_2O_3>Pd(5)/Al_2O_3>Ni(5)/Al_2O_3$. Compared to the precious catalysts, the syngas yield and stability of the $Ni(5)/CeO_2$ catalyst were almost similar to $(5)/CeO_2$ catalyst, and superior to these of any other catalysts. The syngas yield of $Ni(5)/CeO_2$ catalyst was 90.66% at 1023 K. It could be suggested to be the redox cycle of the successive reaction and formation of active site, $Ni^{2-}$ and the lattice oxygen, $O^{2-}$ produced due to reduction of $Ce^{4-}$ to $Ce^{3-}$.

• Applied Science and Convergence Technology
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• 제26권4호
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• pp.62-65
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• 2017

Passivation of surface defects by the formation of chemically inert structure at the surface of $TiO_2$ nanocrystals can be potentially useful in enhancing their photocatalytic activity. In this regard, we have studied the surface chemical states of $TiO_2$ surfaces prepared by a treatment in the afterglow of $N_2$ microwave plasma using X-ray photoemission spectroscopy (XPS). We find that nitrogen is incorporated into the surface after the treatment up to a few atomic percent. Interestingly, the surface oxynitride layer is found to be chemically stable when it's in contact with water at room temperature (RT). The surface nitrogen species were also found to be thermally stable upon annealing up to $150^{\circ}C$ in the atmospheric pressure. Thus, we conclude that the treatment of oxide materials such as $TiO_2$ in the afterglow of $N_2$ plasma can be effective way to passivate the surface with nitrogen species.

• 한국가스학회지
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• 제8권2호
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• pp.8-14
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• 2004

본 연구는 염소가스의 소규모 연속누출에서 분산특성과 독성영향을 해석하였다. 염소 농도의 실험값과 이론값을 비교한 결과, Briggs의 분산계수와 유효누출높이를 사용한 가우시안 모델이 BM 모델보다 적용성이 우수하였다. 또한 가우시안 모델에 의해 염소농도를 산출하고 해석한 결과, 염소분산은 누출속도 보다 대기안정도와 바람속도에 크게 영향을 받으며, 독성영향은 염소분산에 미치는 매개변수의 영향과 유사한 경향을 나타내었다. 이때, 여러 독성기준에 의해 산출된 피해범위로부터 인명을 보호하기 위한 위험지역을 파악할 수 있었다.

• Nuclear Engineering and Technology
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• 제16권3호
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• pp.136-140
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• 1984

원자력발전소 사고 후 그 위험도를 평가하는 새로운 방법으로 몬테칼로 방법을 제시한다. 본 연구에서는 발전소 주위의 주민에게 주는 방사선의 영향을 평가하기 위하여 공기중의 확산계산에 부지에서 측정한 기상조건을 직접 사용하고 있다. 사고가 일어나는 순간에서의 화산조건은 주어진 기상자료로부터 분석된 pdf에 의하여 결정되고 그이후의 조건(풍향, 풍속, 안정도)은 마르코프 조건을 만족시킨다고 가정하였다. 예제로써 KNU-1의 냉각재 상실사고를 분석한 절과 50마일내의 주민이 받는 선량은 50퍼센트 신뢰도를 갖고 200 man-Sv이다.

• Asia-Pacific Journal of Atmospheric Sciences
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• 제54권4호
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• pp.563-573
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• 2018

An Expert Seasonal Prediction System for operational Seasonal Outlook (ESPreSSO) is developed based on the APEC Climate Center (APCC) Multi-Model Ensemble (MME) dynamical prediction and expert-guided statistical downscaling techniques. Dynamical models have improved to provide meaningful seasonal prediction, and their prediction skills are further improved by various ensemble and downscaling techniques. However, experienced scientists and forecasters make subjective correction for the operational seasonal outlook due to limited prediction skills and biases of dynamical models. Here, a hybrid seasonal prediction system that grafts experts' knowledge and understanding onto dynamical MME prediction is developed to guide operational seasonal outlook in Korea. The basis dynamical prediction is based on the APCC MME, which are statistically mapped onto the station-based observations by experienced experts. Their subjective selection undergoes objective screening and quality control to generate final seasonal outlook products after physical ensemble averaging. The prediction system is constructed based on 23-year training period of 1983-2005, and its performance and stability are assessed for the independent 11-year prediction period of 2006-2016. The results show that the ESPreSSO has reliable and stable prediction skill suitable for operational use.