• 한국환경과학회지
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• 제4권1호
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• pp.41-52
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• 1995

The effects of reaction temperature, SO2 and CO2 concentration in an air gas stream, particle sizes of limestone on the reactivity and capacity of SO2 removal have been determined in a thermogravimetric analyser(TGA). The apparent reaction order of sulfation reaction of pre-calcined lime(CaO) with respect to SO2 is found to be close to unity. The apparent activation energies are found to be 17,000 kcal/kmol for sulfation of pre-calcined lime and 19,500 kcal/kmol for direct sulfation of limestone(CaCO3). The initial sulfation reaction rate of pre-calcined lime increases with increasing temperature, whereas the sulfur capture capacity exhibits a maximum value at 90$0^{\circ}C$. In direct sulfation of limestone, sulfation reactivity and sulfur capature capacity of sorbent increase with increasing temperature and decreasing CO2 concentration in a gas bulk stream. The main pare of pre-calcined lime is shifted to the larger pore sizes and pore volume decreases with increasing sulfation time and temperature. The surface area of lime decreases with increasing calcination temperature under an air atmosphere, whereas is yearly constant under a CO2(5, 10%) atmosphere in a gas stream.

• 공업화학
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• 제8권2호
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• pp.179-190
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• 1997

준역청탄, 유연탄, 무연탄 및 국내 무연탄을 포함하는 54종의 석탄회분을 대상으로 화학조성 및 광물분석 그리고 용융온도를 측정하여 화학조성이 용융온도에 미치는 영향을 고찰하였다. 석탄회의 구성 산화물중 CaO와 MgO, 그리고 $Fe_2O_3$가 용융온도를 낮추는 산화물임을 알 수 있었다. $Fe_2O_3$에 의한 용융온도 감소 효과는 환원성분위기에서 증가되었다. 산-염기도에서 염기성분의 함량이 증가할수록 용융온도는 감소하였다. 그러나 산-염기도와 용융온도와의 상관관계는 $Fe_2O_3$/CaO비가 증가함에 따라 낮아졌다. 산화성분위기보다는 환원성분위기에서 용융온도가 낮았으며 이때 분위기 변화에 따른 용융온도차는 $Fe_2O_3$의 함량보다는 $SiO_2/Al_2O_3$비와 밀접한 상관성을 보여주었다. 석탄회의 용융온도(연화)를 예측하기 위한 다중회귀분석결과 산화성분위기에서는 Base/Acid, $Fe_2O_3$/CaO, $SiO_2/Al_2O_3$, $(SiO_2/Al_2O_3){\cdot}(Base/Acid)$ 그리고 환원성분위기에서는 Base/Acid, $Fe_2O_3$/CaO, $SiO_2$, $TiO_2$등을 독립변수로 사용함으로써 비교적 상관성이 높은 관계식을 얻을 수 있었다.

• 대기
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• 제29권3호
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• pp.283-294
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• 2019

For the upper air observations, a temperature measurement using radiosonde is a common method, and the compensation of solar radiation effects in the radiosonde temperature sensor is an important factor. In this paper, we present various experiments and compensation methods of the radiosonde temperature sensor to overcome the errors caused by the movement of the radiosonde rotation, etc. The methods and procedures of this study are as follows. First, we used the solar simulator to analyze the temperature variation and solar effect of the temperature sensor in the radiosonde according to the insolation. We also analyzed the temperature variation and solar effect of the temperature sensor according to the incident angle between the solar simulator and radiosonde. Second, we measured and analyzed solar radiation absorbed by solar cells attached to radiosonde. Third, we present combined compensate solution of the first and the second experiment results, to overcome errors caused by insolation effects in the radiosonde temperature sensors. Fourth, we compared that the reference temperature in similar environment with the upper air conditions, to verify the new radiated compensation performance of the radiosonde temperature sensor. Finally, the radiosonde fabricated in this study was raised to the atmosphere, and the laser correction algorithm proposed through experiments was reviewed. As a result of the radiosonde SRS-10 produced in this study, the temperature deviation from Vaisala RS92 was $0.057^{\circ}C$ in nighttime observation, $0.17^{\circ}C$ in daytime observation, It is expected that the GRUAN under WMO will be able to obtain a high test rating of 5.0.

• Tribology and Lubricants
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• 제14권2호
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• pp.35-41
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• 1998

The $WS_2$ solid lubricant synthesized through the vapour phase transport method was coated on the commercial bearing steel (SUJ 2) substrate, and the tribological behaviour of the lubricant was investigated using a ball-on-disk type tester. The $WS_2$ powder was spray-coated at room temperature using compressed air, and the change of friction coefficient was examined in various conditions, i.e., specimen configuration, atmosphere (air and nitrogen), applied load and rotating speed. $WS_2$ coated ball and disk showed the optimum friction coefficient of 0.07 and wear life of 45,000 cycles in the nitrogen atmosphere under 0.3 kgf and 100 rpm, whereas relatively high coefficient of 0.13 and reduced wear life of 4,000 cycles were observed in air atmosphere. The effect of rotating speed on the friction coefficient was not observed both in nitrogen and in air atmospheres. This confirmed that the spray-coated $WS_2$ solid lubricant was effective in reducing the friction coefficient and improving wear life in nitrogen atmosphere, and the oxygen and moisture existing in air could seriously deteriorate the lubrication effect of $WS_2$ coating layer.

• 한국전자파학회논문지
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• 제19권6호
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• pp.698-705
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• 2008

전자파가 대기를 통과할 때 대기를 형성하고 있는 다양한 요인들에 의해 그 특성이 변동하게 된다. 전파 특성에 영향을 미치는 대기의 주요 요인으로는 수증기, 안개, 산소와 같은 대기 입자, 강우, 강설 및 그 외 여러 종류의 에어로졸을 들 수 있으며, 이러한 것들은 지형 및 지역적 특성에 따라 다르게 분포한다. 따라서 대기 환경에서의 전파 특성을 예측하기 위해서는 주어진 환경에 대한 기온, 습도, 기압, 풍속, 에어로졸 및 강우율 등의 통계적 분석이 중요하다. 본 논문에서는 국내 대기 환경에 대한 통계적 분석을 수행하였으며, 이를 바탕으로 국내 대기 환경에서의 전파 특성을 분석하였다.

• 한국표면공학회지
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• 제50권2호
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• pp.125-130
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• 2017

ZnO nanowires were synthesized and annealed at various temperatures of $500-800^{\circ}C$ in oxygen atmosphere to investigate hydrogen gas sensing properties. The diameter and length of the synthesized ZnO nanowires were approximately 50-100 nm and a few $10s\;{\mu}m$, respectively. $H_2$ gas sensing performance of the ZnO nanowires sensor was measured with electrical resistance changes caused by $H_2$ gas with a concentration of 0.1-2.0%. The response of ZnO nanowires at room temperature to 2.0% $H_2$ gas is found to be two times enhanced by annealing process in $O_2$ atmosphere at $800^{\circ}C$. In the current study, the effect of heat treatment in $O_2$ atmosphere on the gas sensing performance of ZnO nanowires was studied. And the underlying mechanism for the sensing improvement of the ZnO nanowires was also discussed.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.81-81
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• 2008

Applications of CdS films in this study are to exhibit a high conductivity when they are exposed at light with visible wavelength and sequentially to show a low conductivity in dark state. For this purpose, CdS films should have a high photosensitivity, still maintaining a high conductivity at a visible light. In this study, CdS films were prepared at room temperature on glass substrates by rf magnetron sputtering. In order to increase the photo-conductivity in visible light, various defect levels should be located within the CdS band gap. In order to nucleate the defect sites within the CdS band gap, CdS films were deposited on glass substrates at room temperature using various $H_2$/(Ar+$H_2$) flow ratios by an rf magnetron sputtering. Through the investigation of the structural and photoconductive properties of CdS films by an addition of hydrogen, the relationship between photo- and dark-resistance in CdS films was investigated in detail. 200-nm-thick CdS films for photoconductive sensor applications were prepared at various $H_2$/(Ar+$H_2$) flow ratios on glass substrates at room temperature by rf magnetron sputtering. Sulfur concentration in CdS films crystallized at room temperature with (002) preferred orientation depends directly on the hydrogen atmosphere and the surface roughness of the films gradually increases with increasing hydrogen atmosphere. Films deposited at 8% of $H_2$/(Ar+$H_2$) exhibit an abrupt decrease of dark- and photo-resistance, showing a low photo-sensitivity ($R_{dark}/R_{photo}$). Onthe other hand, films deposited at a hydrogen atmosphere of 42% exhibit a photo-sensitivity of $5\times10^3$, maintaining a photo-resistance of an approximately $2\times10^4\Omega$/square. The dark- and photo-resistance values of CdS films were related with a composition, surface roughness, and defect sites within the band gap.

• 자원리싸이클링
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• 제19권1호
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• pp.21-26
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• 2010

본 연구에서는 마이크로웨이브 열탄소환원에 의한 제철 슬래그의 Fe 회수를 위한 기초연구로서, CaO-$SiO_2$-FeO계 슬래그의 열탄소환원 반응에 미치는 가스 분위기(질소 및 대기분위기) 및 탄소 첨가량의 영향을 살펴보았다. 실험결과, 질소 분위기에 비하여 대기 분위기에서 반응 시 최고 도달 온도 및 환원률이 증가하고, 대기 분위기에서는 탄소 당량 증가에 따라 최고 도달 온도 및 환원률이 증가하는 경향을 나타내었다. 대기 중 탄소 당량($C_{eq}$)이 5인 조건에서 최고 온도는 1800K에 도달하였으며 약 90%의 철회수율을 얻을 수 있었고, 탄소 당량이 5 이상 증가할 경우 최고 온도 및 환원율의 변화는 크지 않음을 알 수 있었다.

• 농업과학연구
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• 제45권4호
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• pp.811-821
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• 2018

This study focused on the improvement of blueberry delivery service using pre-cooled ice and $SO_2$ pads to prevent an increase in the fruit temperature as well as decay. To maintain the fruit quality during low temperature storage, the effect of a $SO_2$ pad and modified atmosphere packaging was also examined. Harvested blueberries were precooled at $15^{\circ}C$, sorted, and packaged. And the fruits were placed in a similar environment as that for the parcel service. Part of the fruits were stored at $0^{\circ}C$ for long term storage. The air temperature in the delivery box increased along with an increase in the simulated delivery time regardless of the treatment. However, the rate of temperature increase was lower in the ice pad treatment. No significant difference was not found after 48 h. The oxygen concentration in the box ranged between 10.5 - 14.5% in the ice pad treatment, which was higher than that of the untreated control (7.5 - 11.9%) whereas the $CO_2$ concentration was lower in the ice pad treatment. No differences were found in the occurrence of off-flavor, decay, and sensory quality loss during the 48 hours of the parcel service simulation. The combined treatment of the $SO_2$ pad and modified atmosphere packaging (MAP) using a perforated film increased the shelf-life of the blueberry fruits, the overall quality such as firmness, and the soluble solid content was not different between the treatments except for the decay incidence. No decayed fruit was found in the combined treatment. However, the percentage of decayed fruit in the control was 25% on day 15 of storage and 75% on day 33 of storage, respectively.

• Environmental Analysis Health and Toxicology
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• 제22권2호통권57호
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• pp.177-184
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• 2007

Gaseous organochlorine pesticides (OCPs : heptachlor epoxide, p, p'-DDE, ${\gamma}-HCH,\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor) concentration was measured using PUF high volume sampler from June, 2000 to June, 2002 in the semi-rural atmosphere. The OCPs concentration in atmosphere, which is estimated by the slope (m) of Clausius-Clapeyron equation and phase-transition energy $({\Delta}H)$, was influenced by revolatilization from environmental matrix (soil, water and tree leaves) and a long range transportation of air mass. But the former affected OCPs concentration more than the latter. The degradation rate constants (k) of OCPs calculated using multiple regression analysis and revised standard temperature method were in good agreement each other. The value of k of ${\gamma}-HCH$ was very low as -0.0007, but the range of k of other components were $-0.00l8{\sim}-0.0038$. The half-life $({\tau})$ which was calculated by k of ${\gamma}-HCH$ was 2.6 years-the longest one, but that of heptachlor epoxide was in 0.5 year-the shortest one. $({\tau})\;of\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor in technical chlordane was 1.0, 1.1 and 0.7 year respectively.