• Title/Summary/Keyword: Atmosphere Temperature

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Oxidation Resistance of SPS (Spark Plasma Sintering) Sintered β-FeSi2Bodies at High Temperature (방전플라즈마 소결법으로 제작한 β-FeSi2 소결체의 고온 내산화성)

  • Chang, Se-Hun;Hong, Ji-Min;Oh, Ik-Hyun
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.132-136
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    • 2007
  • Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was investigated at intermediate temperature range in air atmosphere. Fully dense and porous bodies of ${\beta}-FeSi_{2}$ samples were fabricated by using the Spark Plasma Sintering (SPS). They were annealed at $900^{\circ}C$ for 5days to obtain ${\beta}-FeSi_{2}$ phase. The bulk samples were oxidized at $800,\;900\;and\;950^{\circ}C$ in air atmosphere. The high temperature oxidation tests reveal that amorphous $SiO_{2}$ layer, similar to Si was formed and grew parabolically on ${\beta}-FeSi_{2}$. Accelerated oxidation is not observed as well as cracks and grain boundary oxidation. Granular ${\varepsilon}-FeSi$ was developed below the oxide layer as a result of oxidation of ${\beta}-FeSi_{2}$. Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was excellent for high-temperature thermoelectric application.

Fabrication of Tantalum Nitride Thin-Film as High-temperature Strain Gauges (고온 스트레인 게이지용 질화탄탈박막의 제작)

  • Kim, Jae-Min;Choi, Sung-Kyu;Nam, Hyo-Duk;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.97-100
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    • 2001
  • This paper presents the characteristics of Ta-N thin-film strain gauges as high-temperature strain gauges, which were deposited on Si substrate by DC reactive magnetron sputtering in an argon-nitrogen atmosphere(Ar-(4~16%)$N_2$). These films were annealed for 1 hour in $2{\times}10^{-6}$ Torr vaccum furnace range $500\sim1000^{\circ}C$. The optimized conditions of Ta-N thin-film strain gauges were annealing condition($900^{\circ}C$, 1 hr.) in 8% $N_2$ gas flow ratio deposition atmosphere. Under optimum conditions, the Ta-N thin-films for strain gauges is obtained a high resistivity, $\rho=768.93$ ${\mu}{\Omega}cm$, a low temperature coefficient of resistance, TCR=-84 ppm/$^{\circ}C$ and a high temporal stability with a good longitudinal gauge factor, GF=4.12.

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Preparation of Green-Light Emitting BAM:Mn Phosphor Particles by High Temperature Spray Pyrolysis (고온 분무열분해 공정에 의한 녹색 발광의 BAM:Mn 형광체 합성)

  • Ju Seo Hee;Koo Hye Young;Kim Do Youp;Kang Yun Chan
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.496-502
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    • 2005
  • Green-light emitting $BaMgAl_{10}O_{19}:Mn^{2+}$ (BAM:Mn) phosphor particles were prepared by spray Pyrolysis. The effect of reactor temperature and flow rate of carrier gas in the spray Pyrolysis on the morphology, crystallinity and photoluminescence characteristics under vacuum ultraviolet were investigated. The morphology of the as-Prepared Particles obtained by spray Pyrolysis had spherical shape and non-aggregation characteristics regardless of the reactor temperature. The spherical shape of the as-prepared Particles obtained by spray pyrolysis at low temperature disappeared after Post-treatment. On the other hand the as-Prepared Particles obtained by spray Pyrolysis at $1600^{\circ}C$ maintained spherical shape and non-aggregation characteristics after post-treatment at $1400^{\circ}C$ for 3 h under reducing atmosphere. The BAM:Mn Phosphor Particles Prepared by spray Pyrolysis at different reactor temperatures had pure crystal structure and high photoluminescence intensities under vacuum ultraviolet after post-treatment. BAM:Mn phosphor particles prepared by spray Pyrolysis at low How rate of carrier gas had complete spherical shape and filed morphology and high photoluminescence intensity after post-treatment under reducing atmosphere.

A Numerical Study on the Short-term Dispersion of Toxic Gaseous and Solid Pollutant in an Open Atmosphere : Chemical Species, Temperature, Relative Velocity (고-기상 독성오염물질 단기 대기확산에 관한 수치해석적 연구 : 화학종, 온도, 상대속도)

  • 나혜령;이은주;장동순;서영태
    • Journal of the Korean Society of Safety
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    • v.10 no.3
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    • pp.68-80
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    • 1995
  • A series of parametric calculations have been performed in order to investigate the short-term and short-range plume and puff behavior of toxic gaseous and solid pollutant dispersion in an open atmosphere. The simulation is made by the use of the computer program developed by this laboratory, in which a control-volume based finite-difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling appeared In Wavier-Stokes equation. The Reynolds stresses are solved by the standard two-equation k-$\varepsilon$ model modified for buoyancy together with the RNG(Renormalization Group) k-$\varepsilon$ model. The major parameters considered in this calculation are pollutant gas density and temperature, the relative velocity of pollutants to that of the surrounding atmospheric air, and particulate size and density together with the height released. The flow field is typically characterized by the formation of a strong recirculation region for the case of the low density gases such as $CH_4$ and air due to the strong buoyancy, while the flow is simply declining pattern toward the downstream ground for the case of heavy molecule like the $CH_2C1_2$and $CCl_4$, even for the high temperature, $200^{\circ}C$. The effect of gas temperature and velocity on the flow field together with the particle trajectory are presented and discussed in detail. In general, the results are physically acceptable and consistent.

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High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere (고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구)

  • Lee, Han-sang;Jung, Jine-sung;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

Seasonal Variation of Carbon Dioxide Flux between Soil Surface Layer and Atmosphere in Unvegetated Tidal Flat : Beolgyo Tidal Flat (비식생 갯벌 표층과 대기의 이산화탄소 플럭스 계절 변동 분석: 벌교 갯벌)

  • Kyeong-deok Park;Dong-hwan Kang;Yoon Hwan So;Won Gi Jo;Byung-Woo Kim
    • Journal of Environmental Science International
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    • v.32 no.4
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    • pp.267-276
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    • 2023
  • In this study, we analyzed seasonal variations in carbon dioxide fluxes, concentrations, and soil temperatures over three years in unvegetated tidal flats in the Beolgyo area. We also investigated the correlations between carbon dioxide fluxes and influencing factors. The average carbon dioxide flux was positive in summer and autumn but negative in winter and spring. A positive correlation was observed between carbon dioxide flux and soil temperature in spring whereas a negative correlation was noted in summer. In summer and autumn, as the soil temperature increased, the carbon dioxide flux decreased. In contrast, in spring and winter, as the soil temperature decreased, the carbon dioxide flux increased. Overall, this study reveals the significant influence of soil temperatures on carbon dioxide fluxes between the surface layer of the tidal flat and atmosphere.

Change of Science Teachers' Perceptions About the Atmosphere Composition of Molecules with Different Masses (서로 다른 질량을 가진 분자들로 이루어진 대기의 조성에 대한 과학교사들의 인식 변화)

  • Yoo, Seunggyun;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.62 no.4
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    • pp.288-298
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    • 2018
  • In this study, we surveyed pre- and post-perceptions of fourteen science teachers related to the atmosphere composition of molecules with different masses by the developed test. As a result of the test, the teachers were classified into two types of thoughts; One of them is considered the atmosphere to be a homogeneous solution, and the other is a thought that the composition ratio of the atmosphere was not homogeneous considering the different weights of particles. The two types were reclassified into three categories; one of them is considering large gravity effect, another is considering small gravity effect, and the other is considering medium scale gravity effect. Total six types of thoughts were found from the pre-test. After introducing crosscutting concepts which are related to the composition of atmosphere. The teachers discussed the phenomena with the molecular motion by weights of atoms and temperature, the homogeneity of the solution of air in chemistry domain. They also discussed with the relationship between mass and gravity and distance in physics domain. And the discussion included distribution of the atmosphere, convection phenomena, etc. After the discussion, the teachers changed their pre-conceptions to post-concoctions considering combined perspectives of gravity, mass, temperature, altitude etc. Through these changes, we are able to confirm the importance of crosscutting concepts covered in various disciplines. In the integrated science, we should help teachers to provide students with these types of thinking in order to form a coherent world-view and to carry out inquiry thinking as an intellectual tool.

Analysis of Positioning Error Factors in the Hydrostatic Tables (유정압테이블의 위치결정오차요인 분석)

  • Oh Y.J.;Park C.H.;Lee D.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.773-776
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    • 2005
  • In this paper, For improving the positioning accuracy of hydrostatic table, relationship between temperature of atmosphere and thermal characteristics of hydrostatic table is analyzed, and influence of thermal characteristics on positioning accuracy is also analyzed experimentally. From the experimental results, it is confirmed that positioning error and repeatability is $0.21{\mu}m\;and\;0.18{\mu}m$ when the laser scale which has $0.01{\mu}m$ of resolution is used as feed-back unit. and also confirmed that thermal deformation of scale and supporter, which occurs by the temperature variation of atmosphere, works as limit of repeatability in long time operation.

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Characteristics of Chromiun Nitride Thin-film Strain Guges (크로질화박막 스트레인 게이지의 특성)

  • Chung, Gwiy-Sang;Kim, Gil-Jung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.134-138
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    • 2000
  • The physical, electrical and piezoresitive characteristics of CrN(chromiun nitride) thin-films on silicon substrates have been investigated for use as strain gauges. The thin-film depositions have been carried out by DC reactive magnetron sputtering in an argon-nitrogen atmosphere(Ar-(5~25 %)$N_2$). The deposited CrN thin-films with thickness of $3500{\AA}$nd annealing conditions($300^{\circ}C$, 48 hr) in Ar-10 % $N_2$ deposition atmosphere have been selected as the ideal piezoresistive material for the strain gauges. Under optimum conditions, the CrN thin-films for the strain gauges is obtained a high electrical resistivity, $\rho=1147.65\;{\mu}{\Omega}cm$, a low temperature coefficient of resistance, TCR=-186 ppm/$^{\circ}C$ and a high temporal stability with a good longitudinal gauge factor, GF=11.17.

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Modeling of Electrical Conductivity from $\sigma$tot vs. Po21/4 Plot in Wet Atmosphere for High-Temperature Proton-Conducting Oxides

  • Baek, Hyun-Deok
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.136-140
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    • 1998
  • This work demonstrates a method for modeling of electrical conductivity in high-temperature proton-conducting oxides. Total conductivity was calculated assuming that it comprises partial conductivities contributed by protons, oxygen ions and electron holes. From the polt $\sigma_{tot}$ vs. $po_2\;{1/4}$ in wet atmosphere, thermodynamic and kinetic parameters were obtained representing transport properties such as concentration and mobility of the charge-carrying defects. The formulas for the calculation of partial conduction were derived based on the defect structure of HTPCs. Illustrative calculation were made for $SrCe_{0.95}Yb_{0.05}O_{2.975}$ system.

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