• Title/Summary/Keyword: Asymmetric Surface

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Effect of structure of PVDF membranes on the performance of membrane distillation

  • Chang, Hsu-Hsien;Tsai, Chih-Hao;Wei, Hao-Cheng;Cheng, Liao-Ping
    • Membrane and Water Treatment
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    • v.5 no.1
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    • pp.41-56
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    • 2014
  • A series of microporous PVDF membranes were prepared by isothermal immersionprecipitation of PVDF/TEP casting dopes in both soft and harsh coagulation baths. Morphologies of the membranes' top surfaces were found to depend strongly on the bath strength, which could be controlled by the TEP content in the bath. By changing the bath gradually from pure water to 70% TEP, the top surface evolved from a dense skin-like (asymmetric) to a totally open porous morphology (symmetric). The latter structure could similarly be obtained by precipitation of the same dope in an alcoholic bath, e.g., 1-butanol. Membrane distillation processes to desalt sodium chloride aqueous solutions were conducted using various prepared membranes and two commercial microporous membranes, PTFE (Toyo, Japan, code: J020A330R) and PVDF (GE, USA, code: YMJWSP3001). The permeation fluxes were compared and correlated with the morphologies of the tested membranes.

Enhanced flexoelectric switching made from self-assembly of smectic liquid crystal and triallyl dopant

  • Lim, Tong-Kun;Lee, Ji-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.175-177
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    • 2006
  • Here we report an enhanced flexoelectric switching in a self-assembled system of smectic liquid crystal and some specific dopant. The assembled unit block seemed to have electric dipole and as a result induces large flexoelectric polarization due to its asymmetric shape and shows fast switching to the electric field. The unit blocks are oriented in a helical fashion in the cell with large gap (${\sim}5{\mu}m$) and shows selective reflection property. In the thin cell (${\sim}2{\mu}m$), the unit blocks are aligned homeotropically on the bare ITO substrate with no surface treatment and shows fast decaying time.

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Effect of Surface Roughness on Turbulent Concentric Annular Flows (난류 이중동심관 유동에 미치는 표면거칠기 효과)

  • 김경천;안수환;정양범
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1749-1757
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    • 1995
  • The structure of turbulence of fully developed flow through three concentric annuli with both rough inner and outer walls was investigated experimentally for Reynolds number range Re=15000-93000. Turbulence intensities were measured in three (u, v, w) directions, and turbulence shear stresses in annuli of radius ratios .alpha.= 0.26, 0.4 and 0.56, respectively. The result showed that the structure of turbulence for these asymmetric flows was not the same as that for the annulus with smooth walls. The velocity fluctuations of all three components (u, v, and w-directions) showed little discernible variation with Reynolds numbers, but became apparent with the influence of radius ratio (.alpha.) The experimental results for an annulus with the roughened outer wall and a smooth annulus were shown in the figures as a reference. The eddy diffusivities and friction factors were also presented and discussed.

Hydrophobic Membrans of Tetrafluoroethylene and 2,2,4, Trifluoro 5 Trifluorometoxy 1,3 Dioxole

  • Gordano, A.;Clarizia, G.;Tocci, E.;Drioli, E.
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.50-58
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    • 1999
  • Symmetric asymmetric and composite perfluoropolymer membranes made with HYFLON AD have been prepared and evaluated. Porous and non porous symmetric membranes have been prepared by solvent evaporation with various processing conditions. Non-contact atomic force microscopy (AFM) was used to investigate the membrane morphology in air. Analysis of the images gave quantitative imformation on the surface pore strcture in particular on the pore size distributin. Possible useful uses of porous membranes are envisaged in the field of gas-liquid separations such as membrane contactors (MSc) Molecular Dynamics(MD) simulations structure of HYFLON AD 60X copolymer supporting these results are also reported. Amorphous perfluoropolymer membranes appears to be ideal other than in MCs when separation processes have to be performed in hostile environments i.e. high temperatures and aggressive non-aqueous media such as chemicals and solvents. In these cases HYFLON AD mem-branes can exploit the outstanding resistance of perfluoropolymers.

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A Study on Transfer Process Design on Hot Forging of Bearing Hub (베어링 허브의 트랜스퍼 열간 단조 공정 설계에 관한 연구)

  • Byun H.S.;Kim B.M.;Ko D.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.993-996
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    • 2005
  • This paper is concerned with transfer process on hot forging of bearing hub. Workers on hot forging have difficulty in working by high temperature and weight workpiece. And In conventional got forging of bearing hub, the material wasted to the flash accounts approximately 10% of the original workpiece. It is need manufacture automation and reduce the cost of forged products. Surface treatment of die and lubricant are investigated from experiment and FE-simulation for analysis of forming simulation. In order to hot forging process design considered flash thickness and blocker geometry and initial temperature of die and billet. This transfer process gave comparatively good results compared with actual products.

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Automatic Intelligent Asymmetry Detection Using Digital Infrared Imaging with K-Means Clustering

  • Kim, Kwang Baek;Song, Doo Hoen
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.15 no.3
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    • pp.180-185
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    • 2015
  • Digital infrared thermal imaging is a non-invasive adjunctive diagnostic technique that allows an examiner to visualize and quantify changes in skin surface temperature. The asymmetry of temperature differences between the diseased and the contralateral healthy body parts can be automatically analyzed and has been studied in many areas of medical science. In this paper, we propose a method for intelligent automatic asymmetry detection based on a K-means analysis and a YCbCr color model. The implemented software successfully visualizes an asymmetric distribution of colors with respect to the patients’ health status.

Electrochemical Studies of Viologens in Homogeneous Aqueous and Sodium Dodecyl Sulfate Micellar Solutions

  • Park Joon Woo;Ko Seung Hyeon;Park Jong-Yoon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.3
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    • pp.259-265
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    • 1992
  • Cyclic voltammetric behavior of symmetric (dimethyl, diheptyl, dioctyl, dibenzyl) and asymmetric (methyloctyl, methyldodecyl, methylbenzyl) viologens was investigated in homogeneous aqueous solution and sodium dodecyl sulfate (SDS) micellar media. In SDS-free 0.1 M NaCl solutions, the reduction potential is less negative as the chain length of alkyl substituent is longer. This is due to the stabilization of the reduced cationic radical and neutral form of viologen by adsorption on electrode surface. The adsorbed species show the "aging-effect". With the exceptions of methyldodecyl viologen and methylbenzyl viologen, the viologens show strong tendency of conproportionation reaction between viologen dications and neutral forms. In cases of methyldodecyl viologen and methylbenzyl viologen, the conproportionation reaction is kinetically disfavored, though it is thermodynamically favorable. SDS micelles dissolve the adsorbed species and the viologens exhibit two reversible redox processes in SDS micellar solutions. The reduction potentials of viologens in SDS micellar solutions depend little on the length of alkyl chain. Benzyl-substituted viologens are more easily reduced than the alkyl substituted viologens, presumably due to electron-withdrawing character of benzyl group.

Recovery of inferior alveolar nerve injury after bilateral sagittal split ramus osteotomy (BSSRO): a retrospective study

  • Lee, Chi-Heun;Lee, Baek-Soo;Choi, Byung-Joon;Lee, Jung-Woo;Ohe, Joo-Young;Yoo, Hee-Young;Kwon, Yong-Dae;Kwon, Yong-Dae
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.38
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    • pp.25.1-25.4
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    • 2016
  • Background: Bilateral sagittal split ramus osteotomy (BSSRO) is the most widely used mandibular surgical technique in orthognathic surgery and is easy to relocate the distal segments, accelerating bone repair by the large surface of bone contact. However, it can cause neurosensory dysfunction (NSD) or sensory loss by injury of the inferior alveolar nerve. The purpose of the present study was to evaluate NSD after BSSRO and modifiers at NSD recovery. Methods: In this study, NSD characteristics after BSSRO from 2009 to 2014 at the Kyung Hee University Dental Hospital were evaluated. The pattern of sensory recovery over time was also evaluated based on factors such as field of sensory dysfunction, surgical procedure, presence of pre-operative facial asymmetry, and postoperative medications. Results: Most of the patients had shown NSD immediately after orthognathic surgery. Among the 1192 sides of 596 patients, NSD was observed in 953 sides and 544 patients. Sexual predilection was shown in males (p value = 0.0062). In the asymmetric group of 132 patients, NSD was observed in 128 patients (96.97 %). In the symmetric group of 464 patients, NSD was observed in 416 patients (89.45 %); on the other hand, NSD was observed significantly higher in the asymmetric group (p = 0.025). NSD-associated factors were analyzed, and vitamin B12 may be beneficial for NSD recovery. Conclusions: There was a difference between the symmetric group and the asymmetric group in NSD recovery. Vitamin B12 can be regarded as an effective method to nerve recovery. However, a further prospective study is needed.

The Study of Transmittance and Conductivity in ZnO/Ag Multilayer Films (ZnO/Ag Multilayer의 투과율과 전도성에 관한 연구)

  • Kim, Yun-Hae;Kim, Do-Wan;Murakami, Ri-Ichi;Moon, Kyung-Man;Lee, Sung-Yul
    • Journal of Ocean Engineering and Technology
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    • v.25 no.1
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    • pp.39-43
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    • 2011
  • This study has lowered the specific resistance by coating a thin film layer of Ag, playing the role of the electron donor on the ZnO that is used usefully for the transparent conductive oxides. Presently, this study has examined the transmittance and electric characteristics according to the thickness of the Ag thin film layer. Also, this study has observed the transmittance and electric characteristics according to the uppermost ZnO thin film layer of ZnO/Ag/ZnO symmetric film and has conducted the theoretical investigation. In order to observe the transmittance and electric characteristics according to the thickness of the Ag thin film layer and the uppermost ZnO thin film layer, this study conducted the film deposition at room temperature while making use of the DC magnetron sputtering system. In order to see the changes in the thickness of the Ag thin film layer, this study coated a thin film while increasing by 4nm; and, in order to see the changes in the thickness of uppermost ZnO thin film layer, it performed the thin film coating by increasing by 5nm. From the experimental result, the researchers observed that the best transmittance could be obtained when the thickness of the Ag thin film layer was 8nm, but the resistance and mobility increased as the thickness got larger. On the other hand, when the thickness of the uppermost ZnO thin film layer was 20nm, the experiment yielded the best transmittance with excellent electric characteristics. Also, when compared the ZnO/Ag asymmetric film with the ZnO/Ag/ZnO symmetric film, the ZnO/Ag asymmetric film showed better transmittance and electric characteristics.

Biophysical Effects Simulated by an Ocean General Circulation Model Coupled with a Biogeochemical Model in the Tropical Pacific

  • Park, Hyo-Jin;Moon, Byung-Kwon;Wie, Jieun;Kim, Ki-Young;Lee, Johan;Byun, Young-Hwa
    • Journal of the Korean earth science society
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    • v.38 no.7
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    • pp.469-480
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    • 2017
  • Controversy has surrounded the potential impacts of phytoplankton on the tropical climate, since climate models produce diverse behaviors in terms of the equatorial mean state and El $Ni{\tilde{n}}o$-Southern Oscillation (ENSO) amplitude. We explored biophysical impacts on the tropical ocean temperature using an ocean general circulation model coupled to a biogeochemistry model in which chlorophyll can modify solar attenuation and in turn feed back to ocean physics. Compared with a control model run excluding biophysical processes, our model with biogeochemistry showed that subsurface chlorophyll concentrations led to an increase in sea surface temperature (particularly in the western Pacific) via horizontal accumulation of heat contents. In the central Pacific, however, a mild cold anomaly appeared, accompanying the strengthened westward currents. The magnitude and skewness of ENSO were also modulated by biophysical feedbacks resulting from the chlorophyll affecting El $Ni{\tilde{n}}o$ and La $Ni{\tilde{n}}a$ in an asymmetric way. That is, El $Ni{\tilde{n}}o$ conditions were intensified by the higher contribution of the second baroclinic mode to sea surface temperature anomalies, whereas La $Ni{\tilde{n}}a$ conditions were slightly weakened by the absorption of shortwave radiation by phytoplankton. In our model experiments, the intensification of El $Ni{\tilde{n}}o$ was more dominant than the dampening of La $Ni{\tilde{n}}a$, resulting in the amplification of ENSO and higher skewness.