• 자원리싸이클링
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• 제16권1호
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• pp.68-72
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• 2007

전기적 환원을 이용한 인공 사진폐수에서의 은 회수를 연속순환식 공정을 적용하여 환원시간 및 두 전극간의 전합 차, 농도유량에 따른 영향을 검토하였다. 은 함유 인공폐수 처리에 있어 적용(인가) 전압과 초기 농도가 증가함에 따라 제거율이 증가함을 보였다. 은 함유 인공폐수의 전해 반응 시, 음극에 환원 석출된 물질의 정성적인 분석을 위해 EPMA 및 XRD 분석 결과, 석출된 물질이 은임을 확인하였다.

• 한국물환경학회지
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• 제23권5호
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• pp.577-580
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• 2007

The influence of flow rate has been investigated on the treatment efficiency of continuous cycling electrolytic process employing artificial and actual photographic wastewater which containing silver ion. For artificial wastewater, the treatment efficiency of process was found to rise ca. three times when the flow rate of wastewater was increased from 3 mL/min to 15 mL/min. The process efficiency was doubled under the same condition regarding actual wastewater. The effect of flow rate on the treatment efficiency was observed to be altered according to the metal ionic form and solution composition. The coefficient of mass transfer was estimated using model equation, which verified that the raised treatment efficiency at higher flow rate was due to the increased mobility of ionic species.