• 분석과학
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• 제26권3호
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• pp.190-198
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• 2013

호박은 오래전부터 장식품, 공예품, 부장품 등으로 사용되어 매장문화재 형태로 발굴되고 있다. 발굴 당시 호박은 풍화가 많이 진행되어 표면의 균열, 박락 등이 관찰된다. 풍화에 따른 호박의 성분 변화를 파악하는 것은 보존상태를 진단하고, 적절한 보존방법을 적용하는데 있어 매우 중요하다. 본 연구에서는 열분해/GC/MS로 호박의 열분해 산물을 분석하여 호박을 구성하는 성분을 찾고자 하였다. 또한, 열과 산소가 있는 조건에서 60일 동안 인공열화하여 호박의 열분해 산물의 구성비가 변화하는 것을 관찰하였다. 실험결과 호박의 주요 열분해 산물로 abietic acid가 검출되었고, monoterpene류, alkene류, aromatic hydrocarbon류가 검출되었다. 주요한 23개의 성분에 대해 열화에 따른 상대적인 면적비를 비교하여 열화에 따른 경향성을 파악하였다. 주성분인 abietic acid는 산소와 열이 있는 조건에서 급격하게 감소하였지만, 열만 있는 조건에서는 변화가 크지 않은 것으로 보아 산소가 호박의 열화에 중요한 역할을 하는 것으로 판단된다. 실제 풍화된 호박 원석의 표면에 대해 열화실험 결과를 적용하여 열화상태를 파악하는 시도도 하였다.

• The Journal of Advanced Prosthodontics
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• 제12권3호
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• pp.150-156
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• 2020

PURPOSE. The aim of this study was to evaluate the effect of different surface finishing processes on the color stabilities of lithium disilicate glass-ceramics, zirconia-reinforced lithium silicate ceramics, and resin nanoceramics after artificial ageing. MATERIALS AND METHODS. 216 samples were prepared from 3 different CAD/CAM materials (LAVA Ultimate, IPS e.max CAD, VITA Suprinity) with A1 HT color at a size of 14 × 12 mm and a thickness of 0.5 ± 0.05 mm. Color measurements of the samples were performed with a spectrophotometer using color parameters and CIE Lab color system on a gray backing between baseline color and after 5000 cycles of artificial ageing in 4 stages (i.e. the first measurement before the treatment, the second measurement after polishing, the third measurement after cement application, and the fourth measurement after artificial ageing). The results were evaluated using the Variance analysis and Fisher's LSD test. RESULTS. Resin nanoceramics (LU) exhibited higher color change values than zirconia-reinforced lithium silicate (VS) and lithium disilicate (EC) ceramics after artificial ageing. Manual polishing and glazing resulted in similar color change for LU and VS (P>.05). In the EC group, glazing provided statistically different results as compared to the manual polishing and control groups (P<.05). Among the ceramic groups, color change values of the subgroup, which was treated by glazing, of the zirconia-reinforced lithium silicate (VS) and lithium disilicate (EC) samples were below the clinically acceptable level (ΔE < 3.5). CONCLUSION. The lowest color change for all stages was observed in Vita Suprinity.

• 보존과학연구
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• 통권30호
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• pp.93-102
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• 2009

This study was carried out to investigate the effect of artificial accelerated ageing treatment on the permanence of lining papers produced from Korea and Japan. As time gone by, organic cultural properties are affected by chemical and physical deterioration because of various factors including the conditions of preservation environment and their material properties. In the public historical storage or owned as private collections, are vulnerable to sever amages caused by poor preservation environment as well as by other natural factors. In this study, the deterioration behaviors of lining paper in optical & mechanical properties were discussed. Overall, lining papers produced from Korea showed lower reduction in mechanical strength properties compared to the lining papers produced from Japan.

• 보존과학회지
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• 제36권1호
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• pp.1-14
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• 2020

This study investigates the crystallinity distribution of ancient silk. Owing to the inherent multi-hierarchical structure of silk protein and the complicated structural changes that occur due to various burial environments, it is challenging but worthwhile to study ancient silk ageing behavior, which is based on the fact that ageing begins with a single fiber and then spreads to a whole fabric. Crystallinity was one of the most effective indicators found to reveal the ageing status of silk. Therefore, a synchrotron radiation-based X-ray diffraction(SR-XRD) method was employed to study the crystallinity distribution of single fibers of ancient silk unearthed from seven archaeological sites in China from historical periods including the warring states, Han dynasty, Song dynasty, and Ming dynasty. In comparison, the conventional X-ray diffraction method, which uses large amounts of samples, was also performed to determine the integral crystallinity of ancient silk. Thermal stability experiments by thermogravimetry(TG) as well as morphology observations by scanning electron microscopy(SEM) and optical microscopy(OM) all confirmed the deterioration of ancient silk. Moreover, the ageing mechanism of ancient silk was proposed with the assistance of an artificial ageing study. The results confirmed the effectiveness of SR-XRD as an ageing indicator, revealing the crystallinity distribution. This research could provide motivation to determine the deterioration status of ancient silk, and would also aid in explaining the fragility of ancient silk due to ageing.

• 대한기계학회논문집A
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• 제35권7호
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• pp.717-722
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• 2011

본 연구의 목적은 Al6061 의 T6 열처리 시 발생되는 잔류응력의 변화를 예측하는 것이다. Al6061-T6 의 일반적인 열처리 조건인 용체화처리($530^{\circ}C$, 2hr)와 인공시효($175^{\circ}C$, 9hr)에서 인공시효 시간에 따라 잔류응력 변화를 고려하였다. 잔류응력 예측은 열처리 실험을 수행하여 대류 열전달계수를 확보하고, 탄소성 모델로 가정한 유한요소해석을 적용하였다. 또한 인공시효와 같이 재료가 고온에서 장시간 유지되는 경우의 Zener-Wert-Avrami 함수를 적용하여 잔류응력 변화를 확인하였다. 잔류응력의 측정은 X 선 회절법으로 측정하고 측정결과는 예측된 유한요소해석 결과와 비교하여 해석의 신뢰성을 확보하고 해석기법을 확립하였다.

• 한국전기전자재료학회논문지
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• 제12권1호
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• pp.1-10
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• 1999

In this paper, we have investigated the effects of the environmental factors on Low Molecular Weight (LMW) silicone fluid contents existing in high temperature vulcanized (HTV) silicone rubber sample, using dipping method and contact angle, current measurement. Artificial treatments such as immersion in water, elevated temperature, UV irradiation and dry band arcing under salt-fog condition are selected as the environmental factors. This results will be helpful to investigate the degradation with time and to expect a life time, because the LMW silicone content, which is important to recovery the hydrophobicity of silicone rubber surface, show different results by each environmental factors.

• 한국주조공학회지
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• 제38권5호
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• pp.95-102
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• 2018

The dependence of the tensile properties on variations in the porosity of A356 aluminium alloys was investigated in terms of the quality index of the tensile properties based upon the ultimate tensile strength and elongation as well as the variation of the strength coefficient and strain-hardening exponent with regard to a T6 treatment. The test specimens were prepared by low-pressure die-casting and a subsequent T6 treatment, and the experimental results of a tensile test carried out at room temperature were compared to the theoretical description using a modified constitutive model. The nominal value of the quality index of A356 alloys increases gradually with a lapse of the ageing time upon a T6 treatment, despite the fact that this value is temporarily decreased during the initial stage of ageing from a solutionised condition. Additionally, the quality index depends practically upon the porosity variation with a power law relationship without regard to whether in solutionised or artificial aged conditions. The theoretical description indicates that the strength coefficient directly determines the nominal level of the quality index. Moreover, the overall dependence of the quality index on the porosity variation is remarkably weakened with an increase in the tensile strain, whereas the quality index depends sensitively upon the porosity variation with a low value of the strain-hardening exponent.

• 펄프종이기술
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• 제40권1호
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• pp.55-61
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• 2008

The annals of Joseon Dynasty is the most valuable resource containing the record of Korean history and has been known as one of the UNESCO's Memory of the World Register. In some period, wax-treated paper was used in the annals of Joseon Dynasty to prevent the damage from pests. But, wax-treated volumes were discolored to brown, white or black, and partially cracked by the stiffened wax. It means that wax-treated volumes were damaged by the hardening and oxidizing of wax. The wax is considered as the first reason in damages on the wax-treated volume. Therefore, in this study we analysed the oxidation index of Korea traditional paper(Hanji) which is used as the restoration paper of the waxed volume in the annals of Joseon Dynasty by using FT-IR. As the analysis of FT-IR, the traditional two-layed stamping paper (Hanji sample F), which was treated by starch in its surface, was shown the most stable state after the accelerated ageing test.

• Progress in Superconductivity
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• 제11권1호
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• pp.13-18
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• 2009

Partial discharge measurements in cryogenic dielectric materials of HTS transformer are very important because partial discharge was regarded as primary source for ageing and breakdown of cryogenic materials. But, partial discharge measurement techniques and its effects in low temperature high voltage environments were not suggested and there exist only a few reports on this research fields. Therefore, in order to implement reliable HTS transformers, partial discharge diagnosis techniques for cryogenic materials of HTS transformers were investigated using partial discharge (PD) pattern analysis methods. In this works, four different types of artificial defects including turn to turn insulation, free moving particle, void and protrusion, have been fabricated since it was commonly regarded that they might cause the sudden service failures of the power apparatus. For this purpose, these defects are installed into the dielectric materials in liquid nitrogen and experimental investigations have been carried out for the diagnosis of HTS transformer. And various PD patterns caused by the amount of quench of superconductors were analyzed. Throughout this works, the different PD patterns in cryogenic dielectric materials in liquid nitrogen, and PD measuring technique could be the fundamental steps to establish diagnosis technologies of HTS transformer for power applications.

• 전기학회논문지
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• 제60권10호
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• pp.1966-1971
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• 2011

Generally, the characteristics of the conductor that was affected by forest fire can be analyzed only when the forest fire is accurately modeled and its effect is identified. Few studies have been conducted with a forest fire model for transmission lines, and no results of the examination of the actual test specimens that were exposed to forest fire have been reported. As the deterioration characteristics of a forest fire are difficult to analyze in the actual field, an environment that was similar to that in the field was used in this study. Deterioration was deposited on a wire using an artificial flame experiment device, to analysis the temperature, surface and component characteristics. It seems that this analysis data in this study can be used as the basic data for the database that can be utilized to analyze wires exposed to forest fire and deterioration and to predict the ACSR wire refurnishment life.