• 제목/요약/키워드: Arsenopyrite

검색결과 102건 처리시간 0.019초

아르헨티나 후후이주 삐르키타스광산의 현장조사 연구 (Field Study of Pirquitas mine in Jujuy Province, NW Argentina)

  • 이한영
    • 암석학회지
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    • 제16권4호
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    • pp.189-195
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    • 2007
  • 아르헨티나 후후이주 뿌나지역 빠르끼따스광산은 오르도비시안 퇴적암에 제3기 석영안산암이 다양한 천열수 석영맥을 형성하면서 Sn-Ag 광물들을 배태한 볼리비안형 광상이다. 주광종은 주석석이며 부광종은 황철석, 유비철석, 자류철석 등이다. 예상매장량은 2억톤이며 현재 하루생산량은 5천톤이며 탐사와 개발을 병행하고 있고 갱내채굴을 하고 있지만 조만간 노천채굴을 시작할 예정이다. 소유주는 캐나다의 Siver Standard Resources 회사이다. 광산위치는 $S22^{\circ}30'25.0",\;66^{\circ}15'22.5"$, 해발 4086 m이다. 인프라와 지질여건, 매장량 등을 고려할 때 국내기업이 지분참여를 할 만한 가능성 있는 지역이다.

강원도 옥계 금광상에 관한 광물학적·지화학적 연구 (Mineralogy and Geochemistry of the Ogkye Gold Deposits, Gangwondo Province)

  • 최선규;최상훈;이현구
    • 자원환경지질
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    • 제30권1호
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    • pp.15-23
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    • 1997
  • Gold mineralization of the Ogkye gold mine was deposited mainly in quartz veins up to 150 cm wide which occupy fissures in Cambrian Pungchon limestone. Ore minerals are relatively simple as follows: pyrite, arsenopyrite, pyrrhotite, sphalerite, electrum and galena. On the basis of the Ag/Au ratio on ore grades, mode of occurrence and assoicated mineral assemblages, the Ogkye gold deposit can be classified as pyrite-type gold deposit (Group IIB). Fluid inclusion data indicate that ore minerals were deposited between $400^{\circ}$and $230^{\circ}C$ from relatively dilute fluids (0.2 to 7.3 wt.% eq. NaCl) containing $CO_2$. The ore mineralization resulted from a complex history of $CO_2$ effervescence and local concomitant boiling coupled with cooling and dilution of ore fluids. Gold deposition was likely a result of decrease of sulfur activity caused by sulfide deposition and/or $H_2S$ loss accompanying fluid unmixing. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S=3.5{\sim}5.9$‰) are consistent with ${\delta}^{34}S_{H_2S}$ value of 4.8 to 6.1‰, suggesting mainly an igneous source of sulfur partially mixed with wall-rock sulfur.

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장군광산(將軍鑛山)의 자철석광상(磁鐵石鑛床)에서 산출(産出)되는 광석광물(鑛石鑛物)과 생성조건(生成條件) (Ore Minerals and Mineralization Conditions of Magnetite Deposits in the Janggun Mine, Korea)

  • 이현구;이찬희;송석환
    • 자원환경지질
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    • 제29권1호
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    • pp.1-11
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    • 1996
  • Magnetite ores of the Janggun mine are embedded in dolomitic limestone of the Janggun Limestone Formation contacting with Chunyang granite, and are closely associated with skarn minerals. Mineralization of magnetite deposits can be divided into two stages as deep-seated skarn stage and shallow hydrothermal replacement stage. Mineralogies of skarn stage consist of magnetite, pyrrhotite and base-metal sulfides, and those of hydrothermal stage is base-metal sulfides, native bismuth, bismuthinite, tetrahedrite, boulangerite, bournonite and stannite. The FeS mole % in sphalerite and As atom % in arsenopyrite range from 22.47 to 26.30 and from 31.39 to 31.66 in skarn stage, and are from 17.54 to 32.54 and 28.87 to 30.70 in hydrothermal stage, respectively. Based on mineralization characteristics, mineral assemblages, chemical compositions and thermodynamic considerations, formation temperatures, sulfur fugacities ($-logf_2$), pH and oxygen fugacity ($-logfo_2$) estimated to be from 345 to $382^{\circ}C$, from 8.1 to 9.7atm, from 6.5 to 7.2 and from 30.5 to 31.2atm in the skarn stage, respectively, and temperature and $-logfs_2$ are from 245 to $315^{\circ}C$ and from 10.4 to 13.2atm in the hydrothermal stage.

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광양금광상(光陽金鑛床), 고흥동광상(高興銅鑛床)의 광상생성(鑛床生成)과 암석학적(岩石學的) 연구(硏究) (Metallogenesis and Petrology of the Gwangyang Gold Deposits and Goheung Copper Deposits)

  • 박영석;신병우
    • 자원환경지질
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    • 제17권2호
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    • pp.91-100
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    • 1984
  • The Gwangyang gold deposits geologically consist of granitic gneiss, metatectic gneiss and porphyroblastic gneiss which correspond to Jirisan gneiss complex. The formations of Gyeongsang system lies unconformably on these gneisses and are intruded by diorite, porphyritic andesite and Bulgugsa granites. Goheung districts are composed of quartz schist, andesitic rock, tuff and granite. The Gwangyang gold deposits are gold bearing fissure filling veins. The vein thickness varies from 15cm to 40cm and they consist of 7-10 layers in parallel. The Goheung copper deposits are sulphide bearing quartz veln which filled the fracture in andesitic rock and biotite granite. The contact zone of these rocks is partially altered. The mineral paragenesis of the Gwangyang and Goheung districts is pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, galena, sericite, quartz and calcite. The variation trends of FMA and A'KF triangular diagrams and the differentiation index (norm, Q + Or + Ab) versus oxides diagrams is similar to the Gyeonsang basin igneous rocks. From the trace element analysis of 10 samples of country rocks, wall rocks and veins, the distribution of copper and lead contents display a correlative distribution pattern in relation to gold and silver. Homogenization temperature of fluid inclusions range from $200^{\circ}C$ to $270^{\circ}C$ in quartz from the Gwangyang gold vein and the size of fluid inclusion range from 0.01mm to 0.04mm. The fluid inclusions are mainly one or two phase and the filling degree of the inclusions varies from 85 to 95.

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무극광산(無極鑛山)의 탐사(探査)와 개발현황(開發現況) (Exploration and Development of the Muguk Au Mine)

  • 신양우;서규식
    • 자원환경지질
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    • 제20권4호
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    • pp.261-271
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    • 1987
  • Muguk gold deposits are composed of quartz veins emplaced along faults in Mesozoic granodiorite. General strikes and dips of the veins are $N15{\sim}20^{\circ}W$ and $70{\sim}80^{\circ}NE$. Associated ore minerals are pyrite, arsenopyrite, sphalerite, galena, chalcopyrite, pyrrhotite, native silver, argentite, tetrahedrite and electrum. Vein mineral paragenesis is complicated by repeated fracturing, but five distinct depositional stages can be recognized. Electrum grains are associated mainly with sulfide bands formed along both margins of pale pink quartz of stage 3, and with patches of pyrite aggregate of stage 4. Before the close down in 1972, Muguk gold mine yielded more than 8 tons of gold of which major portion was produced from the No.2 vein. No.2 vein, extending about 1,500m laterally, was exploited to a depth of about 750m. In 1984, Young-poong mining company acquired the mining property and began geologic mapping, geochemical and geophysical exploration, diamond drilling and exploration tunnelling around the mine area to seek for other rich gold-bearing quartz veins. As the Samhyungje vein was disclosed to be the most rich vein, exploration works were focussed on the Samhyungje vein. As of August 1987, 22,338m of diamond drilling and 9,652m of exploration tunnelling have been undertaken. Owing to the successful result of exploration, the Muguk mine commenced normal operation on January 1987, treating 5,500 tons of ore per month.

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태백산광화대내의 원동 다금속광상의 성인 (Ore Genesis of the Wondong Polymetallic Mineral Deposits in the Taebaegsan Metallogenic Province)

  • 황덕환;이재영
    • 자원환경지질
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    • 제31권5호
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    • pp.375-388
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    • 1998
  • The purpose of this study is to investigate the ore genesis and occurrence of the Wondong polymetallic mineral deposits. The Pb-Zn, Fe and W-Mo mineralizations are found in skarn zones which formed mainly in or along the fault shear zones with the $N25-40^{\circ}W$ and $N10-50^{\circ}E$ directions, whereas the Cu-Mo mineralization is appeared hydrothermal replacement zone. The skarn minerals consist mainly of garnet and epidote, which were the last alteration phases between pneumatolytic and hydrothermal stages. The mineral paragenesis toward the late stage are as follows: arsenopyrite, scheelite, magnetite, pyrite, pyrrhotite, sphalerite, galena, chalcopyrite and molybdenite. Average ore grades are 0.33 g/t Au, 46.29 g/t Ag, 0.06% Cu, 4.4% Pb, 2.61% Zn and 29.39% Fe in tunnels, and 0.31 % Cu, 0.52% Pb, 6.29% Zn, 29.29% Fe, 0.03% Mo and 0.12% $WO_3$ in drill cores. Fluid inclusion data shows that Type I (liquid-rich), Type II (vapor-rich) and Type III (halite-bearing) inclusions are coexisted and their homogenization temperatures are quite similar. This indicates that boiling conditions have been reached during the mineralization. It is also likely that the ore solutions were evolved through the mixing between magmatic and meteoric waters. Rhyolite and quartz porphyry far the mineralization probably are not responsible of the Wondong polymetallic mineral deposits.

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충남(忠南) 대봉(大鳳) 금(金)·은광상(銀鑛床)에서 산출(産出)되는 광석광물(鑛石鑛物)과 광상(鑛床)의 생성환경(生成環境) (Mineralogy and Ore Geneses of the Daebong Gold-Silver Deposits, Chungnam, Korea)

  • 이현구;유봉철;김상중
    • 자원환경지질
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    • 제25권3호
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    • pp.297-316
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    • 1992
  • The Daebong gold-silver deposits is located in 8 km southwest of Cheongyang, Chungcheongnam-Do, Republic of Korea. The gold-silver-bearing hydrothermal quartz veins was formed within the Precambrian metasediments of Gyeonggi massif. Ore minerals occur as mainly of pyrite, sphalerite (0.78~6.19 wt.% Cd), galena, pyrrhotite and minor amounts of chalcopyrite, arsenopyrite, magnetite, ilmenite, chalcocite, electrum (55.00~89.55 wt.% Au) and argentite. The gangue minerals are quartz, calcite, chlorite, K-feldspar, biotite. Wall-rock alterations such as chloritization, silicification, pyritization, carbonatization and sericitization can be observed near the quartz veins. According to the mineral paragenetic sequence based on vein structure and mineral assemblages, three stage mineralizations can be recognized. Fluid inclusion, sulfur isotope and thermodynamic data show that the ore minerals were dominantly deposited at the between 388 and $204^{\circ}C$ from fluids with salinities of 8.1~0.3 wt.% equivalent NaCl, and sulfur isotope value 4.84 to 6.40 per mil of sulfides indicates igneous sources of sulfur in the hydrothermal system and fluid inclusion salinity data suggest that thermal fluids may have magmatic origin with some degree mixing of meteoric water.

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제이연화광산(第二蓮花鑛山)의 지질광상(地質鑛床)에 대(對)하여 (Geologic Report of the Second Yeonhwa Mine, Kangwon Province, Korea)

  • 한갑수
    • 자원환경지질
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    • 제5권4호
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    • pp.211-217
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    • 1972
  • The Second Yeon Hwa Mine which belongs to a so called Lead-Zines Belt Area in the central east Korea is located at about 10 km northeast of the Seogpo railway station on Yeongdong Line. The exploitation of the mine started in June, 1969 and furnished the machinary ore dressing plant in November, 1971. The current monthly production of rude ore is 15,000 meteric tons. The results of the study on the lead-zinc-copper deposits of the Second Yeonhwa mine are summerized as follows: (1) main ore deposits of the mine are localized in the Pungchon Limestion formation of Cambrian age, (2) related ingneous rock with ore deposits is granite porphyry, which distributed in NS and $N50^{\circ}W$ trend, (3) ore solution ascended along the $N50^{\circ}W$ trend which represents folding axis and fault plane and mineralized selectively in the limestone formation. (4) high grade ore deposits are localized in concave and convex boundaries of granite porphyry, and hanging walls of shale bed ($P_2S$ shale bed) in Pungchon Limestone formation and (5) skarn minerals are consisted of garnet, hedenbergite, diopside, and sulfide minerals are composed of zincblenede, galena, phyrhotite, pyrite and some amount of chalcopyrite and arsenopyrite.

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한국(韓國) 장군광산(將軍鑛山)의 황석석(黃錫石)에 대(對)하여 -장군(將軍) 연(鉛)·아연(亞鉛)·은(銀) 광석광물(鑛石鑛物)의 지식(知識)에의 기여(寄與) (3)- (Stannite from the Janggun Mine, Republic of Korea -Contributions to the Knowledge of Ore-Forming Minerals in the Janggun Lead-Zinc-Silver (3)-)

  • 이현구;이마이 나오야
    • 자원환경지질
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    • 제19권spc호
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    • pp.121-130
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    • 1986
  • In the Janggun mine, stannite occurs as anhedral grains, up to 500 micrometer in long dimension, closely associated with sphalerite, chalcopyrite, arsenopyrite, pyrrhotite, galena and rhodochrosite in the periphery of the South ore body. In reflected light, stannite is grayish yellow green in color and exhibits moderate bireflectance and strong anisotropism without any intenal reflections. Reflection; Rmax. =29.0, Rmin. =27.8 percent at a wavelength of 560nm, and VHN; 219~244kg/mm at a 50g load. The chemical composition on the average from 35 spot analyses by electron microprobe is, Cu 28.0, Fe 12.7, Zn 2.9, Mn 0.2, Sn 25.8, S 30.3, sum 99.9 (all in weight percent); the corresponding chemical formula as calculated on the basis of total atoms=8 is, Cu 1.88 Fe 0.97 Zn 0.19 Mn 0.02 Sn 0.93 S 4.01, which fulfills approximately the ideal formula of $Cu_2FeSnS_4$. The strongest reflections on the X-ray diffraction patterns are; $3.10{\AA}$ (10) (112), $2.72{\AA}$ (5) (020, 004), $1.922{\AA}$ (5) (024), $1.642{\AA}$ (3) (132), $1.244{\AA}$ (3) (143, 136, 235), $1.111{\AA}$(3) (244), $0.958{\AA}$ (1) (048, 422), the patterns are identical with those of literature. From the textural evidence of the microscopic observation, the mineral is considered to have been formed at the middle stage of hydrothermal lead-zinc-silver mineralization.

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영덕(盈德) 금(金)-은광상(銀鑛床)에서 산출(産出)되는 금(金)-은광물(銀鑛物)과 광상(鑛床)의 생성환경(生成環境) (Au-Ag Minerals and Genetic Environments from the Yeongdeog Gold-Silver Deposits, Korea)

  • 이현구;유봉철;김상중
    • 자원환경지질
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    • 제28권6호
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    • pp.541-551
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    • 1995
  • The Yeongdeog gold-silver deposits at Jipum, Gyeongsangbugdo, is of a middle Paleogene $(45.52{\pm}1.02Ma)$ vein type, and is hosted in shale and sandstone of Cretaceous age. Based on mineral paragenesis, vein structure and mineral assemblages, the ore mineralization can be divided into two distinct depositional stages. The early stage is associated with base-metals such as pyrite, arsenopyrite (27.99~30.99 at%), hematite, rutile, pyrrhotite, sphalerite (10.53~18.42 FeS mole%), chalcopyrite and galena with wallrock alteration such as chlorite, sericite and pyrite. The late stage is characterized by the Au-Ag mineralization such as electrum, Ag-bearing tetrahedrite, freibergite, pyrargyrite, unidentified mineral, pyrite, sphalerite (1.08~5.57 FeS mole%), chalcopyrite and galena. Fluid inclusion data indicate that fluid temperatures and salinities range from 343 to $227^{\circ}C$ and from 8.3 to 5.7 wt% eq. NaCl in early stage, respectively. Temperatures and salinities of NaCl eq. wt% range from 299 to $225^{\circ}C$ and from 12.9 to 4.3 in late stage, respectively. They suggest that complex cooling histories were occured by the mixing of the fluids. Sulfur fugacity $(-logfs_2)$ deduced by mineral assemblages and composition ranges from 8.3 to 14.7 atm. in early stage, and from 8.8 to 14.5 atm. in late stage. It suggests that the mineralization was related to decrease of temperature in early stage and fluctuations of $fS_2$ with decrease of temperature in late stage. Sulfur and oxygen isotope compositions are 4.48~5.60‰ and 9.25~10.8% in early stage, and late stage is 4.84~7.00‰ and 5.7‰, respectively. It indicated that hydrothermal fluids may be magmatic origin with some degree of mixing of another water during paragenetic time.

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