• Title/Summary/Keyword: Arsenic(As)

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Evaluation of Leaching Stability of Preservative Treated Wood in the Seawater for the use of a Fish-breeding Ground (해양어초사용을 위한 방부목재의 해수 용탈성 평가)

  • Lee, Myung Jae;Lee, Dong-Heub;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.3 s.131
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    • pp.53-63
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    • 2005
  • This study attempted to obtain the basic data of utilizable possibility of preservative treated wood as a material used in a marine ranch. To evaluate the leaching stability of CCA-, CCFZ-, and ACQ-treated woods in seawater, the specimens treated with 2% and 3% (w/v) of CCA, CCFZ, and ACQ were exposed to deionized water, synthetic seawater and natural seawater for 41 days and then each component released was periodically determined. There was little amount of copper and chromium released from CCA-treated wood exposed in both deionized and seawater. Although relatively large amount of arsenic was released from CCA-treated wood, the release rate in seawater was lower than that in deionized water. The release rate of chromium and zinc from CCFZ-treated wood were somewhat greater in deionized water, but lower in seawater than in deionized water. Retention level and salinity of synthetic seawater had little effect on the release rate of components. The ACQ-treated wood had greater copper release than CCA- and CCFZ-treated wood, and the amount of copper released did not affected by leaching media used.

Heavy metals and pollution index of agricultural soils around industrial complexes in the Jeon-Buk regions of Korea

  • Suwanmanon, Sorakon;Kim, Ki In
    • Korean Journal of Agricultural Science
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    • v.46 no.4
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    • pp.799-811
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    • 2019
  • The aim of this study was to evaluate heavy metal contamination and pollution index of agricultural soils around industrial complexes in the Jeon-Buk Regions of Korea. Soil samples near industrial complexes in 2017 were collected at two depths (0 - 15 and 15 - 30 cm) within a 500- and 1000-meter radius before planting. Eight heavy metals (Arsenic (As), cadmium (Cd), chromium (Cr), Cupper (Cu), nickel (Ni), lead (Pb), mercury (Hg) and zinc (Zn)) and the pollution index (PI), geoaccumulation index (Igeo) and soil pollution index (SPI) were evaluated based on soil contamination warning standard (SCWS). Overall, the heavy metal concentrations were below the SCWS. The PI ranged from 0.1 to 0.9 and categorized into Group 1 which is not polluted with any heavy metals. The average Igeo values of all the soil samples ranged from - 2.56 to 3.22. The Igeo values of Cd and Hg may not represent well the pollution index because the heavy metal concentrations in the soil is lower compared to the SCWS. In fact, based on the heavy metal concentrations, the Igeo for monitored soils should be categorized into Group 1, uncontaminated to moderately contaminated. However, the Igeo of Cd and Hg are classified into heavily contaminated. These results suggest that for calculating the Igeo, the heavy metal concentration and background concentration should be used very carefully if the heavy metal concentration in the soil is lower than the background concentration. SPI for all the soil samples ranged from 0.00 to 0.11 which indicates no heavy metal pollution was observed.

Metal Exposure Through Consumption of Herbal Medicine, and Estimation of Health Risk Among Korean Population (한약재 복용으로 인한 금속 섭취량 추정 및 위해성 평가 연구)

  • Park Hae-Mo;Choi Kyung-Ho;Jung Jin-Yong;Lee Sun-Dong
    • Journal of Environmental Health Sciences
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    • v.32 no.2 s.89
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    • pp.186-191
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    • 2006
  • Metal contamination of medicinal herbs is of growing concern because of their potential adverse health effects. In this study, metal exposures were estimated and their potential health risks were preliminarily evaluated using available data including metal contamination levels and consumption estimates of herbal medicine in Korea. Consumption and contamination data of 34 medicinal herbs abundantly used in Oriental medicine in Korea were used in this study. Lead, mercury, arsenic, cadmium, cobalt, and chrome were identified as contaminants of potential health concerns. Even based on a conservative exposure scenario, i.e., consuming 5 times more herbal medicine with 95th percentile contamination levels, health risks associated with herbal medicine consumption were estimated to be minuscule. Herbal consumption was 0.3% of the provisional tolerable daily intake levels recommended by Joint Expert Committee on Food Additives (JECFA) of WHO/FAO. However, it should be noted that there are several important assumptions and uncertainties associated with this evaluation: This study was conducted for only 34 types of medicinal herbs of which consumption and metal contamination data were available. In addition, there are no reliable herbal medicine consumption data among Korean population. The pattern and amount of herbal (medicine) consumption in Korea need to be investigated in order to conduct more refined risk assessment associated with metal contamination in medicinal herbs.

Transgenic Expression of MsHsp23 Confers Enhanced Tolerance to Abiotic Stresses in Tall Fescue

  • Lee, Ki-Won;Choi, Gi-Jun;Kim, Ki-Yong;Ji, Hee-Jung;Park, Hyung-Soo;Kim, Yong-Goo;Lee, Byung-Hyun;Lee, Sang-Hoon
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.6
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    • pp.818-823
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    • 2012
  • Tall fescue (Festuca arundinacea Schreb.) is an important cool season forage plant that is not well suited to extreme heat, salts, or heavy metals. To develop transgenic tall fescue plants with enhanced tolerance to abiotic stress, we introduced an alfalfa Hsp23 gene expression vector construct through Agrobacterium-mediated transformation. Integration and expression of the transgene were confirmed by polymerase chain reaction, northern blot, and western blot analyses. Under normal growth conditions, there was no significant difference in the growth of the transgenic plants and the non-transgenic controls. However, when exposed to various stresses such as salt or arsenic, transgenic plants showed a significantly lower accumulation of hydrogen peroxide and thiobarbituric acid reactive substances than control plants. The reduced accumulation of thiobarbituric acid reactive substances indicates that the transgenic plants possessed a more efficient reactive oxygen species-scavenging system. We speculate that the high levels of MsHsp23 proteins in the transgenic plants protect leaves from oxidative damage through chaperon and antioxidant activities. These results suggest that MsHsp23 confers abiotic stress tolerance in transgenic tall fescue and may be useful in developing stress tolerance in other crops.

A study on the new manufacturing processes of high quality salt without hazardous ingredients (유해성분이 없는 고품질 소금의 새로운 제조공정에 관한 연구)

  • Kim, Kyung-Geun;Mun, Soo-Beom;Shao, Yudo
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.6
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    • pp.458-467
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    • 2016
  • Salt is the most important substance in physiological activities of the human body concerning transport of the ingested nutrients into the blood. Thus, the most ideal salt must not contain any harmful ingredients such as cadmium, mercury, lead, and arsenic. However, it is legal to include trace amounts of the hazardous ingredients in salt owing to a technical limitation, because salt is generally obtained from seawater. This paper reported an experimental result about a new method of manufacturing high-quality table salts without hazardous ingredients by using "$15^{\circ}C$ low-temperature vacuum drying technology," applied to the sequential extraction phenomenon of seawater with increasing the concentration. The world's best table salt can be produced if the present results are applied and extended to the traditional solar salt industry.

Sanitary Evaluation for Seawater and Laver Pyropia sp. in the Major Laver Growing Areas, Korea (우리나라 주요 김 생산해역의 해수 및 물김에 대한 위생학적 평가)

  • Jeong, Sang Hyeon;Shin, Soon Bum;Oh, Eun Gyoung;Jo, Mi-Ra;Yoon, Min Chul;Lee, Hee Jung;Son, Kwang-Tae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.4
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    • pp.343-351
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    • 2017
  • Sanitary evaluation of seawater and Pyropia sp. laver collected from the five major laver growing areas in Korea was performed four times over the course of a year. The seawater quality in four of these five areas was regarded as the clean area according to Korean criteria, but the seawater at one investigation site in Seoheon area was found to exceed the standard for fecal coliform. In the bacteriological safety analysis of laver (raw source), the percentages of samples not conforming to Chinese criteria at the five sites were 55.6% (Seocheon), 70.0% (Shinan), 81.8% [Jindo (Haenam)], 63.6% (Wando), and 28.6% [Goheung (Jangheung)]. Pathogenic bacteria were not detected in all laver samples. The food safety of laver (raw source) based on heavy metal concentration was confirmed using Korean criteria; the concentrations of heavy metals in laver samples collected from the major laver growing areas were 0.008-0.632 mg/kg wet weight (ww) lead, 0.024-0.137 mg/kg ww cadmium, 0.908-2.892 mg/kg ww total arsenic, and 0.003-0.013 mg/kg ww total mercury. Therefore, pollution source management and periodic monitoring of heavy metals may be required to improve the food safety of laver produced in these laver growing areas.

Heavy Metal Risk Management: Case Analysis

  • Kim, Ji-Ae;Lee, Seung-Ha;Choi, Seung-Hyun;Jung, Ki-Kyung;Park, Mi-Sun;Jeong, Ji-Yoon;Hwang, Myung-Sil;Yoon, Hae-Jung;Choi, Dal-Woong
    • Toxicological Research
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    • v.28 no.3
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    • pp.143-149
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    • 2012
  • To prepare measures for practical policy utilization and the control of heavy metals, hazard control related institutions by country, present states of control by country, and present states of control by heavy metals were examined. Hazard control cases by heavy metals in various countries were compared and analyzed. In certain countries (e.g., the U.S., the U.K., and Japan), hazardous substances found in foods (e.g., arsenic, lead, cadmium, and mercury) are controlled. In addition, the Joint FAO/WHO Expert Committee on Food Additives (JECFA) recommends calculating the provisional tolerable weekly intake (PTWI) of individual heavy metals instead of the acceptable daily intake (ADI) to compare their pollution levels considering their toxicity accumulated in the human body. In Korea, exposure assessments have been conducted, and in other countries, hazardous substances are controlled by various governing bodies. As such, in Korea and other countries, diverse food heavy metal monitoring and human body exposure assessments are conducted, and reducing measures are prepared accordingly. To reduce the danger of hazardous substances, many countries provide leaflets and guidelines, develop hazardous heavy metal intake recommendations, and take necessary actions. Hazard control case analyses can assist in securing consumer safety by establishing systematic and reliable hazard control methods.

Application of TAO System and RDF for Treatment of Cattle Manure (우분뇨의 고형연료화와 고온호기산화 공정 적용 가능성에 관한 연구)

  • Kim, Soo-Ryang;Hong, In-Gi;Kim, Ha-Je;Jeon, Sang-Jun;Lee, Jeong-Soo;Lee, Myung-Gyu
    • Journal of Animal Environmental Science
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    • v.19 no.2
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    • pp.177-182
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    • 2013
  • We studied the possibility to produce solid fuel using cattle manure and to apply TAO (Thermophilic Aerobic Oxidation) process of solid-liquid separation fraction. The physiochemical compositions of cattle manure solid fuel chip were analyzed as water 0.12%, low calorific value 3,510 kcal/kg, ashes 11.9%, chlorine 0.82%, sulfur dust 0.5%, mercury non-detection, cadmium 1.0 mg/kg, lead 2 mg/kg, arsenic non-detection. In treating cattle manure with TAO reactor the internal temperature of the reactor was increasing higher and $50^{\circ}C$ and over was maintained after 20 hours on. The physiochemical compositions of liquids increased from pH 7.3 to pH 9.18 and EC decreased from 4.6 to 3.48 mS/cm in treating process of cattle manure with TAO reactor. COD and SCOD decreased from 16,800 to 10,400 mg/L, from 4,600 to 2,040 mg/L respectively, which showed about 38% and 56% of remove efficiency respectively.

Development of Radiation Shield with Environmentally-Friendly Materials ; Ⅰ: Comparison and Evaluation of Fiber, Rubber, Silicon in the Radiation Shielding Sheet (친환경 소재의 의료 방사선 차폐 시트 개발 ; I: 섬유, 고무, 실리콘 소재 차폐 시트의 성능 비교평가)

  • Kim, Seon-Chil;Park, Myeong-Hwan
    • Journal of radiological science and technology
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    • v.33 no.2
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    • pp.121-126
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    • 2010
  • Traditionally, lead has been primarily used to shield the radiation in the hospital, because of its soft texture, durability and cost effectiveness. However, lead can be dangerous because of its toxicity when exposed to the human body, and it is classified as a heavy metal like cadmium, mercury, and arsenic etc. In order to compensate its noxious properties on the human body, researchers are trying to develop a radiation shield which has similar shielding efficiency and can also be manufactured in any form. In this study, sulfuric acid barium was mixed with fiber, rubber, and silicon all of which are harmless to the human body, tested, and evaluated for its ability of medical radiation shield. The result of this study showed that the sheet containing silicon and barium has the strongest shielding abilities.

L-ASCORBIC ACID AND ARSENIC TRIOXIDE SYNERGISTICALLY REPRESS CONSTITUTIVE ACTIVATION OF NF- $\textsc{k}$B AND COX-2 EXPRESSION IN HUMAN ACUTE PROMYELOCYTIC LEUKEMIA, HL-60

  • Han, Seong-Su;Lee, Sook-J.;Chung, Seung-Tae;Eom, Juno-H.;Surh, Young-Joon;Park, Hye-K.;Park, Mary-H.;Kim, Won-S.;Kim, Ki-Hyun;Park, Keun-Chil;Kim, Jhin-Gook;Yang, Jung-Hyun;Yoon, Sung-S;Neil H.Riordan;HughD.Riordan;BruceF.Kimler;Park, Chan-H.
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2001.10a
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    • pp.143-144
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    • 2001
  • Eukaryotic nuclear transcription factor, NF-B and cyclooxygenase-2 (COX-2) has been implicated in pathogenesis of many human diseases including tumor and are known to be activated by various external stimuli. Recently, increasing evidences have supported that L-ascorbic acid (LAA) is selectively toxic to some types of tumors at pharmacological concentrations as a prooxidant, rather than antioxidant.(omitted)

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