• Title/Summary/Keyword: Arrhenius theory

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Kinetics and Mechanism of Corrosion of ρ-alumina Bonded Alumina Castable by Molten Slag (ρ-알루미나결합 알루미나 캐스터블의 용융슬래그에 의한 침식기구)

  • 천승호;전병세
    • Journal of the Korean Ceramic Society
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    • v.40 no.10
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    • pp.1015-1020
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    • 2003
  • The Corrosion behavior of the matrix of the $\rho$-alumina bonded alumina vibrated castable was, on the basis of Jabsen's theory, elucidated by use of the Kingery's reaction mechanism. Corrosion of the matrix during induction period was controlled by the molecular diffusion. The temperature dependence of activation process is well established by the Arrhenius plots. The difference of Ca concentration between slag and interface is 23.2%, which causes a driving force of the materials transfer. The extent of the corrosion of the matrix is more deeper than that of the sintered mullite, but the corrosion mechanism can be well employed as the reaction mechanism proposed by the Kingery. The life time of the castable may be well estimated by the corrosion mechanism of Kingery.

The Acid-Base-Concepts of Korean Secondary Students (우리나라 중.고등학교 학생이 갖고 있는 '산과 염기'의 개념에 관한 연구 -서울 일부지역의 여학생을 중심으로-)

  • Kim, Hwa-Sook
    • Journal of The Korean Association For Science Education
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    • v.12 no.2
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    • pp.55-65
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    • 1992
  • The purpose of the study is to compare the learning contents of theme acids and bases that are commonly dealed with in elementary, middle and high schools m Korea and to investigate the acid-base-concepts of secondary students. The results of the study were as follows: 1) Many students did not have an interest in the chemistry and they pointed out the necessity of many experiments and practices and its application to the practical life. 2) It is found that most of textbooks used in the elementary school are written to make the students have an interest in the science through the experiments and pratices. However the textbooks used in the secondary school are too theoretically written so that many students are likely to lose the interests in the chemistry. 3) Although students had already learned Arrhenius's acid-base-concept, many students tried to solve the question with Liebig's theory as a acid-base-concept. This misconception might be caused by learning by cramming and teaching too theoretically. Accordingly, it is necessary that the education of science is carried out to make the students have an interest in the science by providing the students with the much more experiments and practices and also applying it to the practical life.

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A study on the Effects of Load Current for Lifetime of Cable Systems (부하 전류가 케이블의 수명에 미치는 영향에 대한 연구)

  • Um, Kee-Hong;Lee, Kwan-Woo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.4
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    • pp.205-209
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    • 2015
  • The economic losses resulted from the accident in the power cables at the power station is not only huge but also requires a great amount of time and expenses to restore to the former condition. In order to prevent these, it is necessary to invent and apply a technique to expect and prevent the accidents. In order to measure insulation resistances of power cables in operation, we derived the relations between load current and temperature. By analyzing data obtained from our measuring equipments, we showed the expected time to change deteriorated cables before accident occurs. We present a result of our study on the effects of the load current on lifetime of 6.6 kV cable systems in operation. With the current flowing through the load of the cable a heat is generated reducing the lifetime of the cable. In order to find out the effect of load current on the lifetime of cable systems, we applied the lifetime theory to the development of two equipments to measure insulation resistance and current of cable systems in operation.

Computer Simulation and Verification of Adiabatic Temperature and Apparent Activity Energy of the NiO/Al Aluminothermic System

  • Song, Yuepeng;Zhu, Yanmin;Gao, Dongsheng;Guo, Jing;Kim, Hyoung Seop
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.332-337
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    • 2013
  • Recently, self-propagating high-temperature synthesis (SHS), related to metallic and ceramic powder interactions, has attracted huge interest from more and more researchers, because it can provide an attractive, energy-efficient approach to the synthesis of simple and complex materials. The adiabatic temperature $T_{ad}$ and apparent activation energy analysis of different thermit systems plays an important role in thermodynamic studies on combustion synthesis. After establishing and verifying a mathematic calculation program for predicting adiabatic temperatures, based on the thermodynamic theory of combustion synthesis systems, the adiabatic temperatures of the NiO/Al aluminothermic system during self-propagating high-temperature synthesis were investigated. The effect of a diluting agent additive fraction on combustion velocity was studied. According to the simulation and experimental results, the apparent activation energy was estimated using the Arrhenius diagram of $ln(v/T_{ad}){\sim}/T_{ad}$ based on the combustion equation given by Merzhanov et al. When the temperature exceeds the boiling point of aluminum (2,790 K), the apparent activation energy of the NiO/Al aluminothermic system is $64{\pm}14$ kJ/mol. In contrast, below 2,790 K, the apparent activation energy is $189{\pm}15$ kJ/mol. The process of combustion contributed to the mass-transference of aluminum reactant of the burning compacts. The reliability of the simulation results was experimentally verified.

A study on Lifetime Evaluation of High-power Cables Based on Temperature Changes (온도변화에 따르는 고전력 케이블의 수명 변화 연구)

  • Um, Kee-Hong;Lee, Kwan-Woo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.2
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    • pp.273-278
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    • 2015
  • In order to meet increasing power demands, electrical capacity of equipment for power transfers should become larger accordingly. The equipment used for producing and delivering high-voltage power is also required to operate with a high degree of reliability. The stable operation of power equipment is a necessity, not an option. The current through the power cable, the only device to deliver high power, generates a Joule heat, which causes a deteriorating process on the cable system. The XLPE cable is manufactured in such a manner that it can operate for 30 years at $90^{\circ}$, but there is no guarantee that each cable will reach its projected lifetime of 30 years. In this paper, we have measured the temperatures of nine power cables in operation, based on the theory of cable longevity. In order to study the relationship between temperature and longevity, we have devised a new set of equipment and installed it at Korea Western Power Co., Ltd. located in Taean.

A Study on the Reliability Prediction about ECM of Packaging Substrate PCB by Using Accelerated Life Test (가속수명시험을 이용한 Packaging Substrate PCB의 ECM에 대한 신뢰성 예측에 관한 연구)

  • Kang, Dae-Joong;Lee, Hwa-Ki
    • Journal of the Korea Safety Management & Science
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    • v.15 no.1
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    • pp.109-120
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    • 2013
  • As information-oriented industry has been developed and electronic devices has come to be smaller, lighter, multifunctional, and high speed, the components used to the devices need to be much high density and should have find pattern due to high integration. Also, diverse reliability problems happen as user environment is getting harsher. For this reasons, establishing and securing products and components reliability comes to key factor in company's competitiveness. It makes accelerated test important to check product reliability in fast way. Out of fine pattern failure modes, failure of Electrochemical Migration(ECM) is kind of degradation of insulation resistance by electro-chemical reaction, which it comes to be accelerated by biased voltage in high temperature and high humidity environment. In this thesis, the accelerated life test for failure caused by ECM on fine pattern substrate, $20/20{\mu}m$ pattern width/space applied by Semi Additive Process, was performed, and through this test, the investigation of failure mechanism and the life-time prediction evaluation under actual user environment was implemented. The result of accelerated test has been compared and estimated with life distribution and life stress relatively by using Minitab software and its acceleration rate was also tested. Through estimated weibull distribution, B10 life has been estimated under 95% confidence level of failure data happened in each test conditions. And the life in actual usage environment has been predicted by using generalized Eyring model considering temperature and humidity by developing Arrhenius reaction rate theory, and acceleration factors by test conditions have been calculated.