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Characterization and Formation Mechanism of Zr-Cu and Zr-Cu-Al Metallic Glass Thin Film by Sputtering Process

  • Lee, Chang-Hun;Sun, Ju-Hyun;Moon, Kyoung-Il;Shin, Seung-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.271-272
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    • 2012
  • Bulk Metallic Glasses (BMGs or amorphous alloy) exhibit high strength and good corrosion resistance. Applications of thin films and micro parts of BMGs have been used a lot since its inception in the research of BMGs. However, Application and fabrication of BMGs are limited to make structural materials. Thin films of BMGs which is sputtered on the surface of structural materials by sputtering process is used to improve limits about application of BMGs. In order to investigate the difference of properties between designed alloys and thin films, we identified that thin films deposited on the surface that have the characteristic of the amorphous films and the composition of designed alloys. Zr-Cu (Cu=30, 35, 38, 40, 50 at.%) and Zr-Cu-Al (Al=10 at.% fixed, Cu=26, 30, 34, 38 at.%) alloys were fabricated with Zr (99.7% purity), Cu (99.997% purity), and Al (99.99% purity) as melting 5 times by arc melting method before rods 2mm in diameter was manufactured. In order to analyze GFA (Glass Forming Ability), rods were observed by Optical Microscopy and SEM and $T_g$, $T_x$, ($T_x$ is crystallization temperature and $T_g$ is the glass transition temperature) and Tm were measured by DTA and DSC. Powder was manufactured by Gas Atomizer and target was sintered using powder in large supercooled liquid region ($=T_x-T_g$) by SPS(Spark Plasma Sintering). Amorphous foil was prepared by RSP process with 5 gram alloy button. The composition of the foil and sputtered thin film was analyzed by EDS and EPMA. In the result of DSC curve, binary alloys ($Zr_{62}Cu_{38}$, $Zr_{60}Cu_{40}$, $Zr_{50}Cu_{50}$) and ternary alloys ($Zr_{64}Al_{10}Cu_{26}$, $Zr_{56}Al_{10}Cu_{34}$, $Zr_{52}Al_{10}Cu_{38}$) have $T_g$ except for $Zr_{70}Cu_{30}$ and $Zr_{60}Al_{10}Cu_{30}$. The compositions with $T_g$ made into powders. Figure shows XRD data of thin film showed similar hollow peak.

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Expression of Human p53 Gene as Glutathione S-transferase Fusion Proteins in Escherichia coli (사람의 p53 유전자와 Glutathione S-Transferase와의 융합 단백질의 대장균에서의 발현)

  • 오상진
    • Korean Journal of Microbiology
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    • v.31 no.4
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    • pp.279-285
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    • 1993
  • Alterations of the p53 gene arc among the most frequent genetic changes in human cancer and often result in increased levels of p53 protein within the malignant cells. Detection of accumulated p53 protein can be a useful prognostic tool in human cancer. In order to make polyclonal antibodies for immunohistochemical screening. human p53 gene was expressed in E. coli in the form of GST (glutathione S-transfi.:rase) fusion proteins. Two p53 gene fragments. which were N('()I small fragment encoding amino acid residues of 1-151-: and Ncol large fragment of 159-393. were subeloned into the unique BamHI site present within the pGEX-2T vector using BamHI linker and recombinant plasmids pGTNS and pGTNL were constructed. respectively. The p53 cDNA fragment (from pC53-$SN_3$,) encoding amino acid 38-145 (proline at residue 72) was amplified by polymerase chain reaction(PCR). The amplified DNA was digested with BamHI and Prull and inserted into the BamHI-Smal sites of pG EX-2T and recombinant plasmid pGTBP was constructed. After IPTG induction of these plasmids for 4 hours. fusion proteins were purified from E. coli extracts with glutathione Sepharose beads. The bound proteins were resolved by 10% SDS-polyacrylamide gel electrophoresis and the molecular weights were 54 kDa. 53 kDa and 40 kDa. respectively. Approximately one milligram of fusion proteins were purified from 1 -liter cultures.

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Geology and Mineral Resources of the Ogcheon Zone: Mineralization in the Pyeongchang-Jucheon Area, Kangwon-Do, Korea (옥천대(沃川帶)의 지질(地質) 및 광물자원(鑛物資源)에 관(關)한 연구(硏究) -평창(平昌)~주천지역(酒泉地域)에 있어서의 광화작용(鑛化作用)-)

  • Yun, Suckew;So, Chil Sop;Kim, Kyu Han
    • Economic and Environmental Geology
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    • v.19 no.1
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    • pp.1-18
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    • 1986
  • A group of 16 $Zn+Pb{\pm}Ag$ deposits distributed in the Pyeongchang-Jucheon area, Kangwon-do, South Korea, were semi-regionally investigated. These deposits are contact metasomatic and/or hydrothermal replacement types hosted in the carbonate-dominated Cambrian Machari Formation and Ordovician Ibtanri Formation, and also in the carbonate interbeds of the Precambrian argillic metasediments. Comparing some key aspects of the individual deposits, it is found that the ore deposits hosted in the Machari and Ibtanri Formations are mostly of steeply-dipping chimneys with or without skarn minerals and are rich in Ag and Pb>Zn in metal grade whereas those occuring in the carbonate interbeds of the Precambrian argillic metasediments are gently-dipping conformable lenticular orebodies mostly with skarn minerals and are generally poor in Ag and Zn>Pb. The skarn mineralization in the area appears to have occurred during the lower Cretaceous (118.7Ma) to mid-Cretaceous (107.8Ma) time assumed from the K-Ar dates of the Dowon and Pyeongchang granites which are closely associated with the skarn ore deposits. The Rb/Ba/Sr ratios of these granites indicate that they are of strongly differentiated anomalous granites, and the Nb vs. Y and Rb vs. Y+Nb plots fall on the field of volcanic arc setting. The contact aureoles are zoned, giving the sequence in order of increasing distance from igneous contact: garnet-wollastonite, granet-wollastonite-clinopyroxene and garnet-clinopyroxene in such as the Pyeongchang and Yeonwol 114 areas. Electron microprobe analyses reveal that garnets and clinopyroxenes are generally low in Fe and Mn. Garnets are grossular to intermediate grandite except for those from the Ogryong exoskarn which are richer in andradite, pyrope and spessartine fractions. This indicates that the oxidation state of skarn-forming environment at Ogryong was higher than at the other deposits. Clinopyroxenes are mostly salitic except for those from the Ogryong exoskarn which involve considerable amounts of hedenbergite and johansenite fractions. The ${\delta}^{18}O$ value of Jurassic biotite granite at Ogryong is higher (+10.21‰) than that of Cretaceous one at Chodun (+8.41‰). The ${\delta}^{13}C$ values of carbonate rocks range from -0.89‰ to 0.68‰ and the ${\delta}^{18}O$ values range from +11.91‰ to + 19.34‰ indicating that these carbonate rocks are of marine origin. However, the ${\delta}^{13}C$ values of skarn calcite and vein calcite are -4.80‰ and -12.92‰, and the ${\delta}^{18}O$ values are +5.56‰ and +10.32‰, respectively, indicating that these calcites are of hydrothermal origin. The ${\delta}^{34}S$ values of sulfide minerals range from +4.4‰ to +8.7‰ suggesting that the sulfurs are of magmatic origin.

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A Characteristics of the Vulnerable Area for Emergency Medical Service in Daejeon by Analysis of Geographic Information System (지리정보시스템(GIS)으로 분석한 대전광역시 응급의료서비스 취약지 특성)

  • Hwang, Ji-Hye;Na, Baeg-Ju;Lee, Dong-Woo;Hong, Jee-Young;Lee, Moo-Sik
    • Proceedings of the KAIS Fall Conference
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    • 2010.05b
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    • pp.859-862
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    • 2010
  • 본 연구는 대전광역시의 응급의료서비스 취약지를 도출하고 취약지역의 보건학적 특성 및 응급의료서비스 취약여부와의 관련성을 분석하여 응급의료 관련 정책의 의사결정에 유용한 기초자료로 제공하기 위한 연구이다. 응급의료서비스 취약지 도출은 Arc GIS의 공간분석 방법 중 가중분석(Cost Weighted distance) 방법으로 응급의료센터로부터의 접근성 분석을 하였으며, 응급의료서비스 취약지의 보건학적 특성 및 응급의료서비스 취약여부와의 관련성은 SPSS 17.0을 이용하여 비모수 t-검정 및 다중회귀분석을 시행하였다. 본 연구의 주요 결과는 다음과 같다. 연구지역의 응급의료기관 분포는 동구와 유성구, 대덕구는 지정된 응급의료센터가 없으나 서구와 중구는 응급의료센터가 2개소 이상 위치하고 있어 응급의료기관 분포가 편중되어 있으며, GIS를 활용하여 응급의료센터와의 접근성 분석을 수행한 결과, 대전광역시 자치구별 전체 면적 대비 응급의료서비스 취약지의 비율이 높은 자치구는 동구가 41.2%로 가장 높았다. GIS를 활용하여 행정동별 응급의료서비스 취약지를 분석한 결과, 대덕구 신탄진동, 동구 대청동과 산내동, 유성구 구즉동과 노은2동, 서구 기성동, 중구 산성동으로 나타났으며, 응급의료서비스 취약지 중 기성동, 대청동이 노인 인구밀도가 높게 나타났다. 응급의료서비스 취약여부에 따른 보건학적 특성별 차이를 분석한 결과, 국민기초생활수급권자, 장애인등록자, 농업인구 비율의 평균은 취약지가 비취약지에 비해 높았으며 통계적으로 유의한 차이를 보였다(p<0.01). 응급의료서비스 취약여부를 종속변수로 하고 지역별 보건학적 특성을 독립변수로 하여 로지스틱 회귀분석을 시행한 결과, 농업인구 비율과 국민기초생활수급권자 비율이 높았으며 이는 통계적으로 유의하여 응급의료서비스 취약여부를 설명할 수 있는 변수인 것으로 나타났다(p<0.01, p<0.05). 이상의 결과를 종합하면 대전광역시 5개 자치구의 행정동 중 응급의료서비스 접근 불평등지역이 도출되었고 이러한 지역은 보건학적 특성 중 농업인구 비율과 국민기초생활수급권자의 비율이 높았으며 이는 통계적으로 유의하여 응급의료서비스 취약여부와 관련성이 있는 것으로 나타났다. 향후 효율적인 응급의료 자원 분배를 위해서는 GIS를 활용한 의사결정이 필요하며, 응급의료서비스 이용의 형평성을 증진시키기 위해서 응급의료서비스의 사각지대에 놓여있는 지역의 보건학적 특성을 고려한 정책이 시행되어야 할 것으로 사료된다.

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A Study on Characteristics of Magnetism from Hydrothermal Vent Area on Esmeralda Bank in Mariana Arc (Mariana 해령 Esmeralda Bank 해저열수분출 지역에서의 지자기 특성 연구)

  • Kim, Ho;Kim, Chang-Hwan;Jeong, Eui-Young;Park, Chan-Hong;Kim, Jong-Uk;Park, Chung-Hwa
    • 한국지구물리탐사학회:학술대회논문집
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    • 2008.10a
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    • pp.27-32
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    • 2008
  • Detailed bathymetry and magnetic survey data for Esmeralda Bank obtained by R/V Onnuri of Korea Ocean Research & Development Institute in September 2007 were analyzed to estimate the locations of possible hydrothermal vents. The shape of Esmeralda Bank is caldera type opened in the western part. The summit is very shallow, about 50 meter b.s.l. and the bottom is about 1300 meter b.s.l. The western part of Esmeralda Bank is more steeper and topographic irregular than eastern part, and showed the valley made by erosion or collapse. The magnetic anomaly patterns of Esmeralda Bank located low anomalies over the north and high anomalies over the south. The magnetic anomalies are steep over the summits and gently smooth over the deep bottom. Two low magnetization zones are located in the summit and westside of Esmeralda Bank. The low magnetization zones of the summits of Esmeralda Bank suggest the possible existence of hydrothermal vent.

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Petrological Characteristics of the Satkatbong Pluton, Yeongdeok, Korea (영덕 삿갓봉암체의 암석학적 특성)

  • Lim, Hoseong;Kim, Jung-Hoon;Woo, Hyeondong;Do, Jinyoung;Jang, Yun-Deuk
    • The Journal of the Petrological Society of Korea
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    • v.25 no.2
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    • pp.121-142
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    • 2016
  • The Satkatbong pluton was studied with other plutons together, but some fundamental petrological characteristics were missing. This study mainly reports the petrography and geochemistry of the Satkatbong pluton comparing with the Daebo and the Bulguksa granitoids in south Korea. The Satkatbong pluton, which is host rock including a number of Mafic Magmatic Enclaves (MME), is north-south shaped dioritic pluton, located along the east coast of south Korea. The Satkatbong pluton seems to be unconformable with Cretaceous sedimentary rocks from fieldwork result. In geochemistry, the Satkatbong pluton, which is roughly similar with the Daebo granitoids, is classified into calc-alkali series rock and volcanic arc granitoid Tectonically. The fact that AlT value in marginal parts of amphiboles in the Satkatbong pluton is lower than other granitoids implies emplacement depth of the Satkatbong pluton was relatively shallow. The Satkatbong pluton shows different geochemical feature compared to the adjacent adakitic Yeongdeok granite. This seems to be caused by mafic mantle material expected from the occurrence of MMEs.

Freeze and Thaw Durability of Concrete Using Recycled Aggregates (재생골재를 사용한 콘크리트의 동결융해 저항성)

  • 문대중;팽우선;문한영
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.307-314
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    • 2002
  • Utilization of demolished-concrete as recycled aggregate has been researched for the purpose of substituting for insufficient natural aggregate, saving resources and protecting environment. There, however, are some Problems not only the large difference of dualities in recycled aggregates but also a little deterioration of mechanical properties in recycled aggregate concrete in comparison with that of natural aggregate concrete. In this study, the test results of freez and thaw durability of concrete with demolished-concrete recycled aggregate(DRA) arc as follows. Improvement of crushing process is an important assignment because that adhered mortar on source-concrete recycled aggregate(SRA) and DRA highly affects thc qualifies of recycled aggregate. The compressive strength of recycled aggregate concrete was not highly different in comparison with that of control concrete. But the resistance to penetration of Cl in recycled aggregate concrete was shown smaller than that of control concrete because of adhered mortar on recycled aggregate. The resistance to frcezing and thawing of recycled aggregate concrete was highly different due to adhered mortar on recycled aggregate, and durability factor of concrete with NA-SRA and DRA was more decreased than that of control concrete. On the other hand, durability factor of concrete with AA-SRA was larger than that of control concrete. It, therefore, is necessarily required that recycled aggregate including adequate entrained air should be used for satisfying the freez and thaw durability of recycled aggregate concrete.

Geochemical Characteristics of the Jurassic Chunyang Granites in Northeastern Part of the Yeongnam Massif (영남육괴에 분포하는 쥐라기 춘양화강암의 지화학적 특성)

  • Kang, Minyoung;Kim, Yunji;Wee, Soomeen
    • Journal of the Korean earth science society
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    • v.38 no.1
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    • pp.49-63
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    • 2017
  • The geochemical results of the Chunyang granites located in the northeastern part of the Yeongnam Massif, indicate that these rocks have characteristics of calc-alkaline series in the sub-alkaline field, I-type and peraluminous. Most of the geochemical features in major and trace elements show systematic trends, which are similar to differentiation trends of the general Jurassic granitoids in South Korea. The Chunyang granite is largely enriched in mobile LILE (Sr, K, Rb and Ba) relatively immobile HFSE. They show LREE enriched patterns [$(La/Lu)_{CN}=41.8-73.2$] with a slightly negative Eu anomaly [$(Eu/Eu^*)_{CN}=0.89-1.10$]. There are no meaningful correlations in major and trace elements between the Chunyang granites and the Buseok plutonic rock which is the main unit of the Yeongju batholith. This result may suggest that these two plutonic rocks be not derived from the same parent magma. Tectonic discrimination diagrams indicate that the Chunyang granite was formed in volcanic arc environments. These geochemical characteristics results suggest that the Chunyang granite must have been generated at the active continental margin during the subduction of the Jurassic proto-Pacific plate.

Structural Behaviors of Precast Concrete Box Structures Using Recycled Aggregate (순환골재 콘크리트 박스 구조의 거동)

  • Byun, Keun-Joo;Song, Ha-Won;Kim, Ho-Jin;Nam, Jin-Won;Kim, Ki-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.93-102
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    • 2006
  • In order to use a recycled aggregate concrete for precast concrete box structures, the structural behaviors should be analytically and experimentally evaluated. In this study, full-scale precast concrete box structures are manufactured using the recycled aggregate (30% replacement) and natural aggregate. Then, the flexural failure test and shear failure test as well as water leakage lest for the structures arc carried out. First of all, test results of compressive strength show that recycled aggregate concrete is only 4% lower than normal concrete. In the flexural and shear failure test, the structural performances of precast box using the recycled aggregate concrete are 95% of the capacities of normal precast concrete box or more. Especially, the water leakage test shows that leakage pressure of recycled concrete box is more than the critical value, 60kPa, as well as 9% higher than normal precast concrete box. These test results are analyzed and compared with results of finite clement analysis. The comparison shows that test results are more excellent than analytical results. Also, the comparison confirms the applicability of recycled aggregate concrete for the use as practical precast concrete box structure.

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Formation of Layered Bi5Ti3FeO15 Perovskite in Bi2O3-TiO2-Fe2O3 Containing System

  • Borse, Pramod H.;Yoon, Sang-Su;Jang, Jum-Suk;Lee, Jae-Sung;Hong, Tae-Eun;Jeong, Euh-Duck;Won, Mi-Sook;Jung, Ok-Sang;Shim, Yoon-Bo;Kim, Hyun-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.3011-3015
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    • 2009
  • Structural and thermo-analytical studies were carried out to understand the phase formation kinetics of the single phase $Bi_5Ti_3FeO_{15}$ (BTFO) nanocrystals in $Bi_2O_3-Fe_2O_3-TiO_2$, during the polymerized complex (PC) synthesis method. The crystallization of Aurivillius phase $Bi_5Ti_3FeO_{15}$ layered perovskite was found to be initiated and achieved under the temperature conditions in the range of ${\sim}$800 to 1050$^{\circ}C$. The activation energy for grain growth of $Bi_5Ti_3FeO_{15}$ nanocrystals (NCs) was very low in case of NCs formed by PC (2.61 kJ/mol) than that formed by the solid state reaction (SSR) method (10.9 kJ/mol). The energy involved in the phase transformation of Aurivillius phase $Bi_5Ti_3FeO_{15}$ from $Bi_2O_3-Fe_2O_3-TiO_2$ system was ${\sim}$ 69.8 kJ/mol. The formation kinetics study of $Bi_5Ti_3FeO_{15}$ synthesized by SSR and PC methods would not only render a large impact in the nanocrystalline material development but also in achieving highly efficient visible photocatalysts.