• Title/Summary/Keyword: Ar-$CO_2$

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A Study on Low Temperature Impact Strength of Inconel 625 for Petroleum Application by FCAW Weld (석유시추용 인코넬 625강의 FCAW용접에 의한 저온 충격강도에 관한 연구)

  • PARK KEYUNG-DONG;AN DO-KEYUNG;JUNG JAE-WOOK
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.356-359
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    • 2004
  • Above all Ni-alloys Inconel 625 is used widely in plate of welding structural materials such as turbine case, a combustor of liner. In general, weldability of Inconel 625 is not well because of poorly liquids of weld metal also it have a broken probability oj the welding crack. In case of FCAW weld process, it is not easy to develope of welding materials, because it is possible only fillet welding at view position of look down except for butt welding. But recently, though it is more used by FCAW process, owing to welding materials worked at the vertical position. the study for FCAW weld of Inconel 625 is actively not yet worked. In this study, the weldability and weld characteristics(mechanical characteristics, corrosive property) of Inconel 625 are considered in FC4W weld associated with the several shielding gases$80\%Ar\;+\;20\%\;CO_2,\;50\%Ar\;+\;50\%\;CO_2,\;100\%\;CO_2$ in viewpoint of welding productivity. The results of impact test are follows; It was evaluated 70J at shielding gase of $100\%\;CO_2$, and obtained about 35J at the other shielding gases. If it was used for parts be required the impact value at the extremely low temperature, it is expected to have the advantage of using the $100\%\;CO_2$ shield gase than the others.

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$High-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ thin films on $SrTiO_3$(100) substrates prepared by the PLD process

  • Wee, Sung-Hun;Moon, Seung-Hyun;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.2
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    • pp.1-6
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    • 2009
  • We report a successful fabrication of $high-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ (NdBCO) films on $SrTiO_3$(STO) (100) substrates by pulsed laser deposition (PLD) in a relatively wide processing window. Under various oxygen pressures controlled by either 1%$O_2$/Ar mixture gas or pure $O_2$ gas, strongly c-axis oriented NdBCO films were grown at the substrate temperature $(T_s)\;of\;800^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas and also in 400 and 800 mTorr with pure $O_2$ gas. These samples exhibited $T_c$ values over 90K and $J_c$ values of $2.8-3.5MA/cm^2$ at 77K in self-field (77K, sf). On the other hand, $J_c$ values over $1A/cm^2$ were obtained at the temperature regions of $700-830^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas at those of $750-830^{\circ}C$ in 800 mTorr with pure $O_2$ gas. Unlike previous reports, resent results support that the PLD processing window for high-Jc NdBCO films is not narrow.

The Effect of Mixture Component in a Gasoline Engine on Combustion (The Effect of Combustion Velocity) (가솔린 기관(機關)의 혼합기(混合氣) 성분(成分)이 연소특성(燃燒特性)에 미치는 영향(影響) (연소(燃燒) 속도(速度)에 미치는 영향(影響)))

  • Song, J.I.
    • Journal of ILASS-Korea
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    • v.2 no.4
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    • pp.47-53
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    • 1997
  • By using a premixed laminar burner, the effect of mixture component on laminar burning velocity($S_L$) was investigated. The following was made clear ; (1)As the humidity$(H_2O)$, $CO_2$ and Ar in mixture is increased, $S_L$ decreased in proportion to quantity of those dilution gases. (2) The heat reaction theory says that mean thermal conductivity $(\lambda_m)$, specific heat $(C_{pm})$ of mixture and adiabatic flame temperatures $(T_b)$ affect $S_L$. As a result of theoretical analysis, the effect of $\lambda_m\;and\;C_{pm}$ on $S_L$ is less than 1/25 of the effect of $T_b$, so the effect of $\lambda_m\;and\;C_{pm}$ can be ignored. (3) From experimental results, it was confirmed that $\ln(S_L)$ is proportional to $(1/T_b)$, that is, the effect of $H_2O$ on $S_L$ is mainly caused by changes of $T_b$. This conclusion was verified by the fact increases of $H_2O,\;CO_2$ and Ar decrease the intensity of radiation typical $C_2$, CH, and OH in the same manner.

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Establishment Aerobic Soil Metabolism System Using [14C]Butachlor ([14C]Butachlor를 이용한 호기성 토양대사 시험법 확립)

  • Kim, Ju-Hye;Kim, Jong-Hwan;Kim, Dae-Wook;Lee, Bong-Jae;Kim, Chan Sub;Ihm, Yangbin;Seo, Jong-Su
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.258-268
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    • 2014
  • The test method of aerobic transformation in soil has established based on international test guideline (OECD TG 307). And then, the case study was conducted with [$^{14}C$]butachlor. Butachlor is commonly used herbicide in Korea. [$^{14}C$]Butachlor was treatrd $6.83mgKg^{-1}$ in loamy soil. The treated soil was incubated in flow-through system for 60 days. The mass balance of applied radioactivity (AR) ranged from 91.1 to 95.5% and from 93.0% to 97.7% for non-sterile and sterile soils, respectively. In non-sterile soil, the concentration of [$^{14}C$]butachlor was declined from 94.4% AR at 0 day to 8.4% AR at 60 days after treatment. 2-Chloro-2',6'-diethylacetanilide was the major degradation product detected in soil extract. The calculated $DT_{50}$ and $DT_{90}$ of butachlor were 10.4 days and 34.6 days, respectively. $^{14}CO_2$ and non-extractable soil residue were increased up to 3.5% and 43.5% AR at 60 DAT. There is no significant decrease of the [$^{14}C$]butachlor through the incubation period in sterile soil.

The Effect of Oxygen and Carbon Dioxide Concentration on Soot Formation in Nonpremixed Flames Using Time Resolved LII Technique

  • Oh, Kwang-Chul;Shin, Hyun-Dong
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2068-2076
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    • 2005
  • The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.

Assessment of Ni Catalyst Properties for Removal of O2 and CO Impurity in Inert Gas (불활성 가스의 O2와 CO 불순물 제거를 위한 Ni 촉매의 물성 평가)

  • Kim, Kwangbae;Jin, Saera;Kim, Eunseok;Lim, Yesol;Lee, Hyunjun;Kim, Seonghoon;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.588-595
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    • 2020
  • This study examined the catalytic property of Ni-catalyst used in the gas purifying process to manufacture inert gases of N2 and Ar with high-purity over 9N for semiconductor industrial applications. Two types of Ni-catalysts with a cylindrical shape (C1) and churros shape structure (C2) were compared for the assessment. Optical microscopy and FESEM were used to analyze the shape and microstructure of the Ni-catalyst. EDS, XRD, and micro-Raman characterization were performed to examine the composition and properties. BET and Pulse Titration analyses were conducted to check the surface area and catalytic property of the Ni-catalyst. From the composition analysis results, C1 contained a relatively large amount of graphite as an impurity, and C2 contained higher Ni contents than C1. From specific surface area analysis, the specific surface area of C2 was approximately 1.69 times larger than that of C1. From catalytic property analysis, outstanding performance in O2 and CO impurity removal was observed at room temperature. Therefore, C2, having low-impurity and large specific surface area, is a suitable catalyst for the high-purity inert gas process in the semiconductor industry because of its outstanding performance in O2 and CO impurity removal at room temperature.

The effects of primary gas physical properties on the performance of annular injection type supersonic ejector (주유동 기체의 물리적 특성이 환형 분사 초음속 이젝터의 성능에 미치는 영향)

  • Jin, Jung-Kun;Kim, Se-Hoon;Park, Geun-Hong;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.12
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    • pp.68-75
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    • 2005
  • The effects of the physical properties of primary flow on the performance of a supersonic ejector were investigated. Axisymmetric annular injection type supersonic ejector was used for the study of the effects of molecular weight and the specific heat at constant pressure on the ejection performance. Test gases include; air, $CO_{2}$, Ar, $C_{3}H_{8}$, and $CCl_{2}F_{2}$ for different values of gas properties. As the molecular weight and CP of the primary gas increase, the secondary flow pressure increases at the same primary stagnation pressure and this behavior results from the combined effects of molar specific heat or specific heat ratio.

Evaluations of Mn-Ni-Co type thermistor thin film for thermal infrared sensing element (열형 적외선 센싱소자용 Mn-Ni-Co계 써미스터 박막 특성 평가)

  • 전민석;최덕균
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.6
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    • pp.297-303
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    • 2003
  • Mn-Ni-Co type thin films were prepared at various conditions by a rf magnetron sputtering system. At the condition. or substrate temperature of $300^{\circ}C$ and $Ar/O_2$= 10/0, a cubic spinel phase was obtained. When oxygen was included in process gas, a cubic spinel phase was not formed even after the thermal annealing at $900^{\circ}C$. The thermistor thin film had no other elements except Mn, Ni and Co. The infrared reflection spectra of the thermistor thin films showed that the films had somewhat high reflectance for incoming infrared ray with some angle. The etch rate of the thermistor thin films was about 63nm/min at a condition of DI water : $HNO_3$: HCl = 60 : 30 : 10 vol%. The B constant and temperature coefficient of resistance of the thermistor thin films were 3500 K and -3.95 %/K, respectively. The voltage responsivity of the thermistor thin film infrared sensor was 108.5 V/W and its noise equivalent power and specific detectivity were $5.1\times 10^{-7}$ W/$Hz^{-1/2}$ and $0.2\times 10^6$cm $Hz^{1/2}$/W, respectively.

Protective Effects of Oleic Acid Against Palmitic Acid-Induced Apoptosis in Pancreatic AR42J Cells and Its Mechanisms

  • Ahn, Joung Hoon;Kim, Min Hye;Kwon, Hyung Joo;Choi, Soo Young;Kwon, Hyeok Yil
    • The Korean Journal of Physiology and Pharmacology
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    • v.17 no.1
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    • pp.43-50
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    • 2013
  • Palmitic acid (PAM), one of the most common saturated fatty acid (SFA) in animals and plants, has been shown to induce apoptosis in exocrine pancreatic AR42J cells. In this study, we investigated cellular mechanisms underlying protective effects of oleic acid (OLA) against the lipotoxic actions of PAM in AR42J cells. Exposure of cells to long-chain SFA induced apoptotic cell death determined by MTT cell viability assay and Hoechst staining. Co-treatment of OLA with PAM markedly protected cells against PAM-induced apoptosis. OLA significantly attenuated the PAM-induced increase in the levels of pro-apoptotic Bak protein, cleaved forms of apoptotic proteins (caspase-3, PARP). On the contrary, OLA restored the decreased levels of anti-apoptotic Bcl-2 family proteins (Bcl-2, Bcl-xL, and Mcl-1) in PAM-treated cells. OLA also induced up-regulation of the mRNA expression of Dgat2 and Cpt1 genes which are involved in triacylglycerol (TAG) synthesis and mitochondrial ${\beta}$-oxidation, respectively. Intracellular TAG accumulation was increased by OLA supplementation in accordance with enhanced expression of Dgat2 gene. These results indicate that restoration of anti-apoptotic/pro-apop-totic protein balance from apoptosis toward cell survival is involved in the cytoprotective effects of OLA against PAM-induced apoptosis in pancreatic AR42J cells. In addition, OLA-induced increase in TAG accumulation and up-regulation of Dgat2 and Cpt1 gene expressions may be possibly associated in part with the ability of OLA to protect cells from deleterious actions of PAM.

Effects of combined argon gas treatment on the quality of fresh-cut potatoes (Argon gas 병용처리가 신선편이 감자의 품질에 미치는 영향)

  • Son, Hyun-Ju;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.21 no.2
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    • pp.163-169
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    • 2014
  • The effect of the combined argon (Ar) gas packaging treatment on the browning of fresh-cut potatoes was studied. Fresh-cut potatoes were prepared for the following six groups: dipping distilled water for 1 minute and air packaging (Cont); dipping in distilled water for 1 minute and argon gas packaging (AR); dipping in 1% ascorbic acid for 1 minute and air packaging (AA); dipping in 1% ascorbic acid for 1 minute and argon gas packaging (AAR); blanching at $35^{\circ}C$ for 30 minutes and air packaging (BL); and blanching at $35^{\circ}C$ for 30 minutes and argon gas packaging (BAR). The potatoes were washed, peeled, and sliced ($1.5{\times}1.5{\times}1.5$ cm) before treatment. The samples were packed with a 0.04-mm-thick OPP film and were stored at $5^{\circ}C$ for 9 days. During the storage, the $O_2$ concentration decreased in Cont but increased in the AR, AA, AAR, BL, and BAR groups. The $CO_2$ concentration increased during storage. The AR, AAR, and BAR groups showed high $L^*$ and low $a^*$, $b^*$ values (browning index). The growth of the total aerobic bacteria was also inhibited in the AR group. During storage, the PPO activity gradually increased, and the AR group showed lower PPO activity. The AA and AAR groups showed high DPPH radical scavenging activity. It was demonstrated that the argon gas packaging is effective in the quality maintenance of fresh-cut potatoes.