• Title/Summary/Keyword: Aqueous system

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Metachromasy of Methylene Blue and Thionine on the Phospholipid Bilayer Membrane (Phospholipid 이중층막에서 Methylene Blue와 Thionine의 Metachromasy)

  • Kim, Ki-Jun;Lee, Hoo-Seol
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.43-49
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    • 1996
  • Metachromatic properties of admixture of thionine and methylene blue(MB) in aqueous solution and phospholipid bilayer membrane have been studied by absorption spectroscopy. When thionine and MB were mixed, new coaggregate has been formed because of MB was redistributed to thionine aggregate. In phosphlipid bilayer membrane system, the highly concentrated thionine was easily formed the coaggregation with MB moiety independent of MB concentration, and absorption band of admixture were more transferred to short wavelength than aqueous system. In monomeric thionine concentration, the coaggregation band was observed at the middle wavelength between the site of monomeric thionine and the site of dimeric MB in the presence of lipid bilayer membrane.

Poly(2-ethyl-2-oxazoline)/poly(acrylic acid) 계의 수소결합 특성 및 이용

  • Kim, Jin-Hui;Jang, U-Jin;Gu, Yun-Mo
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.644-647
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    • 2000
  • The properties of hydrogen bonding between poly(2-ethyl-2-oxazoline)[PEOx] and poly(acrylic acid)[PAA] were investigated. PEOx and PAA formed stable complex and precipitated due to hydrogen bonding between hydrogen of PAA and oxygen of PEOx in acidic condition(below pH 4.3). Optimum reaction ratio of PEOx and PAA was determined as mass ratio of 1:1.5 for applications in aqueous two phase system. The mixtures of the polymers formed aqueous two phase system with dextran solution after the breakage of hydrogen bondings. This properties can be used for the recovery of valuable products.

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Synthesis of Hybrid Sol Based on ZrO2-SiO2 System and their Coating Properties

  • Lee, Sang-Hoon;Park, Won-Kyu
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.349-352
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    • 2004
  • Organic-inorganic hybrid sol based on ZrO$_2$-SiO$_2$ system was prepared by sol-gel process. Firstly, ZrO$_2$ non-aqueous precursor sol was synthesized and then organosilane compounds which include epoxy silane (GPTS; 3-g1ycidoxypropyl tri-methoxysilane) and acryl silane (ACS; (3-(tri-methoxysilyl)propylmethacrylate)) were added to ZrO$_2$precursor sol for hybridization. Finally, com-mercial silica sol was added to improve the mechanical properties. Synthesized organic-inorganic Zr-hybrid sol was coated on polycarbonate substrate for enhancing it’s mechanical properties, especially hardness. Vicker’s hardness of polycarbonate sub strate was increased from 13.6 to 17.8 MPa and its pencil hardness was increased from 2 to 7 H, respectively, after coating and drying at 10$0^{\circ}C$ for 30 min.

A New Valve Actuator for a Glaucoma Treatment by Using MEMS

  • Byunghoon Bae;Kim, Nakhoon;Park, Kyihwan;Hongseok Kee;Kim, Seonho;Lee, Yeon
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.103.6-103
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    • 2001
  • Glaucoma is an eye disease which is caused by abnormal high IOP (Intra Ocular Pressure) in the eye. High IOP is caused by the aqueous humor which is produced consistently but not drained due to the malfunction of the trabecular system which has a role of draining the aqueous humor into the venous system. Currently, there are some methods to treat glaucoma, Among these, the use of implants is increasing in these days due to many problems in other methods. However, conventional implants are passive implants and have critical disadvantage. Therefore, it is needed to develop a new implant using MEMS structure which is capable of controlling the IOP actively and copes with personal difference of patients. An active glaucoma implant consists of the valve actuator, pressure sensor, controller, and power supply. In this paper the valve actuator is considered. We make experiments and simulations with the fabricated ...

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Application of the Electrochemical Noise Method with Three Electrodes to Monitor Corrosion and Environmental Cracking in Chemical Plants

  • Ohtsu, Takao;Miyazawa, Masazumi;Ebara, Ryuicluro
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.173-178
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    • 2008
  • Recently an electrochemical noise method (ENM) with three electrodes has gained attention as a corrosion monitoring system in chemical plants. So far a few studies have been carried out for localized corrosion and environmental cracking of chemical plant materials. In this paper the ENM system is briefly summarized. Then an application of ENM to general corrosion for chemical plant materials is described. The emphasis is focused upon the analysis of stress on the corrosion cracking process of austenitic stainless steel in 30% $MgCl_2$ aqueous solution and the corrosion fatigue crack initiation process of 12 Cr stainless steel in 3% NaCl aqueous solution by ENM. Finally future problems for ENM to monitor regarding corrosion and environmental cracking in chemical plants are discussed.

Simply Modified Biosensor for the Detection of Human IgG Based on Protein AModified Porous Silicon Interferometer

  • Park, Jae-Hyun;Koh, Young-Dae;Ko, Young-Chun;Sohn, Hong-Lae
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1593-1597
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    • 2009
  • A biosensor has been developed based on induced wavelength shifts in the Fabry-Perot fringes in the visible reflection spectrum of appropriately derivatized thin films of porous silicon semiconductors. Porous silicon (PSi) was generated by an electrochemical etching of silicon wafer using two electrode configurations in aqueous ethanolic HF solution. Porous silicon displayed Fabry-Perot fringe patterns whose reflection maxima varied spatially across the porous silicon. The sensor system studied consisted of a mono layer of porous silicon modified with Protein A. The system was probed with various fragments of an aqueous Human Immunoglobin G (Ig G) analyte. The sensor operated by measurement of the Fabry-Perot fringes in the white light reflection spectrum from the porous silicon layer. Molecular binding was detected as a shift in wavelength of these fringes.

Thermodynamic Analysis of an Absorption Heat Pump System with New Working Pairs[I] (1, 2종 흡수식 히트펌프의 작동 매체에 따른 성능 해석[I])

  • Won, S.H.;Lee, W.Y.;Chung, H.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.1 no.3
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    • pp.219-227
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    • 1989
  • Performance analysis of an absorption heat pump system for solar energy recovery has been done by computer simulation to find improved working pairs. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio have been calculated to compare two aqueous solutions [LiCl-water, $LiCi-CaCl_2-Zn(NO_3)_2$-water] which were developed for cooling by others, with the conventional LiBr-water solution. As a result of this analysis, the performances of the new aqueous solutions were found to be better than that of LiBr-water solution not only in cooling systems, but also in heating and in heat transformer systems. Their theoretical thermodynamic performance data were given here with.

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The Aqueous Corrosion Characteristics of Catenary Materials of Electric Railway System (전차선로 가선재의 수용액 부식 특성)

  • 김용기;장세기;조성일;이재봉
    • Journal of the Korean Society for Railway
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    • v.4 no.2
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    • pp.62-70
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    • 2001
  • Pure copper, Cu-1.1wt%Cd and ACSR(Aluminum Conductor Steel Reinforced) have been used as catenary materials of the electric railway system. Since these materials may be exposed to the corrosive environments like polluted air, acid rain and sea water, it is important to investigate the corrosion rates in various corrosive environments. The aqueous corrosion characteristics of catenary materials in aerated acid, neutral and alkali solutions were studied by using immersion corrosion tests, electrochemical measurements and analytical techniques. In order to examine corrosion characteristics according to the dissolved oxygen content, pH, chloride ion concentration ion, and the addition of Cd to Cu, a series of tests such as potentiodynamic polarization, a.c impedance spectroscopy and galvanic corrosion tests were carried out with these materials. Results showed that the addition of Cd to Cu and chloride ion in the solution have an adverse effects on the resistance to corrosion. Additionally, Galvanic currents between Al and steel wires of ACSR were confirmed by using ZRA(zero resistance ammeter) method.

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Thermodynamic Analysis of Double-effect Absorption Heat Pump System with New Working Pairs (작동매체에 따른 2중효용 흡수식 시스템의 성능해석)

  • Won, S.H.;Lee, Y.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.4
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    • pp.250-255
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    • 1991
  • Performance analysis of double-effect absorption heat pump system has been done to find improved working pairs (or mixture) by computer simulation. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio are investigated to compare three aqueous solutions [LiCl-water, LiSCN-LiBr-water, LiCl-$CaCl_2$-$Zn(NO_3)_2$-water] which was developed for only cooling, with conventional LiBr-water solution. It is found that the performances of the new aqueous solutions are better than that of LiBr-water solution not only in cooling systems, but also in heating systems. Theoretical thermodynamic performance data can be used in heat recovery systems by basic design data.

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Inhibiting Factors and Kinetics of Nonenzymatic Browning in Ginger(Zingiber officinale Roscoe) Paste Model System (생강 페이스트 모형액의 비효소적 갈색화 억제인자 및 반응속도)

  • 조길석;장영상;신효선
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1135-1139
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    • 1997
  • Major factors inhibiting nonenzymatic browning in stored ginger paste were investigated using aqueous model systems with temperature, water activity, pH and sulfur compounds. Browning index and total gingerols were measured during storage. The rate of nonenzymatic browning reactions showed a strong depencence on temperature and pH and a negligible influence on water activity. It was also reduced by the addition of 0.04% N-actyl-L-cysteine(NAcCys), effectively. Activation energies for aqueous ginger model systems with and without 0.04% NAcCys were 29.0 and 25.8kcal/mole, respectively.

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