• Title/Summary/Keyword: Aqueous system

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In Vitro Uptake of Salicylate by Human Red Blood Cells

  • Kim, Chone-Kook
    • Archives of Pharmacal Research
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    • v.2 no.1
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    • pp.65-70
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    • 1979
  • Distribution and binding properties of sodium salicylate the human red blood cells were studied under various experimental conditions. The effect of tonicity and hemolysis on the steady state level of the drug within the human red blood cells were accounted for in this study. When the washed cells were suspended in normal saline solution, the drug was so rapidly permeated into red cells. Since the pH of the system forces nearly complete ionization of the drug, ionic diffusion through aqueous pores is thought to be the mode of salicylate transport. Human red cell binding capacity and association constant for salicylate were estimated. This work supports the view that the red cells act asan important reservior of salicylate.

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MEK SEPARATION FROM ITS AQUEOUS SOLUTION BY MEMBRANE CONTACTOR

  • Hyoseong Ahn;Yoonjin Oh;Lee, Yongtaek
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.17-20
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    • 2003
  • Separation of MEK(methylethylketone) was carried out experimentally by a flat membrane contactor using a variety of extracting organic compounds. A correlation equation of Sherwood number was determined in terms of Reynolds number and Schmidt number for the flat membrane contactor system. This correlation equation was applied to get theoretically the overall mass transfer coefficient of MEK: it was compared to the experimental one. It was found that they are in good agreement.

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Medium effects on the H-Atom Abstraction and Silyl-Transfer Photoreactions of Silylalkyl Ketones

  • Oh, Sun-Wha
    • Journal of Photoscience
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    • v.12 no.1
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    • pp.47-50
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    • 2005
  • Mediumeffects have been explored on the competitive H-atom abstraction and SET-promoted, silyl-transfer reactions of excited states of silylalkyl-substituted phenyl ketones. The chemical selectivities of photochemical reactions of silylalkyl phenyl ketones appear to depend on medium polarity, medium silophilicity, added metal cation and alkyl length. Irradiations of silylalkylketones in aqueous solvent system and in presence of metal cation such as $Li^+$ and $Mg^{+2} $lead to formation of acetophenone predominantly by the sequential SET-silyl transfer route.

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Growth Behavial Couctive PolyanilineFilm on a Platinum Electrode by Electrochemical Oxidation (II) (전해산화에 의한 백금전극상 전도성 폴리아닐린 피막의 생장 거동(II))

  • 신성호;이주성
    • Journal of the Korean institute of surface engineering
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    • v.21 no.3
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    • pp.95-102
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    • 1988
  • The anodic oxidation of aniline in aqueous sulfuric acid solution on a platinum was studied. To examine of mechanism of this reaction, the date were obtained during controlled potential electrolysis, aided by computer system. The reaction mechanism was assumed the electrochemical-chemical-electrochemical(ECE) mechanism. We obtained the result that the intial charge transfer step proceeds through a radical cation, and this radical cation were bound cation led to may type of dimer in which p-aminodiphenylamine was de-electronated again to give the polymer.

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