• Title/Summary/Keyword: Aqueous binder

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Hydration Properties of High Volume Cement Matrix Using Blast Furnace Slag and Alkaline Aqueous by Electrolysis (고로슬래그 및 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 수화특성)

  • Kim, Sun-A;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.8-13
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    • 2017
  • This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

Mechanical Properties of Alumina-Glass Dental Composites Prepared from Aqueous-Based Tape Casting (수계공정에 의한 알루미나 테이프로 제조한 세라믹 인공치관용 알루미나 유리 복합체의 기계적 물성)

  • 이명현;김대준;이득용;이정훈;김창은
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1123-1131
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    • 1999
  • Alumina-glass composites which are considered as the material of the choice for all dental crown was prepared by aqeous-based tape casting and sintering for 2h at 1120$^{\circ}C$ followed by glass infiltration for 2h at 1100$^{\circ}C$ Biaxial strength and fracture toughness of the composites were evaluated to determine the optimum composition of the tape as a function of the amount of constituent such as alumina binder and plasticizer. The strength and the fracture toughness of the alumina tape increased with increasing the contents of alumina and binder. These observations are consistent with in fluence of the constituents on mean alumuna particle distance in tapes suggesting that high strength of the glass infiltrated alumina composites is related to toughening by crack bowing. The biaxial strength and the fracture toughness of the composite containing the optimum constituent composition were 523 MPa and 3.3 MPa$.$1/2 respectively.

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Electrochemical Properties of Carbon Nanofiber Electrode with Different PVDF Binder Concentration (PVDF 접합제 농도 변화와 탄소나노섬유 전극의 전기화학적 특성)

  • Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.446-451
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    • 2007
  • Physicochemical properties of carbon nanofibers were evaluated as a supercacitor electrode materials could store electrochemical energy reversibly. A capacitance of carbon nanofiber electrode was increased gradually, depending on the PVDF binder ratio. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. PVDF 5 wt.% ratio in electrode was observed a suitable binder amount by CV result.

Dispersion and Rheological Characteristics of Alumina Slurries in Aqueous Tape-casting Using Acrylate Binder (Acrylate를 결합제로 사용한 수계 테이프 캐스팅에서 알루미나 슬러리의 분산 및 점성 특성)

  • Cho, Yu-Jeong;Park, Il-Seok;Moon, Joo-Ho;Kim, Dae-Joon
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.164-170
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    • 2002
  • Measurements of sedimentation, solid loading, zeta potential, and viscosity were employed to determine a proper dispersant and its amount for a well dispersed alumina powders in aqueous alumina tape casting using acrylate as a binder. Polycarboxylic acid was the most effective one among various dispersants considered in the present study and its amount was 0.23∼0.24 g per 100 g alumina for a dispersion. Better dispersion was obtained as an increase of dispersant addition. However, the dispersion was hindered as the amount of dispersant was higher than the optimum amount because of bridging or tangling of polymer chains. Excellent aqueous alumina tapes were prepared from the slurry containing the optimum amount of the polycarboxylic acid (0.2g), alumina powders(100 g), acrylate and Benzoflex as binder and plasticizer, respectively. The viscosity of the slurry was 570 cps and the alumina loading in the tape was 57 vol%.

Evaluation of Chemical Resistance of Polymer Powder-Modified Mortars With Accelerators (급결제를 이용한 분말수지 혼입 폴리머 시멘트 모르타르의 내약품성 평가)

  • Lee Chol Woong;Mun Kyoung Ju;Xu Xiang Yu;Park Won Chun;Choi Nak Woon;Soh Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.555-558
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    • 2005
  • The purpose of this study is to evaluate the chemical resistance of polymer powder-modified mortars with special accelerator component. Polymer powder-modified mortars with the accelerator are prepared with various polymer-binder ratios, and tested for flexural and compressive strengths and mass change. Chemicals resistance was tested by dealing with $10\%$ HCl and $5\%\;H_2SO_4$ aqueous solution. As a result, the weight reduction ratio of the mortars decreased with increasing polymer-binder ratio. However, in the viewpoint of strength reduction by chemical attacks, the maximum chemical resistance of the mortars was shown at a polymer-binder ratio of $5\%$.

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A new Aqueous Injection Molding Method of Fabricating W-Cu Pseudo-alloy Part (수계 바인더를 이용한 W-Cu 합금의 새로운 사출성형법 연구)

  • Lee Jeong-Keun
    • Journal of Powder Materials
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    • v.13 no.1 s.54
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    • pp.57-61
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    • 2006
  • The present work illustrates the use of water-soluble cupric salts as ingredients of binder for injection molding of $W-10 wt\%$ Cu. Parts produced are dense, homogeneous and have good surface finish, compared to those produced using conventional binder system. This new binder system provides also process-simplification benefit. $CuCl_2\;and\;Cu(NO_3)_2$ with the purity of $98\%$ was selected for this study. Rapid sintering process involving thermal decomposing was successful in densification for 1h. Final density that is about $93\%$ of theoretical value could be obtained, and are distinguishable from conventionally processed W-Cu composites.

Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

Dispersion of Carbon Black in Acrylic Resin Aqueous Solution (아크릴 수지 수용액에서의 Carbon black의 분산에 관한 연구)

  • 오지만;김성빈;권대환
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.16-27
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    • 2002
  • Recently, the attraction for water-based ink is increasing, Because Solvent ink, based on organic solvent, cause bad effect on environment and rise the cost. Instead of organic solvent that cause environment pollution as well as cost-rise by rise of petroleum price, Binder based on alkali-soluble resin is popular and studied by many other country. However, in domestic, research and development for alkali-soluble resin is not like, because of lack of understanding environmental pollution and safety, therefor alkali-soluble resin development and research for the properties of the water-based ink used by alkali-soluble resin is not study very well. In this paper, we studied dispersion of carbon black in acrylic resin solution and the properties of water-based ink used by carbon black and acrylic binder.

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Superhydrophilicity of Titania Hybrid Coating Film Imposed by UV Irradiation without Heat-treatment (저온 경화형 초친수성 티타니아 하이브리드 졸의 제조와 친수성 특성 평가에 관한 연구)

  • Kim, Won-Soo;Park, Won-Kyu
    • Journal of Technologic Dentistry
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    • v.29 no.1
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    • pp.121-131
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    • 2007
  • A preparation process's conditions of aqueous sol which contains anatase-type nano titania particles with photocatalyic properties was established by using Yoldas process, so called, DCS(Destabilization of Colloidal Solution) process in this study. And crystal size change and phase transformation of titania particles in aqueous titania sol depending on reaction conditions was investigated by a light scattering method and XRD analysis of frozen dried powders, respectively. This sol with photo catalytic nano titania particles was used to the following hydrophilic hybrid coating film's fabrication and its properties was evaluated. Subsequently, for coating film using the above mentioned aqueous titania sol, non-aqueous titania sol was prepared without any chemical additives and its time stability according to aging time was investigate. By using the above mentioned aqueous titania sol and non-aqueous sol, a complex oxide coating sol for metal and ceramic substrate and a organic-inorganic hybrid coating sol for polymer substrate was prepared and it's hydrophilicity depending on UV irradiation conditions was evaluated. As a conclusions, the following results were obtained. (1)Aqueous titania sol The average particle size of titania in formed aqueous titania sol was distributed between 20$\sim$90nm range depending on reaction conditions. And the crystal phase of titania powders obtained by frozen drying method was changed from amorphous state to anatase and subsequently transformed to rutile crystal phase and it is attributed to concentration gradient in aqueous sol. (2)Non-aqueous titania sol Non-aqueous titania sol was prepared using methanol as a solvent and a little distilled water for hydrolysis and nitric acid as a catalyst were used. The obtained non-aqueous titania sol was stable at room temperature for 20 days. Additionally, non-aqueous titania sol with addition of chealating reagent such as acethylaceton and ethylene glycol prolonged the stability of sol by six months. (3)Complex sol and hybrid sol with super hydrophilicity The above mentioned aqueous titania sol as a main photocataylic component and non-aqueous titania sol as a binder for coating process was used to prepare a complex sol used for metal, ceramic and wood material substrate and also to prepare the organic-inorganic hybrid sol for polymer substrate such as polycarbonate and polyethylene, in which process APMS(3-Aminopropyltrimethoxysilane), GPTS(3-Glycidoxypropyl-trimethoxysilane) as a hydrophilic silane compound and HEMA(2-Hydroxyethyl methacrylate) as a forming network in hybrid coating film were used. The hybrid coating film such as prepared through this process showed a superhydrophilicity below 1$10^{\circ}$ depending on processing conditions and a pencil's hardness over 6 H.

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