• Textile Coloration and Finishing
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• v.34 no.3
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• pp.165-172
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• 2022

Polypropylene(PP) is a textile material with various functions such as eco-friendliness, lightness, and elasticity. Although most synthetic fibers can be dyed and finished, but original PP is difficult to dye or finish due to its extremely hydrophobic properties, so its application expansion is limited. In order to solve this problem, dyeable PP was developed, and various researches on textiles for clothing such as mass production technology, fine fiberization and performance improvement are in progress. Plasma treatment is a processing method for modifying the surface of fabrics, and has effects such as hydrophilization, deepening color, improving adhesion, and surface polymerization. In this study, plasma treatment was applied to study changes in hydrophilization properties of dyeable PP, surface changes before and after plasma treatment and performance according to hydrophilization.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.196-200
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• 2013

We conducted investigation on polymeric binders for anti-static coating agent which can maintain stability under the high-voltaic condition. Various polyesters composed of polyethylene glycol (PEG) and polypropylene glycol (PPG) were synthesized and studied in term of the variation in the surface resistance of the film made from coating solution composed of a conductive polymer and these polyesters as a binder. We found that the surface resistance displayed $10^7{\sim}10^8{\Omega}/{\square}$ regardless of chemical composition of binders under the potential of 10 V. Whereas, the surface resistance surged to higher than $2{\times}10^{10}{\Omega}/{\square}$ when 1000 V was applied, rendering it improper for anti-static purpose. When 1,4 butanediol (BD) was incorporated into polyesters ([PEG]/[PPG]/[BD] = 25.0/67.5/7.5), the surface resistance showed $2.8{\times}10^9{\Omega}/{\square}$ under 1000 V, acceptable for anti-static application. These observations may indicate that the hydrophobic nature of BD makes a significant contribution to the surface resistance at a high positive potential.

• Polymer(Korea)
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• v.36 no.4
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• pp.531-535
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• 2012

Conductive polyaniline (PANI) nanofibers in UV-curable resin were used for a transparent conductive film. The emeraldine-salt PANI (ES-PANI) nanofibers were prepared by chemical oxidation polymerization of aniline, which could be changed into emeraldine-base PANI by dedoping. EB-PANI nanofibers as a precursor for conductive fillers were thereby transformed into re-dpoed PANI (rES-PANI) by dodecylbenzenesulfonic acid in the UV-curable resin solution. rES-PANI nanofibers have high conductivity and long-term stability in the solution without a defect of nanostructure. The resulting conductive resin solution was proved to be highly stable where no precipitation of rES-PANI fillers was observed over a period of 3 months. The transparent film was spin-casted on a poly(methyl methacrylate) sheet of thickness ca. $5{\mu}m$. A surface resistance of $6.5{\times}10^8{\Omega}/sq$ and transmittance at 550 nm of 91.1% were obtained for the film prepared with a concentration of 1.4 wt% rES-PANI nanofibers in the solution. This transformation process of rES-PANI from ES-PANI by dedoping-redoping can be an alternative method for the preparation of an antistatic protection film with controllable surface resistance and optical transparencies with the PANI concentration in UV-curable solution.

• Journal of the Korean Society of Clothing and Textiles
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• v.11 no.1
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• pp.51-62
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• 1987

In this study, electrostatic behavior of polyester and nylon fabric treated with anti-static agents were investigated. The effects of the concentration of the agents and curing conditions on the electrostatic charge of the fabrics were studied. And washfastness, lightfastness and physicalproperties of the treated fabrics were also investigated. The results were as follows: 1) Polyethylene glycol alkylester was more effective in antistatic behavior than polyethylene laurylphosphate, and polyester is more effective in anti-static behavior than nylon. 2) Concentration of anti-static agents were suitable in concentration of $4\%$. 3) Glyoxal resin was more effective in anti-static behavior than melamine resin, and it was also good in the retaing anti-static behavior after treatments of lightfastness and washfastness. 4) As the condition of curing treatment, $190^{\circ}C$, 1min. for glyoxal resin and $130^{\circ}C$, 4min. for melamine resin is appropriate. 5) In comparison of anti-static behavior according to treating conditions, the simultaneous treatment was more effective than any other treatments. 6) Change of electrostatic charge of anti-static nylon cloths after treatments of lightfastness and washfastness increased greatly in above 10 laundering time and 20 fade-O-meter time. 7) In physical properties according to concentration of treating agents. decrease of physical properties scarcely appeared in concentration of treating agents $4\~5\%$.

• Textile Coloration and Finishing
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• v.4 no.1
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• pp.1-9
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• 1992

In order to study on the surface modification of the poly(ethylene Terephthalate)(PET) fabrics, low temperature plasma$(O_2)$ has been irradiated on the PET fabrics in various conditions. Experiments were carried out at pressure ranging from 0.5 tort to 3 tort. The properties of PET fabrics treated with low temperature plasma($(O_2)$, such as bathochromic, wettability, antistatic property were measured. Etching ratio was increased as the pressure and the output of discharge increased. When its were put on the cathode, the most efficient effect of etching according to the position of sample between anode and cathode was obtained. The bathochromic effect has more or less improved as pressure was getting higth in case of dyed fabrics treated with only low temperature plasma$(O_2)$ . And when it was treated with the low refractive index resin, the bathochromic of dyed fabrics treated with low temperature plasma$(O_2)$ was better than that of the dyed fabrics untreated.

• Nuclear Engineering and Technology
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• v.10 no.4
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• pp.195-201
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• 1978

The radiation-induced graft polymerization of methacrlic acid and methyl methacrylate onto a polyester fabric was investigated with ${\gamma}$-ray as the radiation source, and the rate of grafting was examined. When acrylic acid, methacrylic acid, and methyl methacrylate were grafted onto a polyester fabric, grafting efficiency was depened upon the dielectric constant of the solvent in the monomer mixture. The yield of the graft polymerization was related to the total dose, the concentration of the monomer, and the concentration of the swelling agent. The melting point and the glass transition temperature of MA and MMA grafted copolymers were analysed by means of DTA. Physical properties, such as the moisture regain, the antistatic property, and the wicking time were measured.

• Textile Coloration and Finishing
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• v.17 no.3 s.82
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• pp.1-7
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• 2005

Cationic dyeable polyester(CDP) was produced through melt blending of cationic chips having $2mol\%$ of sodium salt of dimethyl ester of 5-sulfoisophthalic acid(DMS salt) and normal polyester chips in different proportions to obtain yarns having varying amount of comonomer in the fiber. The modified polyesters showed increased moisture regain, decreased viscosity, lower softening point and improved antistatic characteristics, according to the amount of modifier. In dyeing at $100^{\circ}C$ the dyeing rate of cationic dyes with CDP fiber increased slowly than that of disperse dyes. In dyeing at $120^{\circ}C$ cationic dyes reached to equilibrium at 30min and disperse dyes at 10min. Cationic dyes in dyeing of CDP fabric have a better wash fastness compared with disperse dyes, also rubbing fastness of cationic dyes is better than that of disperse dyes. The light fastness of CDP fabric for cationic and disperse dyes is not good. The fastness of 75d/36f CDP fabric is higher than 75d/72f fabric. Solvent wicking fastness of CDP with cationic dyes is better than that of disperse dyes.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.26 no.2
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• pp.74-79
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• 2016

The lanthanum oxide nano-rods were grown on the surface of 3 mol% Yttria Partially Stabilized Zirconia ceramic composite which containing Lanthanum-Strontium Manganate, $La_xSr_yMn_zO_3$ for the purpose of endorsing the antistatic property. The diameter and the aspect ratio of the nano-rods were greatly changed according to the growing condition. With the optical microscope observation, the nano-rods shining brightly. It was confirmed that the major components of nano-rods is La, and Sr, Mn, Si are minor components by SEM and TEM analyses.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.1138-1141
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• 2004

고분자 재료에 이온을 주입하면 표면전기저항이 이온주입조건에 따라 $10^{16}\Omega/sq$ 에서 $10^7\Omega/sq$ 까지 변하게 되며, 광학적 특성도 변하게 된다. 이는 산업적으로 대전방지 등에 적용이 가능하며 이러한 신소재 개발을 위하여 산업용 이온빔 표면처리 장치를 제작하고 인출광학을 기초로 이온빔을 제어하여 고분자 재료의 이온주입처리 양산기술을 개발하였다. 본 연구에서는 대면적, 대전류 이온빔 인출을 위한 이온원의 광학적 설계 및 빔라인에서의 솔레노이드 전자석을 이용한 빔프로파일 제어방법을 설명하였다. 사용된 고분자 소재는 PC(PolyCarbonate) 및 PET(PolyEthylene Teraphthalate)이며, 질소이온주입조건은 이온에너지 40-50 keV, 이온주입량 $5\times10^{15}$, $1\times10^{16}$, $7\times10^{16}ions/cm^2$의 조건으로 공정을 수행하였다. 또한 대전방지용 고분자 대량생산을 위한 연속 생산조건과 양산공정조건에 따른 표면전기저항변화를 관찰하였다.

• Fire Science and Engineering
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• v.25 no.3
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• pp.107-112
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• 2011

We have considered the fire hazard by the static in anti-static film manufacturing factory on this study. Solvents that the flash point as ethanol, methanol and iso-propyl alcohol is low are used on the manufacturing process of anti-static film, and the minimum ignition energy of these solvents is ignited easily despite less discharge energy form 0.16 mJ to 0.65 mJ. After the static electric potential produced on each of the manufacturing plants was measured, electric potential on films of paste board is measured form 17 kV to 20 kV. But this exceeds 5 kV, which is electrifiable of objective of nonconductor for fire & explode protection. Therefore, We figure out the fire hazard was high by a static discharge in anti-static film manufacturing factory.