• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1939-1944
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• 2007

New liquid crystalline (biphenylcarbonyloxy)benzoates with an achiral swallow-tail derived from 3-alkoxy-2- (alkoxymethyl)-1-propanol [(ROCH2)2CHCH2OH, R = Me, Et, Pr, Bu] were prepared. These liquid crystals exhibited the phase sequence (I-SmA-SmCalt-(SmCX)-Cr) and showed antiferroelectric-like Smectic C phase (SmCalt) at temperature lower, and temperature range broader than do the compounds containing a branched alkyl group as a swallow-tail. The temperature ranges of antiferroelectric phase were found to be 30-90 oC and crystallization temperatures were 4-60 oC. The binary mixture of an achiral swallow-tailed liquid crystal and a chiral antiferroelectric liquid crystal, (S)-MHPOBC showed antiferroelectric smectic C phase at temperature much lower than the single chiral antiferroelectric liquid crystal does.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.441-444
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• 2002

If an antiferroelectric liquid crystal (AFLC) cell is set between crossed polarizers for optical modulators or displays, it has low transmittance efficiency. This happens because AFLC materials have inherent tilt angles of typically $18^{\circ}{\sim}38^{\circ}$, not $45^{\circ}$. To improve the low transmittance efficiency, we propose a new optical configuration for antiferroelectric liquid crystal displays, which also improves color dispersion.

• Proceedings of the KIEE Conference
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• 1987.11a
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• pp.220-223
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• 1987

In this paper, electro-optic characteristics of PLZT 7.6/70/30 composition in MPB regions, which antiferroelectric and ferroelectric phases coexist together, were studied. As sintering times are increased, Curie temperatures ore linearly decreased. And the antiferroelectric phase becomes more stronger when Curie temperatures are decreased. The crystal structure investigated by lie of X-ray analysis is proved to cubic in the thermally depoled specimen and rhombohedral in the poled specimen. Accordingly, the applicability of 7.6/70/30 specimen as image storage and display device is expected by the method for applying field induced reversible transitions between antiferroelectric(AFE) and ferroelectric(FE) phase.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1239-1243
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• 1997

A phase analysis in the solid solution of (1-x) PbFe1/2Nb1/2O3-xPbCo1/2W1/2O3 is conducted by dielectric properties, heat capacity and E-P hysteresis at x=0.1 interval. Lattice constants and superlattice intensity are analyzed by the x-ray diffraction, and the temperature - composition phase diagram is determined. The system is found to form a solid solution of perovskite structure throughout the entire composition range, but the nature of phase transitions changes from ferroelectric-paraelectric for $0{\leq}x{\leq}0.5$ to antiferroelectric-paraelectric for $0.6{\leq}x{\leq}1.0$. The transitions of ferroelectric-paraelectric and antiferroelectric-paraelectric for $0.2{\leq}x{\leq}0.5$ and for $0.6{\leq}x{\leq}0.8$, respectively, are diffuse, while those of the ferroelectric-paraelectric and the antiferroelectric-paraelectric for $0.0{\leq}x{\leq}0.1$ and $0.9{\leq}x{\leq}1.0$, respectively are sharp.

• Coupled systems mechanics
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• v.6 no.1
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• pp.29-40
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• 2017

This work employed density functional theory to investigate the structural and ferroelectric properties of the Ruddlesden-Popper (RP) phase of lead titanate, $Pb_2TiO_4$, as well as its phase transitions with epitaxial strain. A wealth of novel structural instabilities, which are absent in the host $PbTiO_3$ material, were identified in the RP phase through phonon soft-mode analysis. Our calculations showed that the ground state of $Pb_2TiO_4$ is antiferroelectric, distinct from the dominant ferroelectric phase in the corresponding host material. In addition, applied epitaxial strain was found to play a key role in the interactions among the instabilities. The induction of a sequence of antiferroelectric and antiferrodistortive (AFD) phase transitions by epitaxial strain was demonstrated, in which the ferroic instability and AFD distortion were cooperative rather than competitive, as is the case in the host $PbTiO_3$. The RP phase in conjunction with strain engineering thus represents a new approach to creating ferroic orders and modifying the interplay among structural instabilities in the same constituent materials, enabling us to tailor the functionality of perovskite oxides for novel device applications.

• Proceedings of the Optical Society of Korea Conference
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• 1999.08a
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• pp.206-207
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• 1999

• Journal of Information Display
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• v.3 no.4
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• pp.1-3
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• 2002

The antiferroelectric liquid crystal display (AFLCD) is a unique display that can at demonstrate a moving image perfectly the passive matrix driving scheme. We optimised driving the waveform and introduced a dual-driving method. Also, by improving this driving method and using line inversion method, we realize the AFLC display of high image quality with $160(RGB){\times}240$, 32768 colors, crosstalk free and flicker free contrast ratio is greater than 60:1, and the brightness is above 200 $cd/m^2$.

• Korean Journal of Optics and Photonics
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• v.13 no.2
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• pp.162-165
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• 2002

We propose an optical configuration for a transflective display mode using a transflective film and a half-wave AFLC cell whose in-plane tilt angle is 22.5。. It provides high brightness and high contrast in the reflective mode as well as in the transmissive mode.

• Journal of Information Display
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• v.1 no.1
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• pp.48-51
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• 2000

In this work, we proposed a reflective antiferroelectric liquid crystal display (AFLCD) using a half-wave cell whose inplane tilt angle is $22.5^{\circ}$. To check the validity of our design, we fabricated a reflective half-wave AFLC cell of which inplane tilt angle is $24.9^{\circ}$, and measured VIS reflection spectra, contrast ratio and response time. In the results, the half-wave AFLC cell in the reflective configuration exhibits high brightness, high contrast ratio of 20:1, and fast response time of $700{\mu}s$.

• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.575-577
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• 2003

Achiral swallow-tailed liquid crystals derived from 1,3-dialkoxy-2-propanol were prepared and their mesomorphic properties were investigated. 1,3-Dialkoxy-2-propyl swallow-tailed material showed antiferroelectric-like smectic C phase at lower temperature and in broader temperature range than the corresponding compounds with a branched alkyl group as a swallow-tail. They could serve as suitable host for antiferroelectric mixtures.