• Title/Summary/Keyword: Anthracite

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Variation of Pore Structure of Coal-based Activated Carbon with Burn-off of Steam Activation (수증기 활성화법으로 제조된 석탄계 활성탄의 Burn-off에 따른 세공구조의 변화)

  • Lee, Song-Woo;Moon, Jang-Cheon;Lee, Chang-Han;Choi, Dong-Hoon;Ryu, Dong-Chun;Song, Seung-Koo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2141-2148
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    • 2000
  • This study is to investigate changes of pore structure with different burn-off degree of steam activated carbons manufactured from domestic anthracite. The activated carbons were characterized by adsorption of nitrogen at 77 K. Steam activation substantially enhanced the porosity of the activated carbons. Burn-off increased linearly according to increasing activation time, and total pore volume and BET surface area increased with burn-off. Activation at $800^{\circ}C$ increased more micropore volume than that at $950^{\circ}C$. Activated carbons manufactured at high temperature had less microporosity than that at lower temperature, but had more developed macroporosity. The steam activation produced an enlargement of pore below $100{\AA}$ diameter in the activated carbons. Furthermore, the porosity in the $6{\sim}40{\AA}$ pore diameters range increased considerably with the degree of burn-off.

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An Analysis of the Flow and Bed Topography Characteristics of Curved Channels with Numerical Model (수치모형에 의한 만곡수로의 흐름 및 하상 특성 분석)

  • Jeong, Jae-Uk;Han, Jeong-Seok;Yun, Se-Ui
    • Journal of Korea Water Resources Association
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    • v.33 no.1
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    • pp.111-121
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    • 2000
  • A numerical model which can analyze the flow and bed topography characteristics of a single bend and continuous one was suggested using the equations of mass, momentum, the vertical distribution of secondary flow, and the transverse bed slope. The calculated flow and bed topography characteristic values were compared with the experimental data in a single bend, and the predicted path of maximum streamwise velocity in continuous bends also compared with the Vadnal and Chang's data. The comparisons gave good results. A curved channel with 180 degrees was used. Sand and anthracite were selected as bed materials in the movable bed experiments. The model application of this model to the sand bed and the anthracite one accorded well with the observed values in the experiments. This model was proved to be useful for predicting the flow and bed topography with the change of bed materials. The results of this research could be used to construct and control curved channels as a fundamental information.mation.

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Effect of the imported bituminous coal and the domestic anthracite coal mixed with petroleum coke (석유코크스와 혼합된 국내무연탄과 수입유연탄 슬래그의 특성 규명)

  • Kim, Min-Kyung;Oh, Myong-Sook S.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.230-233
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    • 2008
  • The vanadium rich ash of petroleum coke can give a slagging problem during because of the high melting point of $V_2O_3$. For continuous removal of the slag, petroleum coke is often mixed with coal, and the viscosity of the mixed slag is an important property, determining the gasification temperature. The viscosities of the mixed slag from various mixing ratios of petroleum coke and a bituminous coal were investigated. When mixed with a crystalline coal slag, $T_{cv}$ was increased at a higher the coke content in the mixed feed. When the $V_2O_3$ concentration was greater than 4.5%, it was difficult to get accurate measurements of $T_{cv}$. The SEM/EDX analyses of the cooled slag revealed that the major crystalline phase was anorthite, and $T_{cv}$ should be related to the formation temperature of anorthite. The SEM/EDX analyses also showed that, at low concentrations of vanadium, part vanadium formed a crystalline phase with Al-Si-Ca-Fe, and the rest remained in the glassy phase, suggesting that vanadium existed as a slag component at the low viscosity region. At a high concentration, vanadium forms a phase with Ca, and the Ca-V phase was separated from the slag phase, and formed a layer above the slag. FeO in petroleum coke also played an important role determining viscosity: at high temperatures, increased FeO lowered the viscosity, but as it formed a spinel phase, the depletion of FeO in the slag resulted in a higher viscosity.

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Development of pre-treatment for the injection water into the aquifer storage and recovery(ASR) in Korea: The two-step rapid filter to reduce physical clogging and secure the volume of the injected water (지하저수지(ASR) 유입수 전처리기법 개발: 물리적 폐색 저하 및 수량공급원활을 위한 2 단계 급속여과지)

  • Park, Byeong-Joo;Do, Si-Hyun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.3
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    • pp.337-345
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    • 2015
  • Two step rapid filter system as a pre-treatment for the injected water into aquifer storage and recovery (ASR) in Korea was developed to reduce physical blockage and secure the volume of the injected water. First, single rapid sand filters with three different media sizes (0.4~0.7, 0.7~1.0 and 1.0~1.4 mm) were tested. Only two sizes (0.4~0.7 and 0.7~1.0 mm) satisfied target turbidity, below 1.0 NTU. However, they showed the fast head loss. To prevent the fast head loss and secure the volume of the injected water, a rapid anthracite filter with roughing media size (2.0~3.4 mm) were installed before a single rapid sand filter. As results, both the target turbidity and reduction of head loss were achieved. It was determined that the media size for a rapid sand filter in two step rapid filter system (i.e. a rapid anthracite filter before a rapid sand filter) was 0.7~1.0 mm. In addition, the effects of coagulant doses on the removal of natural organic matter (NOM), which might cause a biological clogging, were preliminarily evaluated, and the values of $UV_{254}$, dissolved organic carbon (DOC) and SUVA were interpreted.

Estimated CO2 Emissions and Analysis of Solid Recovered Fuel (SRF) as an Alternative Fuel

  • Kim, Sang-Kyun;Jang, Kee-Won;Hong, Ji-Hyung;Jung, Yong-Won;Kim, Hyung-Chun
    • Asian Journal of Atmospheric Environment
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    • v.7 no.1
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    • pp.48-55
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    • 2013
  • The purpose of this study was to develop a $CO_2$ emission factor for refuse plastic fuel (RPF) combustion facilities, and calculate the $CO_2$ emissions from these facilities. The $CO_2$ reduction from using these facilities was analyzed by comparing $CO_2$ emission to facilities using fossil fuels. The average $CO_2$ emission factor from RPF combustion facilities was 59.7 Mg $CO_2$/TJ. In addition, fossil fuel and RPF use were compared using net calorific value (NCV). Domestic RPF consumption in 2011 was 240,000 Mg/yr, which was compared to fossil fuels using NCV. B-C oil use, which has the same NCV, was equal to RPF use. In contrast, bituminous and anthracite were estimated at 369,231 Mg/yr and 355,556 Mg/yr, respectively. In addition, the reduction in $CO_2$ emissions due to the alternative fuel was analyzed. $CO_2$ emissions were reduced by more than 350 Mg $CO_2$/yr compared to bituminous and anthracite. We confirmed that using RPF, an alternative fuel, can reduce $CO_2$ emissions.

Effect of Carbon Materials on the Slag Foaming in EAF Process (전기로 슬래그 포밍에 미치는 가탄재 종류의 영향)

  • Kim, Young-Hwan;Yoo, Jung-Min;Um, Hyung-Sic
    • Resources Recycling
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    • v.28 no.2
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    • pp.40-45
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    • 2019
  • During steelmaking in EAF, recycled scraps is used as a main material, melted by arc, and electricity use as a main energy. Slag foaming is an important technology for reducing electrical energy. CO gas generated by the reaction between injection carbon and (FeO), [C] and injection {$O_2$}. CO gas generated by this reaction is collected in slag, resulted in slag foaming. In general, the carbon materials used in the EAF process is anthracite and coke. This study investigated the effects of the carbon materials used on slag foaming in the steelmaking process. As a result of this study, the slag foaming height is increased by cokes rather than anthracite, and with an increase in the amount of particles samller than $500{\mu}m$. Based on these results, the application to the operation resulted in increase of slag forming height, reduction of injection carbon, and reduction of electrical energy.

Usage of Coal in the Paradigm Shift toward Sustainable Energy (지속가능 에너지 패러다임 변화속에서 석탄의 활용)

  • Park, Jay Hyun;Yang, In Jae;Lee, Jin Soo;Lee, Cheong Ryong
    • Economic and Environmental Geology
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    • v.53 no.6
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    • pp.793-807
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    • 2020
  • The policy for Green New Deal will promote the shift of the application to coal as feedstock from coal as fuel. Coal can be used as fuel for production of hydrogen and as feedstock materials such as synthetic graphite or activated carbon. Hydrogen is obtained from syngas produced through Steam carbon(SC), Water-Gas Shift(WGS), and Carbonation reactions, and these processes should be used in conjunction with CO2 sequestration technology. Anthracite has a potential in terms of cost advantage as a feedstock compared to a petroleum pitch, because Synthetic graphite is prepared by heat treating an anthracite with high rank to a graphitization temperature which is in the range of 2400~2800℃, in the presence of inorganic catalyst such as silicon or iron. From several studies, it has been confirmed that coal-based activated carbon(AC) is manufactured with quality similar to the large specific surface area and much micropore volume of lignin-based AC, can be prepared. Therefore it is expected that lignin-based AC is replaced to coal-based AC.

Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil (Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響))

  • Kim, Yong-Woong;Yun, Chong-Hee;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.275-283
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    • 1994
  • The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

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The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea (한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.18 no.1
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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Characteristics of pore structure of steam activated carbon with carbonization temperature (수증기 활성화법으로 제조된 활성탄의 탄화온도에 따른 세공구조 고찰)

  • 이송우;나영수;김도한;최동훈;류동춘;송승구
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.345-349
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    • 2000
  • Activated carbons were prepared from Korean coal by steam activation in this study. The variation of pore structure of the activated carbons were investigated according to different carbonization temperatures. Yield, surface area, pore volume and pore structure of this activated carbon were compared with those of activated carbon prepared without carbonization. The investigated carbonization temperature ranged from 700${\circ}C$ to 1,000${\circ}C$. Carbonization was carried out in nitrogen atmosphere for 70 minutes and activation was performed by steam at 950${\circ}C$ for 210 minutes. Surface area and pore volume of the resulting activated carbons increased with carbonization temperature. Also pore volume increased by 20% compared to the activated carbon without carbonization. Especially, in mesopore region, the activated carbon carbonized at 900${\circ}C$ had more pores by 60% than that of activated carbon carbonized at other temperature.

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