• Title/Summary/Keyword: Anode Effect

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Effect of Fabrication Method of Anode on OCV in Enzyme Fuel Cells (효소연료전지의 Anode 제조조건이 OCV에 미치는 영향)

  • Kim, Young-Sook;Lee, Se-Hoon;Chu, Cheun-Ho;Na, Il-Chai;Lee, Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.6-10
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    • 2015
  • Enzyme fuel cells were composed of enzyme anode and PEMFC cathode. Enzyme anodes was fabricated by compression of a mixture of graphite particle, glucose oxidase as a enzyme and ferrocene as a mediator, and then coated with Nafion ionomer. Open circuit voltage (OCV) were measured with variation of anode manufacture factors, to find optimum condition of enzyme anode. Optimum pressure was 9.0 MPar for enzyme anode pressing process. Highest OCV was obtained at 60% graphite composition in enzyme anode. Optimum glucose concentration was 1.7mol/l in anode substrate solution and enzyme activity of anode was stable for 7 days.

Effect of Target Angle and Thickness on the Heel Effect and X-ray Intensity Characteristics for 70 kV X-ray Tube Target

  • Kim, Gyehong;Lee, Rena
    • Progress in Medical Physics
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    • v.27 no.4
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    • pp.272-276
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    • 2016
  • To investigate the optimum x-ray tube design for the dental radiology, factors affecting x-ray beam characteristics such as tungsten target thickness and anode angle were evaluated. Another goal of the study was to addresses the anode heel effect and off-axis spectra for different target angles. MCNPX has been utilized to simulate the diagnostic x-ray tube with the aim of predicting optimum target angle and angular distribution of x-ray intensity around the x-ray target. For simulation of x-ray spectra, MCNPX was run in photon and electron using default values for PHYS:P and PHYS:E cards to enable full electron and photon transport. The x-ray tube consists of an evacuated 1 mm alumina envelope containing a tungsten anode embedded in a copper part. The envelope is encased in lead shield with an opening window. MCNPX simulations were run for x-ray tube potentials of 70 kV. A monoenergetic electron source at the distance of 2 cm from the anode surface was considered. The electron beam diameter was 0.3 mm striking on the focal spot. In this work, the optimum thickness of tungsten target was $3{\mu}m$ for the 70 kV electron potential. To determine the angle with the highest photon intensity per initial electron striking on the target, the x-ray intensity per initial electron was calculated for different tungsten target angles. The optimum anode angle based only on x-ray beam flatness was 35 degree. It should be mentioned that there is a considerable trade-off between anode angle which determines the focal spot size and geometric penumbra. The optimized thickness of a target material was calculated to maximize the x-ray intensity produced from a tungsten target materials for a 70 keV electron energy. Our results also showed that the anode angle has an influencing effect on heel effect and beam intensity across the beam.

A Study on Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 이용한 레일부식 저감 방안에 관한 연구)

  • Choi, Jung-Youl;Kim, Jun-Hyung;Lee, Kyu-Yong;Kim, Young-Ki;Park, Jong-Yoon;Song, Bong-Hwan;Seol, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.54-60
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    • 2017
  • A railway rail will be corroded by the repetitive sea wind and fog in the splash and tidal zone such as Youngjong grand bridge. And these rusts of rail could be increased by increasing service period, and it frequently occurred the safety accidents or disorders in electrical problem. In this study, the sacrificial anode cathodic protection method was proposed as a measures for reducing the corrosion of the railway rails in the oceanic climate conditions. As the results of immersion test using the salt water during four months, the sacrificial anode cathodic protection method using the aluminum anode(Al-anode) was evaluated that a distinct effect on corrosion reduction in the rails. Therefore the sacrificial anode cathodic protection method was experimentally proven that a disorders in aspects electric and signal of railway operation condition such as direct fixation track system in Youngjong grand bridge could be prevented by reducing rust falling from the rail. In addition, the installation conditions of the anodes directly affect the transmission range of corrosion potential, the sectional loss of anode, and the corrosion reduction effect. Therefore, to expect the corrosion reduction effect of rails under the oceanic climate conditions for railway track, it was important to adopted the appropriate spacing of anode installation by considering the actual field conditions.

Effect of Porous Flow Field on PEMFC Performance with Dead Ended Anode System (Dead ended anode 시스템에서 다공성 유로가 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.646-652
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    • 2022
  • The dead-end anode (DEA) system is a method that closes the anode outlet and supplies fuel by pressure. The DEA method could improve fuel usage and power efficiency through system simplification. However, flooding occurs due to water and nitrogen back diffusion from the cathode to the anode during the DEA operation. Flooding is a cause of decreased fuel cell performance and electrode degradation. Therefore, tthe structure and components of polymer electrolyte membrane fuel cell (PEMFC) should be optimized to prevent anode flooding during DEA operation. In this study, the effect of a porous flow field with metal foam on fuel cell performance and fuel efficiency improvement was investigated in the DEA system. As a result, fuel cell performance and purge interval were improved by effective water management with a porous flow field at the cathode, and it was confirmed that cathode flow field structure affects water back-diffusion. On the other hand, the effect of the porous flow field at the anode on fuel cell performance was insignificant. Purge interval was affected by metal foam properties and shown stable performance with large cell size metal foam in the DEA system.

Compact Anode Design with the Heat Capacity Performance in Rotating Anode X-ray Tube for Digital Radiography

  • Lee, Seok Moon
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.136-141
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    • 2015
  • We studied the compact anode design to develop 100 kW rotating anode X-ray tube with large focal spot 1.2 mm, small focal spot 0.6 mm and tube voltage 150 kV for large hospital digital radiography using computer thermal simulation. The larger thermal radiation effect in a high vacuum can reduce the temperature of anode so the method to increase the surface area of anode is investigated. The anode has the multi-tier shape at the back side of TZM body of anode and also bigger diameter of anode. The number of multi-tiers was varied from 6 to 15 and the diameter of anode was also varied from ${\Phi}74$ to ${\Phi}82$. From ANSYS transient thermal simulation result, we could obtain $1056.4^{\circ}C$ anode maximum temperature when applying 100 kW input power at 0.1 second on target focal track which is less than $1091^{\circ}C$ of the conventional 75 kW X-ray tube with reduced anode weight by 15.5% than the conventional anode. The compact anode of reduced anode weight is able to improve the unwanted noise when the rotor is rotating at high-speed and also reduce the rotational torque which the cost effective stator-coil is possible. It is believed that the anode with 15 ea multi-tiers using ${\Phi}82$ can satisfy with the specification of the anode heat capacity. From the results of this paper, it has been confirmed that the proposed compact anode can be used as the anode of 100 kW rotating anode X-ray tube for digital radiography.

Effect of the Chathodic Protection in Concrete by Applying Sacrificial Anode System (희생양극방식을 응용한 콘크리트 중의 철근의 전기방식 효과)

  • 김성수;김홍삼;김진철;김종필;박광필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.87-92
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    • 2001
  • Reinforced concrete have defect in durability due to carbonation, freezing and thawing, and penetration of chloride ions with time in spite of superb structure. Especially steel corrosion in concrete due to penetration of chloride ions have result in a marked decline in service life. The principal purpose in this study is to see effect of sacrificial anode cathodic system, one of the electrochemical methods in order to the control of steel corrosion in concrete. There are chloride content in concrete in cracked and no cracked specimen with cathodic protection. To recognize the effect of sacrificial anode cathodic protection, Instant-off potential are measured. We have the excellent effect for control steel corrosion adaption sacrificial anode cathodic system.

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The Anode Heel Effect caused by changing the Angle of X-Ray Tube (X-선관 각도 변경에 따른 Anode Heel Effect)

  • Shin, Seong-gyu;Lee, Hyo-Yeong
    • Journal of the Korean Society of Radiology
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    • v.10 no.6
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    • pp.435-442
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    • 2016
  • This study was an investigation of the anode heel effect caused by changing the angle of the x-ray tube. We established the following conditions for experimental measurements: 70 kV, 30 mAs, focus-detector distance of 100cm, and a collimator setting of $35{\times}43cm^2$. The measurement points were set up at the center of the collimator and extended to each side in intervals of 3.5cm, with points A1, A2, A3, A4, A5, A6 on the anode side and points C1, C2, C3, C4, C5, C6 on the cathode side. We measured the entrance surface dose from point A6 to point C6 with each point perpendicular to an x-ray tube. And we did the same when measuring different angles of the x-ray tube from 15 to 30 degrees for every point on the anode and cathode sides. Using perpendicular x-ray tube, we found that the entrance surface dose of the A5 point was three times higher than that of the C5 point. Thus, we conclude that if the anode side is placed near highly radiosensitive organs, then there will be less radiation exposure when using a perpendicular x-ray tube. When imaging using x-ray tube angles, an angle to the cathode side can reduce the gap of the entrance surface dose on both the anode and cathode sides. When imaging areas where there are differences in thickness between the upper and lower sides, the angle to the cathode side that is closer to the thicker area can reduce the gap of the entrance surface dose and capture a higher quality image.

A Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship's Materials (선박재료용 SS400강의 내식성에 대한 용접후열처리효과에 관한 전기화학적 연구(I))

  • 김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.6
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    • pp.806-813
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    • 1999
  • The effect of Post-Weld Heat Treatment(PWHT) of SS400 Steel was investigated with parameters such as micro vickers hardness corrosion potential polarization behaviors galvanic current Al anode generating current Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM)by PWHT is lower than that of each parts by Non Post-Weld Heat Treatment(NPWHT) However hardness of WM of HAZ part was the highest among those three parts and HAZ area were also acted as cathode without any case of heat treatment. Potential difference between each three parts by PWHT was also smaller compared to NPWHT. Therefore it is suggested that Corrosion resistance property is increased by PWHT. However both Al anode generating current and anode weight loss was also decreased by PWHT compared to NPWHT when SS400 steel is cathodically protected by Al anode.

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Effect of Solution-treated on Electrochemical Properties of AZ91 Magnesium Alloy Anode

  • Zhiquan, Huang;Yanjie, Pei;Renyao, Huang;Xiangyu, Gao;Jinchao, Zou;Lianyun, Jiang
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.486-496
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    • 2022
  • The effect of solution-treated on the self-corrosion performance and discharge performance of AZ91 magnesium alloy as anode material was analyzed by microscopic characterization, immersion tests, electrochemical measurements, and discharge performance tests. The study shows that the β-phase in the AZ91 magnesium alloy gradually dissolved in the matrix with the increase of the solution temperature, and the electrochemical activity of the magnesium alloy anode was significantly improved. Through the comparison of three different solution-treated processes, it is found that the AZ91 magnesium alloy has the most vigorous activity and better discharge performance after solution-treated of 415℃+12 h. In addition, the proportion and distribution of β-phase AZ91 magnesium alloy have a direct impact on its discharge performance as an anode material.

The Effect of the Anode Thickness on Electrolyte Supported SOFCs

  • So Yeon Shin;Dae-Kwang Lim;Taehee Lee;Sang-Yun Jeon
    • Journal of Electrochemical Science and Technology
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    • v.14 no.2
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    • pp.145-151
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    • 2023
  • Planer-type electrolyte substrates are often utilized for stack manufacturing of electrolyte-supported solid oxide fuel cells (ES-SOFCs) to fulfill necessary requirements such as a high mechanical strength and redox stability. This work did an electrochemical analysis of ES-SOFC with different NiO-YSZ anode thicknesses to find the optimal value for the high performance of the fuel cell. The cell resistivities were constant at anode thickness between 25-58 ㎛, but a thick anode (74 ㎛) caused a high electrode resistivity leading to a dramatic reduction in cell performance. A stability test was performed for 50 hours at 700℃, and the results showed a degradation rate of 0.3% per 1000 h by extrapolated fitting.