• Title/Summary/Keyword: Anhydrides

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Acylation of Wool Keratin with Dibasic Acid Anhydrides - on reaction mechanism - (2염기산 무수물에 의한 양모섬유의 아실화(I) - 반응메카니즘을 중심으로 -)

  • 신은주;박찬헌;최석철
    • Textile Coloration and Finishing
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    • v.7 no.1
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    • pp.65-71
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    • 1995
  • Wool yarns were treated in dimethylformamide solutions containing various concentrations of three dibasic acid anhydrides : succinic, itaconic, and phthalic anhydrides in various conditions. The structural aspects of these dibasic acid anhydrides are different : the succinic, itaconic, and phthalic acid anhydrides have saturated aliphatic etylene, unsaturated aliphatic vinyl and aromatic phenyl groups, respectively. The reaction mechanism of the acylation of wool keratin and some resction conditions were invastigated. And the results are as follows. 1. The N-acylation and formation of free carboxyl group were dominant rather than the O-acylation cross-linked on the side chain of polypeptide. The acylation of wool keratin is easier than that of silk fibroin. 2. The higher molecular weight, steric hinderance and resonance caused lower acylating reactivity. By the determination of acyl contents for acylated keratin, it was rerealed that the degree of acylation was succinic acid anhydride > itaconic acid anhhydride > phthalic acid anhydride.

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An Efficient Synthesis of Alkoxyallylthiopyridazine Derivatives from Maleic Anhydrides (Maleic Anhydrides로부터 Alkoxyallylthiopyridazines 유도체의 효과적 합성)

  • Lee, Jae-In;Yun, Young-Sook
    • Journal of the Korean Chemical Society
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    • v.48 no.6
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    • pp.609-615
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    • 2004
  • Alkoxyallylthiopyridazine derivatives which exhibit superior effect for the treatment of hepatic diseases were synthesized from maleic anhydrides. The reaction of maleic anhydrides with hydrazine monohydrate in aq HCl at reflux afforded dihydroxypyridazines, which were transformed to dichloropyridazines with phosphorus oxychloride. The substitution of the first chlorine atom in dichloropyridazines proceeded selectively with alcoholic sodium alkoxides in THF to afford alkoxychloropyridazines, which were converted to alkoxyallylthiopyridazines with lithium 2-propene-1-thiolate in high yields.

A Facile Reduction of Acid Anhydrides with Borane in the Presence of Lithium Chloride in Tetrahydrofuran

  • Yoon, Nung-Min;Lee, Whee-Seong
    • Bulletin of the Korean Chemical Society
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    • v.7 no.4
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    • pp.296-298
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    • 1986
  • Carboxylic acid anhydrides are rapidly reduced with borane-lithium chloride (1:0.1) system to give corresponding alcohols (diols in the case of cyclic anhydride) quantitatively in tetrahydrofuran at room temperature. This reagent tolerates aromatic acid ester, nitro, and halide functional groups, however competitively reduces aliphatic ester and nitrile groups.

Photochemical Ring-Opening of Acid Anhydrides by $TiO_2$ Photocatalyst in Methanol

  • Kim, Sung-Sik;Mah, Yoon-Jung;Lee, Hye-Jong;Park, Sang-Kyu
    • Journal of Photoscience
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    • v.10 no.3
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    • pp.241-243
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    • 2003
  • Photoreactions of some carbonyl compounds with TiO$_2$ were investigated in methanol. Although 1,3-cyclohexanedione and phthalimide afforded 3-methoxy-2-cyclohexen-l-one and 3-methoxy-1-isoindolinone, respectively, acid anhydrides such as succinic, phthalic, and maleic anhydrides gave the monoesters of dicarboxylic acids in good to excellent yields, when they were irradiated on TiO$_2$ in methanol with 300 nm UV light.

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Montmorillonite KSF Clay as Novel and Recyclable Heterogeneous Catalyst for the Microwave Mediated Synthesis of Indan-1,3-Diones

  • Marvi, Omid;Giahi, Masoud
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2918-2920
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    • 2009
  • Various indan-1,3-dione derivatives were synthesized from the reaction of different phthalic anhydrides with diethylmalonate using montmorillonite KSF clay as a recyclable heterogeneous acidic catalyst and microwave irradiation in good yields and short reaction times.

Cycloaddition of Homophthalic Anhydrides to Azodicarboxylate and Alkylidenecarbamates (호모프탈산 무수물과 아조디카르복시산 에스테르 및 알킬리덴카르밤산 에스테르와의 고리화첨가반응)

  • Youn Young Lee;Ho Hyeon Kim;Yang Mo Goo
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.243-247
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    • 1986
  • The cycloaddition between homophthalic anhydrides (1 or 2) and diethyl azodicarboxylate and ethyl arylmetbyldenecarbamates was investigated. The former led to 2,3-diethoxycarbonyl-2,3-dihydro-1-hydroxyphthalazines (3 and 4), while the latter gave 3-aryl-4-carboxy-2-ethoxycarbonyl-3,4-dihydro-1(2H) isoquinolinones (5∼10).

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