• Journal of the Korean Wood Science and Technology
• /
• v.35 no.5
• /
• pp.16-23
• /
• 2007

This study was performed as part of a research project aimed at developing an ultrasonic computed tomography (CT) system of wood for field application. In this reports, we investigate the variation of wave velocities on the cross section of real size wooden structural member to confirm the reason of image distortion on CT image of wood, and then proposed a new image reconstruction method by considering the velocity variation on wood cross section. First of all, the effect of wood anisotropy on ultrasonic velocities of wooden members was investigated. Based on the relationship between ultrasonic velocity and annual ring angle, which was obtained from test results of small clear specimens, ultrasonic velocities of each measuring angle were predicted. Next, they were compared with the ultrasonic velocities measured on five wood disks. There were very large differences between predicted and measured results, thought to be caused by the skewing effect of ultrasound and the presence of juvenile-wood. Based on these findings, a new method was proposed to reconstruct cross-sectional image of wood. By using this method, some distortions on reconstructed images could be removed, and defects were more easily and clearly detected. The minimum size of detectable defect was decreased remarkably, from 33 mm to 13 mm. However, the size of the detected defect was enlarged and the position somewhat shifted to the specimen surface on the CT images, which was also thought to be caused by the skewing effect of ultrasound. Additional research has been planned to solve these problems.

• Korean Journal of Crystallography
• /
• v.15 no.1
• /
• pp.1-4
• /
• 2004

The title compound, $C_{18}H_{20}O_5S$, crystallized in the centrosymmetric space group $P\={1}$ with one molecule in an asymmetric unit. The S atom in the sulfonate group retains the overall tetrahedral environment of the O and C atoms with an average S-O bond of 1.420(2) ${\AA}$ for double bond and of 1.598(2) ${\AA}$ for single bond and S-C length of 1.742(3) ${\AA}$. The torsion angle C(7)-S-O(3)-C(8) is 100.3(2)$^{\circ}$ and the dihedral angle of the two planar six-membered rings is 42.73(20)$^{\circ}$.

• Journal of Gastric Cancer
• /
• v.12 no.1
• /
• pp.43-45
• /
• 2012

Mesenteric pseudocyst is rare. This term is used to describe the abdominal cystic mass, without the origin of abdominal organ. We presented a case of mesenteric pseudocyst of the small bowel in a 70-year-old man. Esophago-gastro-duodenoscopy showed a 3.5 cm sized excavated lesion on the posterior wall of angle. Endocopic biopsy confirmed a histologic diagnosis of the poorly differentiated adenocarcinoma, which includes the signet ring cell component. Abdominal computed tomography scan showed a focal mucosal enhancement in the posterior wall of angle of the stomach, a 2.4 cm sized enhancing mass on the distal small bowel loop, without distant metastases or ascites in rectal shelf, and multiple gallbladder stones. The patient underwent subtotal gastrectomy with gastroduodenostomy, segmental resection of the small bowel, and cholecystectomy. The final pathological diagnosis was mesenteric pseudocyst. This is the first case report describing incidentally detected mesenteric pseudocyst of the small bowel in gastric cancer patients.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.12
• /
• pp.4161-4164
• /
• 2012

Density functional MO calculations for the methylsilole anion of $[C_4H_4SiMe]^-$ and methylgermole anion of $[C_4H_4SiMe]^-$ at the B3LYP (full)/6-311+$G^*$ level (GAUSSIAN 94) were carried out and characterized by frequency analysis. The ground state structure for the methylsilole anion and methylgermole anion is that the methyl group is pyramidalized with highly localized structure. The difference between the calculated $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are 9.4 and 11.5 pm, respectively. The E-Me vector forms an angle of $67.9^{\circ}$ and $78.2^{\circ}$ with the $C_4E$ plane, respectively. The optimized structures of the saddle point state for the methylsilole anion and methylgermole anion have been also found as a planar with highly delocalized structure. The optimized $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are nearly equal for both cases. The methyl group is located in the plane of $C_4E$ ring and the angle between the E-Me vector and the $C_4E$ plane for the methylsilole anion and methylgermole anion is $2.0^{\circ}$ and $2.3^{\circ}$, respectively. The energy difference between the ground state structure and the transition state structure is only 5.1 kcal $mol^{-1}$ for the methylsilole anion. However, the energy difference of the methylgermole anion is 14.9 kcal $mol^{-1}$, which is much higher than that for the corresponding methylsilole monoanion by 9.8 kcal $mol^{-1}$. Based on MO calculations, we suggest that the head-to-tail dimer compound, 4, result from [2+2] cycloaddition of silicon-carbon double bond character in the highly delocalized transition state of 1. However, the inversion barrier for the methylgermole anion is too high to dimerize.

• Polymer(Korea)
• /
• v.37 no.6
• /
• pp.777-783
• /
• 2013

We used dipodal type bis[3-(trimethoxysilyl)propyl]amine (BTMA) silane coupling agent to modify silica nanoparticles to introduce secondary amino groups on the silica surface. These grafted N-H groups were reacted with glycidyl methacrylate (GMA) to introduce polymerizable methacrylate groups on the silica surface. After modification reaction, we used several analytical techniques such as Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA) and solid state $^{13}C$ cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy (NMR) to analyze the effects of reaction time, reaction temperature and used GMA concentration on the modification degree between N-H groups on the silica surface and epoxide groups of GMA. We found increased introduction of methacrylate groups on the silica surface by ring opening reaction of epoxide groups of GMA with N-H groups on BTMA treated silica with increased reaction time, reaction temperature and used GMA concentration within our experimental conditions.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.4
• /
• pp.395-400
• /
• 2001

The effects of ortho- (R = H and CH3) and Y-substituents (Y = OCH3, CH3H and CN), which are directly attached to the carbonyl carbon, on the protonation equilibria of the para-X-substituted benzoyl derivatives, 4-X -2, 6-di-R-C6H2-C(=O)-Y, are investigated theoretically using the B3LYP method with 6-31+G* basis set. Structurally, both of the (B) and (BH+ ) forms in the species with R = H are nearly coplanar regardless of the Y-substituents implying that the steric repulsion between Y-substituent and R = H is relatively small. In the species with R = CH3 , the tortional angle (Θ) between the carbonyl moiety and aryl ring varies from zero to near right angle depending on the degree of steric repulsion between Y and R = CH3 and the resonance demand. However the reaction energies, ΔG°, for the protonation processes are more favorable for R = CH3 than for R = H due to stronger electron donating effect of R = CH3 , although the species with R = CH3 are unfavorable sterically. On the other hand, the Hammett type plots are progressively better correlated with б+ than with б values on going from Y = OCH3 to Y = CN for both species with R = H and CH3 indicating that the degree of resonance delocalization between carbonyl moiety and X-substituent is increased for a more electron accepting Y-substituent. Nevertheless the effects of R = CH3 on the magnitude of Hammett type reaction constants ( б or б+ ) are not much different from those of R = H.

• Journal of Industrial Technology
• /
• v.28 no.A
• /
• pp.3-10
• /
• 2008

This paper is to investigate the characteristics of debris flow landslides in Gangwon Province through literature review, data collection and analyses and site investigation. As results of data analyses about landslides occurred currently in this province, the landslide in the form of debris flow is found to be 55 %. Therefore major loss and costs are caused by discharge of soil and rock fragments from landslide. From results of analyzing the geometrical characteristics of landslide, length of most of landslide is less than 200 m, their width is in the range of 10 - 40 m, most of them are know to be occurred in lower elevation than 400 m. Slope angle is in the range of 25 - 35 degrees. Comparing the period of rainfall intensity with the time of landslide being occurred, occurrence of landslide is quite related to duration of a heavy rainfall. For measures of controlling water flow discharge and debris flow, considering geological and topographical ground conditions, appropriate selection and building check dam, erosion control dam and ring net is very beneficial for reducing the loss and costs caused by the landslide of debris flow.

• The Journal of the Acoustical Society of Korea
• /
• v.34 no.5
• /
• pp.351-359
• /
• 2015

Typical underwater acoustic transducers detect only the magnitude of an acoustic pressure and they have the limitation of not being able to recognize the direction of the sound signal. Hence, the authors of this paper proposed a new vector sensor structure based on Tonpilz transducers that could detect both the magnitude and the direction of a sound pressure. In the proposed structure, the piezoceramic ring was divided into four segments, and proper combination of the output voltages of the segments in response to the external sound pressure could provide the information on the orientation of the sound source. In this paper, a Tonpilz transducer has been fabricated to have the proposed structure and its characteristics has been measured to confirm the validity of the proposed structure.

• Proceedings of the KSME Conference
• /
• 2001.06e
• /
• pp.690-695
• /
• 2001

The three-dimensional spatial structures of impeller flow created by a six bladed Rushton turbine have identified based on the volumetric velocity information from multi-plane stereoscopic PIV measurements. A total of 10 planes with 2 mm space with a 50 mm by 64 mm size of the field of view were targeted. To reduce the depth of focus, we adopted an angle offset configuration which satisfied the Scheimpflug condition. The distortion compensation procedure was utilized during the in situ calibration. Phase-locked instantaneous data were ensemble averaged and interpolated in order to obtain mean 3-D, volumetric velocity fields on a 60 degree sector of a cylindrical ring volume enclosing the turbine blade. Using the equi-vorticity surface rendering, the spatial structure of the trailing vortices was clearly demonstrated. Detail flow characteristics of the radial jet reported in previous studies of mixer flows were easily identified.

• Journal of the Korean Wood Science and Technology
• /
• v.9 no.1
• /
• pp.1-12
• /
• 1981

The structure of spiral thickenings, particulary the appearance, arrangement and orientation of thickenings in compression wood of Torreya nucifera, were studied in detail by light and polarizing microscope, scanning and transmission electron microscope. The results obtained are as follows: (1) Using the inclined sections at an angle of 45 degrees to the fiber axis, it seems that we can not only observe the more accurate transverse view of the thickenings but also investigate the formation of their thickenings. (2) Generally 2-4 pieces of thickenings are projected to the cell lumen as nipple-like appearance in transverse section and are as frequent, well developed, forming pair and have the rope-like appearance in radial surface. (3) The secondary wall of early wood is composed of 3 layers (S1, S2, S3) and orientation of thickening appears S helix but that of late wood is of 2 layers (S1, S2) and that orientation shows Z helix. Above two regions are demaracted at several tracheid cells from the growth ring boundary. (4) Orientation of thickening seems to be a element showing the characteristics of compression wood in Torreya nucifera. (5) It believes that the thickenings of compression wood are integral part of the S3 in early wood tracheids and of the S2 in late wood and have the same orientations as the inner-most microfibrils in these layers. (6) Thickening and cavities seem to be not formed together in a secondary cell wall of same tracheids.