• Bulletin of the Korean Chemical Society
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• v.6 no.4
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• pp.202-206
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• 1985

The crystal structure of The crystal structure of $Ag^+$-Exchanged Zeolite A, $Ag_{4.6}Na_{7.4}-A$, dehydrated, treated with $H_2$, and evacuated, all at $350^{\circ}C$, has been determined by single crystal x-ray diffraction methods in the cubic space group Pm3m at $24(1)^{\circ}C;$ a = $12.208(2)\AA.$ The structure was refined to the final error indices R1 = 0.088 and R2 (weighted) = 0.069 using 194 independent reflections for which II_0$ > $3{\sigma}(I_0)$. On threefold axes near the centers of 6-oxygen rings, $7.4 Na^+$ ions and $0.6 Ag^+$ ions are found. Two non-equivalent 8-ring $Ag^+$ ions are found off the 8-ring planes, each containing about $0.6 Ag^+$ ions. Three non-equivalent Ag atom positions are found in the large cavity, each containing about 0.6 Ag atoms. This crystallographic analysis may be interpreted to indicate that $0.6 (Ag_6)^{3+}$ clusters are present in each large cavity. This cluster may be viewed as a nearly linear trisilver molecule $(Ag_3)^0$ (bond lengths, 2.92 and 2.94 $\AA;$ angle, $153^{\circ})$ stabilized by the coordination of each atom to a Ag^+$ ion at 3.30, 3.33, and 3.43 $\AA$, respectively. In addition, one of the silver atoms approaches all of the 0(1) oxygens of a 4-ring at $2.76\AA.$ Altogether $7.4 Na^+$ ions, $1.8 Ag^+$ ions, and 1.8 Ag atoms are located per unit cell. The remaining $1.0 Ag^+$ ion has been reduced and has migrated out of the zeolite framework to form silver crystallites on the surface of the zeolite single crystal.

• Journal of the Korean Geotechnical Society
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• v.29 no.5
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• pp.39-52
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• 2013

The shear stress characteristics of landslide materials can be affected by various factors. We examined the shear stress characteristics of two different soils using ring-shear apparatus, in which saturation-consolidation-shearing speed can be easily controlled. This paper presents (i) shear stress-time characteristics, (ii) shear stress depending on normal stress and shear speed and (iii) shear stress as a function of shearing speed. Materials used in this paper were the Nakdong River sand and muds taken from Jinhae coastal area in Korea. Samples were prepared in three types: Sand (upper)-Sand (lower), Clay (upper)-Clay (lower) and Sand (upper)-Clay (lower). The upper and lower indicate the samples placed in upper and lower ring shear boxes, respectively. For given normal stresses (50 and 100 kPa) and shearing speed (0.1 mm/sec), we performed ring shear tests. Then the failure lines were determined in the second test. Last, we determined the shear stress characteristics depending on different shearing speeds, such as 0.01, 0.1, 1, 10, 100 mm/sec. As a result, we found that shear stress characteristics are strongly dependent on above three factors. The shear stress of Sand (upper)-Clay (lower) is smaller than that of Sand (upper)-Sand (lower), but slightly larger than that of Clay (upper)-Clay (lower). The shear stress is also characterized by grain crushing and wetting process at slip surface.

• Journal of the Korean earth science society
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• v.32 no.6
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• pp.548-559
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• 2011

3-D Multi-geophysical surveys were carried out around the Hwasan caldera at the Euisung Sub-basin. To overcome the limitations of resolutions in previous studies, dense gravity data and magnetotelluric (MT) data were obtained and analyzed. In this study, the independent inversion models from gravity and MT data were integrated using correlation and classification approaches for 3-D imaging of the geologic structures. A Structure Index (SI) method was proposed and applied to the integration and classification analyses. This method consists of Type Angle (TA) and Type Intensity (TI) values, which are estimated by the spatial correlation and abnormality of the physical properties. The SI method allowed the classification analysis to be effectively performed. Major findings are as follows: 1) pyroclastic rocks around the central area of the Hwasan caldera with lower density and resistivity than those of neighboring regions extended to a depth of around 1 km, 2) intrusive igneous rocks with high resistivity and density were imaged around the ring fault boundary, and 3) a basement structure with low resistivity and high density, at a depth of 3-5 km, was inferred by the SI analysis.

• Journal of Korean Society of Forest Science
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• v.109 no.1
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• pp.62-71
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• 2020

With the aim of restoring slow-moving landslide areas, this study collected fundamental data from tree-ring analysis of curved trees in these areas. We collected both upper and lower stem disks to measure the azimuth angles of six trees with growth curvature caused by tension cracks. Additionally, we analyzed various factors in the slow moving landslide area. The geological strata and main constitutive rocks in the study area were anorthosite-formed in the Precambrian period; moreover, there were no intrusive rocks, other geological strata, geological folds, or faults. The talus with weathered rocks was distributed in the upper zone of the slow-moving landslide area. According to annual-ring analysis of curved trees and terrain analysis by satellite imagery, slow-moving landslide occurred from the top to the bottom end of the slope between 1999 and 2011. There was a significant relationship (P < 0.01) between the azimuth angle of cracks caused by the slow-moving landslide and the angle of the curved trees. These results suggest that the occurrence of slow-moving landslides could be confirmed through analysis of annual-rings of curved trees, underground water levels, and terrain (by satellite imagery).

• Journal of the Korean Chemical Society
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• v.18 no.5
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• pp.329-340
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• 1974

Sulfadiazine, $C_{10}H_{10}N_4O_2S$, forms monoclinic crystals of space group $P21}c$ from a mixture of acetone and ethanol with $a=13.71{\pm}0.04,\;b=5.84{\pm}0.03,\;c=15.11{\pm}0.05{\AA},\;{\beta}=115.0{\pm}0.3^{\circ}$, and four molecules per cell. Three dimensional photographic data were collected with $CuK\alpha$ radiation. The structure was determined using Patterson and Fourier synthesis methods and refined by block diagonal least-squares methods with isotropic thermal parameter for all non-hydrogen atoms. The final R value was 0.15 for the 1517 observed independent reflections. The dihedral angle between the planes through the benzene ring and the pyrimidine ring is $76^{\circ}$. The conformational angle formed by the projection of the S-C(5) bond with that of N(1)-C(1) where the projection is taken along the S-N(1) bond is $77^{\circ}$. The imino nitrogen atom, N(1), and pyrimidine nitrogen atom, N(3), form intermolecular $N-H{\cdots}N$ hydrogen bond between the molecules related by center of symmetry. Amino nitrogen atom, N(4), forms two intermolecular $N-H{\cdots}O$ hydrogen bonds, with O(1) and O(2) atoms of different molecules separated by b. A two dimensional network of hydrogen bonds form infinite molecular sheets parallel to the (100) plane. Adjacent sheets are bound together by van der Waals forces.

• Journal of Plant Biology
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• v.31 no.3
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• pp.169-185
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• 1988

Vessel elements in lateral root, tap root, transition region, stem and mid vein of 1-year old, 3-year old and 5-year old ginseng (Panax ginseng C.A. Meyer) are studied with light microscope to clarify the distribution and differentiation of several kinds of vessel elements. Vessel elements are classified into five types such as ring vessel, spiral vessel, scalariform vessel, reticulate vessel and pitted vessel according to the secondary thickenings of cell wall. All of the five types are not observed in each organ, but diverse kinds of vessels are present in stem and mid vein compared with the underground organs such as tap root and lateral root. The length of vessel elements is longest (680$\mu$m) in stem and shortest (143$\mu$m) in tap root. The diameter of vessel elements is 19.0$\mu$m in tap root and the angle of perforation plate comes under 22$^{\circ}$-60$^{\circ}$. The degree of differentiation of vessel elements according to the length, diameter and angle of perforation plate of vessel elements is highest in tap root regardless of the age of ginseng. Three types of perforation plate such as scalariform, intermediate type of simple and scalariform, and simple perforation plate are observed. The vascular tracheids are characteristically observed in mid vein of 1-year old ginseng, and in transition region of 3 and 5-year old ginseng.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.24 no.4
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• pp.448-454
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• 2015

In this paper, the band structural design that is typically in a line was arranged in a ring shape, so as to configure the high power LED lighting in such a way as to form a concentrated light distribution angle of less than 15 degrees. The parabolic aluminized reflector PAR38 that facilitates design using area and the area of the optical system to the same extent, applied a multiple light-source condenser lens optical system for the control of integration. The LED used here implemented a single linear light source using ans LED module with ans LED, flip-chip chip-scale package. The optical system was designed based on the energy star standard.

• Journal of Mechanical Science and Technology
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• v.17 no.2
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• pp.181-186
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• 2003

In order to assure the quality of the bent axis design axial piston pumps driven by tapered pistons, it is necessary to know the characteristics of force applied to tapered pistons and the mechanism for driving the tapered pistons. Since they are able to perform both reciprocating and spinning motions in cylinder block, it is difficult to understand the driving mechanismand-tomeasure the forces applied to tapered pistons experimentally In the present study, the theoretical mechanism for driving the tapered pistons is studied by use of the geometric method. The driving area of the tapered pistons is measured by measuring the strain of a cylinder forced against a tapered piston using an electric strain gauge and a slip ring. The forces applied to tapered pistons is also investigated with the change of discharge pressure and the rotational speed. As a results of this investigation, it is concluded that the cylinder block is driven by one tapered piston in a limited area and the driving area is changed due to space angle of the tapered pistons and the swivel angle of the cylinder block. It is also observed that the force applied to tapered pistons increases as the discharge pressure and the rotational speed increase.

• Structural Engineering and Mechanics
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• v.75 no.1
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• pp.123-131
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• 2020

The bond performance of glass fibre reinforced polymer (GFRP) bars and that of steel bars embedded in Alkali Activated Cement (AAC) concrete are analysed and compared using pull-out specimens. The bond failure modes, the average bond strength and the free end bond stress-slip curves are used for comparison. Tepfers' concrete ring model is used to further analyse the splitting failure in ribbed steel bar and GFRP bar specimens. The angle the bond forces make with the bar axis was calculated and used for comparing bond behaviour of ribbed steel bar and GFRP bars in AAC concrete. The results showed that bond failure mode plays a significant role in the comparison of the average bond stress of the specimens at failure. In case of pull-out failure mode, specimens with ribbed steel bars showed a higher bond strength while specimens with GFRP bars showed a higher bond stress in case of splitting failure mode. Comparison of the bond stress-slip curves of ribbed steel bars and GFRP bars depicted that the constant bond stress region at the peak is much smaller in case of GFRP bars than ribbed steel bars indicating a basic bond mechanism difference in GFRP and ribbed steel bars.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.136-145
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• 2009

Factors influencing shear behavior of granular material include particle size, shape, distribution, relative density, particle crushing, etc. In this study, these factors are characterized by viewpoint of shear behavior using numerical analysis based on DEM. Geometrical particle shape is represented by a combination of small circular particles and influence of particle shape on crushing is studied through relative comparisons between clump (uncrushable) and cluster (crushable) models which are modeled using DEM. Also, particle shape is quantified by the dimensionless parameters such as circularity and convexity. The results indicate that particle shape indexes have a negative association with internal friction angle. Also, internal friction angle becomes reduced and failure envelop curve becomes nonlinear due to the particle crushing. It is also found that numerical results are quite good agreement with the experimental test conducted in this study.