• Tribology and Lubricants
• /
• v.23 no.3
• /
• pp.130-133
• /
• 2007

Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.

• Tribology and Lubricants
• /
• v.24 no.3
• /
• pp.129-132
• /
• 2008

Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.27 no.3
• /
• pp.432-439
• /
• 2003

Inconel 690 for nuclear steam generator tube has more Chromium than the conventionally used Inconel 600 in order to increase the corrosion resistance. To evaluate the tribological characteristics of Inconel 690 under fretting condition the fretting tests were carried out in air and elevated temperature water. Fretting tests of the cross-cylinder type were done under various vibrating amplitudes and applied normal loads in order to measure the friction forces and wear volumes. From the results of fretting wear tests. the wear of Inconel 690 can be predictable using the work rate model. The amounts of friction forces were proportional to relative movement between two fretting surfaces. The friction coefficients were decreased as increasing the normal loads and deceasing the vibrating amplitudes. Depending on fretting environment, distinctively different wear mechanisms and often drastically different wear rates can occur It was found that the fretting wearfactors in air and water at 2$0^{\circ}C$, 5$0^{\circ}C$, and 8$0^{\circ}C$ were 7.38 $\times$ $10^{-13}$$Pa^{-1}$, 2.12 $\times$$10^{-13}$$Pa^{-1}$, 3.34$\times$$10^{-13}$$Pa^{-1}$and 5.21$\times$$10^{-13}$$Pa^{-1}$, respectively flexibility to model response data with multiple local extreme. In this study, metamodeling techniques are adopted to carry out the shape optimization of a funnel of Cathode Ray Tube, which finds the shape minimizing the local maximum principal stress. Optimum designs using two metamodels are compared and proper metamodel is recommended based on this research.

• Journal of the Korean GEO-environmental Society
• /
• v.11 no.1
• /
• pp.53-59
• /
• 2010

In seawater deposition condition, the corrosion and chemical attack of grouts are similar to those of concrete structure. Used in domestic MSG (Micro Silica Grouting) mixtured large amounts of silicate materials containing as cement powder is $8,000cm^2/g$ of the specific surface area or more due to the high hydration activity and high-strength, high durability, and features, $C_3A$ content of less than 5% to meet the standards chemical attack of seawater was evaluated as a cement material. Therefore, in this paper, with excellent seawater attack resistant MSG in combination with rapid hardening mineral was used, those of seawater characteristics were evaluated experimentally. Typically, sodium-silicate minerals or rapid hardening cements are used in domestic. About the homogel specimens with combination of MSG and rapid hardening agents for compressive strength, weight and length change characteristics were evaluated experimentally, and so we could present the excellent seawater resistant grouts combination.

• Journal of Korea Foresty Energy
• /
• v.21 no.3
• /
• pp.18-27
• /
• 2002

Pine bark was liquefied in the presence of phenol using organic sulfonic acids as catalysts, and the liquefied barks were characterized. It was found that the organic sulfonic acids were more effective catalysts than hydrochloric acid for complete liquefaction of pine bark. The liquefied barks prepared from phenol-organic sulfonic acid liquefaction were highly phenolated, and the amounts of combined phenol were 2-3 times greater than that of the liquefied bark obtained from phenol-hydrochloric acid liquefaction. The glass transition points (Tg) were lower than that of the liquefied barks prepared from phenol-hydrochloric acid. It can be concluded that by using the organic sulfonic acids, the phenol used as a liquefying reagent is highly introduced into the bark, resulting in the phenolated bark preventing further condensation reactions, which may occur during the liquefaction. The carbohydrates such as cellulose and hemicellulose in the liquefied barks were almost decomposed during the liquefaction, from the results of IR spectra and neutral sugar analyses. Energy dispersive X-ray spectromery (EDS) results from the residues and the liquefied barks showed that the organic sulfonic acid catalysts did not lead to serious corrosion of the reactor compared with the hydrochloric acid catalyst.

• Journal of the Korea Concrete Institute
• /
• v.15 no.6
• /
• pp.829-839
• /
• 2003

Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation but the future studies for combined environment will assure the precise assessment.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.12
• /
• pp.3748-3754
• /
• 2009

An integral head loss test in a test apparatus was conducted to simulate chemical effects on a head loss across a strainer in a pressurized water reactor (PWR) containment water pool after a loss of coolant accident (LOCA). The test was conducted during 30 days in the condition of a short spray, a long spray, and no materials with chemical effects. The result exhibited that the head loss was affected on amounts of the exposed materials according to spray conditions. XRD analysis of the collected precipitates showed that the precipitates were phosphate compounds. Comparison of the head loss with dissolved species concentration showed that high increase rate of the head loss resulted from the corrosion of aluminum and zinc but slow increase rate of the head loss resulted from the precipitates induced by Si, Mg, and Ca from leaching reaction at NUKON and concrete after passivation of metal specimens.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.25 no.2
• /
• pp.42-53
• /
• 2020

In this study, heavy metal in road-deposited sediments (RDS) and marine sediment around Gwangyang Bay area have been investigated to assess the pollution status of metals and to understand the environmental impact of RDS as a potential source of metal pollution. Zn concentration for <63 ㎛ size fraction was the highest (2,982 mg/kg), followed by Cr, Ni, Pb, Cu, As, Cd, and Hg. Metal concentrations in RDS increased with decreasing particle size and relatively higher concentrations were observed around the metal waste and recycling facilities. For particle size in RDS smaller than 125 ㎛, EF values indicated that Zn was very high enrichment and Cr, Cd, Pb were significant enrichment. The concentrations of metals in marine sediments were mostly below the TEL value of sediment quality guidelines of Korea. However, the Zn concentrations has increased by 30~40% compared to 2010 year. The amounts of Zn, Cd and Pb in less than 125 ㎛ fraction where heavy metals can be easily transported by stormwater runoff accounted for 54% of the total RDS. The study area was greatly affected by Zn pollution due to corrosion of Zn plating materials by traffic activity as well as artificial activities related to the container logistics at Gwangyang container terminal. The fine particles of RDS are not only easily resuspended by wind and vehicle movement, but are also transported to the surrounding environments by runoff. Therefore, further research is needed on the adverse effects on the environment and ecosystem.

• Journal of the Society of Disaster Information
• /
• v.9 no.4
• /
• pp.449-461
• /
• 2013

As the hydrofluoric acid leak in Gumi-si, Gyeongsangbuk-do or hydrochloric acid leak in Ulsan, Gyeongsangnam-do demonstrated, chemical related accidents are mostly caused by large amounts of volatile toxic substances leaking due to the damages of storage tank or pipe lines of transporter. Safety assessment is the most important concern because such toxic material accidents cause human and material damages to the environment and atmosphere of the surrounding area. Therefore, in this study, a hydrofluoric acid leaked from a storage tank was selected as the study example to simulate the leaked substance diffusing into the atmosphere and result analysis was performed through the numerical Analysis and diffusion simulation of ALOHA(Areal Location of Hazardous Atmospheres). the results of a qualitative evaluation of HAZOP (Hazard Operability)was looked at to find that the flange leak, operation delay due to leakage of the valve and the hose, and toxic gas leak were danger factors. Possibility of fire from temperature, pressure and corrosion, nitrogen supply overpressure and toxic leak from internal corrosion of tank or pipe joints were also found to be high. ALOHA resulting effects were a little different depending on the input data of Dense Gas Model, however, the wind direction and speed, rather than atmospheric stability, played bigger role. Higher wind speed affected the diffusion of contaminant. In term of the diffusion concentration, both liquid and gas leaks resulted in almost the same $LC_{50}$ and ALOHA AEGL-3(Acute Exposure Guidline Level) values. Each scenarios showed almost identical results in ALOHA model. Therefore, a buffer distance of toxic gas can be determined by comparing the numerical analysis and the diffusion concentration to the IDLH(Immediately Dangerous to Life and Health). Such study will help perform the risk assessment of toxic leak more efficiently and be utilized in establishing community emergency response system properly.

• Journal of the Mineralogical Society of Korea
• /
• v.26 no.2
• /
• pp.101-110
• /
• 2013

Due to the large specific surface area and great reactivity toward environmental contaminants, nanocrystalline mackinawite (FeS) has been widely applied for the remediation of contaminated groundwater and soil. Furthermore, nanocrystalline FeS is rather thermodynamically stable against anoxic corrosion, and its reactivity can be regenerated continuously by the activity of sulfate-reducing bacteria. However, nanocrystalline mackinawite is prone to either spread out along the groundwater flow or cause pore clogging in aquifers by particle aggregation. Accordingly, this mineral should be modified for the application of permeable reactive barriers (PRBs). In this study, coating methods were investigated by which mackinawite nanoparticles were deposited on the surface of alumina or activated alumina. The amount of FeS coating was found to significantly vary with pH, with the highest amount occurring at pH ~6.9 for both minerals. At this pH, the surfaces of mackinawite and alumina (or activated alumina) were oppositely charged, with the resultant electrostatic attraction making the coating highly effective. At this pH, the coating amounts by alumina and activated alumina were 0.038 and 0.114 $mmol{\cdot}FeS/g$, respectively. Under anoxic conditions, arsenite sorption experiments were conducted with uncoated alumina, uncoated activated alumina, and both minerals coated with FeS at the optimal pH for comparison of their reactivity. Uncoated activated alumina showed the higher arsenite removal compared to uncoated alumina. Notably, the arsenite sorption capacity of activated alumina was little changed by the coating with FeS. This might be attributed to the abundance of highly reactive hydroxyl functional groups (${\equiv}$AlOH) on the surface of activated alumina, making the arsenite sorption by the coated FeS unnoticeable. In contrast, the arsenite sorption capacity of alumina was found to increase substantially by the FeS coating. This was due to the consumption of the surface hydroxyl functional groups on the alumina surface and the subsequent occurrence of As(III) sorption by the coated FeS. Alumina, on the surface area basis, has about 8 times higher FeS coating amount and higher As(III) sorption capacity than silica. This study indicates that alumina is a better candidate than silica for the coating of nanocrystalline mackinawite.