• Title/Summary/Keyword: Ammonia-water

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Modeling of Ammonia Mass Transfer Using a Hollow Fiber Membrane Contactor (중공사막 접촉기를 이용한 암모니아 물질전달 모델링)

  • Oh, Dae-Yang;Jeong, Joo-Young;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.503-510
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    • 2011
  • Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

Effects of ammonia water on sporulation of coccidial oocysts originated from bovine (암모니아수(水) 처리가 소콕시디아 오시스트 포자형성(胞子形成)에 미치는 영향(影響))

  • Wee, Sung-hwan;Kang, Yung-bai;Jang, Hwan;Lee, Hee-su;Choi, Sang-ho
    • Korean Journal of Veterinary Research
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    • v.30 no.1
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    • pp.103-106
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    • 1990
  • Effects of ammonia water on the spornlation of coccidial oocysts collected from bovine feces were studied with particular reference to the various levels of ammonia water (1% to 10%) for 30 minute conservation at room temperature. The sporulation rates showed a negative linear coorelation according to the treatment leavels of ammonia water, 85.3% at 1% level to 8.9% at 10% level. The optimum level of ammonia concentration was regarded as 5% to 10% with more than 80% of sporulation inhibition effect.

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Removal of Ammonia Nitrogen and Reduction of THMs in Low Temperature by BAC Pilot Plant (BAC Pilot Plant 를 이용한 겨울철 암모니아성 질소 제거 및 THMs 변화)

  • Kang, Eun-Jo;Seo, Young-Jin;Lee, Won-Kwon;Chun, Pyoung-Hee;Lee, Ji-Hyung;Yoon, Jung-Hyo;Kim, Dong-Youn
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.4
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    • pp.107-114
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    • 1995
  • The raw drinking water quality is getting worse because of the winter drought and the conventional treatment system is'nt suitable to obtain the satisfied quality of water. So, the advanced water system, BAC(Biological Activated Carbon) process is said to be effective to remove dissolved organics and ammonia nitrogen. In our study, the BAC pilot plant using Nak-dong river water is tested in low temperature. Following results are found from the study. The ammonia nitrogen removal rate of BAC system using wood-based carbon (PICABIOL) was 99% in $6^{\circ}C$ temperature. Chlorine dosage in wood-based BAC effluent was reduced to 67% of that in sand filtered wate. It resulted from the removal of ammonia nitrogen. Also, THM formed by chlorine addition in wood-based BAC effluent was decreased to 65% of that in sand filtered water. In the case of dual-filter, the removal efficiency of ammonia nitrogen was increased 30% more than in conventional sand filter. According to this result, the ammonia nitrogen load to BAC system could be lessened by the use of dual-filter.

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Performance Characteristics Analysis of Evaporator in Ammonia-Water Rankine Cycle Based on Exergy and Entransy (암모니아-물 랭킨사이클의 증발기에서의 엑서지 및 엔트랜시 성능 특성 해석)

  • KIM, KYOUNG HOON;JUNG, YOUNG GUAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.621-628
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    • 2019
  • The use of the ammonia-water zeotropic mixture as a working fluid in the power generating system has been considered as a proven technology for efficient recovery of low-grade heat sources. This paper presents a thermodynamic performance analysis for ammonia-water evaporator using low-grade heat source, based on the exergy and entransy which has been recently introduced as a physical quantity to describe the heat transfer ability of an object. In the analysis, effects of the ammonia mass fraction and source temperature of the binary mixture are investigated on the system performance such as heat transfer, effectiveness, exergy destruction, entransy dissipation, and entransy dissipation based thermal resistance. The results show that the ammonia mass concentration and the source temperature have significant effects on the thermodynamic system performance of the ammonia-water evaporator.

Interpretation of Ammonia Absorption Behavior in Water Turbulent Flow (물 난류에서의 암모니아 흡수 거동 해석)

  • Lee, Sang-Ryong;Park, Jin-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.3
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    • pp.75-80
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    • 2019
  • The article is devoted to the interpretation of ammonia, one of the fine dust precursors, absorption behavior in water turbulent flow. The water flow was considered as a turbulent flow with Reynolds number more than $10^4$, because ammonia gas penetration depth was deeper at turbulent flow compared to laminar flow. For the interpretation, the dimensionless mass transfer governing-equation and the constant physical-properties at room temperature were used. The diffusivity of ammonia in water and the kinematic viscosity of water were $2{\times}10^{-9}m^2/s$ and $1{\times}10^{-6}m^2/s$, respectively. The concentration distribution of ammonia in water was estimated with respect to the position from the point where the water started to be exposed to ammonia. The quantitative distribution as a function of the mixing length was also acquired. The quantitative interpretation may provide the insight how much the turbulent flow was more efficient to remove ammonia rather than the laminar flow.

Ammonia Removal Characteristics of Biolfilm Reactor (생물막을 이용한 상수 원수에서의 암모니아 제거 특성)

  • Shin, Hang-Sik;Lim, Kycong-Ho;Lee, Sang-Min
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.1
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    • pp.78-84
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    • 1996
  • The presence of ammonia, usually in the form of ammonium ion ($NH_4{^+}$), can enhance bacterial growth m the distribution system and make the production of drinking water more costly if ammonium must be removed to ensure good disinfection. Removal of ammonia by biological oxidation could be economical which prevents excess chlorine dosage In this research, effects of hydraulic retention time (HRT) and media type on the ammonia removal efficiencies of submerged biofilm reactor were investigated. The biofilm reactors combined the characteristics of high biological solids capture efficiency and good hydraulic control. The results indicate that biofilms can remove over 77 percent of the ammonia with HRT of longer than 2 hr even at low temperature ranging from 14.6 to $16.6^{\circ}C$. The HRT has a significant effect on nitrification. The overall nitrification and efficiency of ammonia removal increase with increasing HRT. It has also been observed that when the fibrous media was used, the ammonia removal, nitrification rate and endurance to shock improved.

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Simulation of Ammonia Reduction Effect by Hydroxylamine-oxidoreductase Enzyme Immobilized on the Surface of Water Pipe (수로관 표면 고정 히드록실아민-산화환원효소에 의한 암모니아 저감 효과 모사)

  • Lee, Sang-Ryong;Park, Jin-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.35-41
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    • 2020
  • The immobilization of the hydroxylamine-oxidoreductase on the water channel surface was performed to investigate the efficacy of ammonia removal in turbulent flow. The reaction by this enzyme proceeds rapidly by converting hydroxylamine into nitrous acid. For the analysis of the effect, a dimensionless mass transfer governing equation was established with the physical properties based on room temperature. The ammonia diffusion coefficient in water and the kinematic viscosity coefficient of water were 2.45×10-9 ㎡/s and 1×10-6 ㎡/s, respectively. The distribution of ammonia concentration in the water was calculated with respect to the distance from the point at which exposure to ammonia began. The quantitative distribution with respect to the mixing depth was also found. Such a quantitative analysis can provide insight into whether the enzyme immobilized on the water channel surface can be effectively used for ammonia removal.

Effects of Water Temperature and Ambient Ammonia Concentration on Oxygen Consumption and Ammonia Excretion of Greenling Hexagrammos otakii Jordan et Stalks (환경수의 수온과 암모니아 농도 변화에 따른 쥐노래미(Hexagrammos otakii Jordan et Starks) 육성어의 산소소비와 암모니아 배설)

  • Kim, You-Hee;Kim, Pyong-Kih;Kim, Hyeon-Ju;Jo, Jae-Yoon;Han, Won-Min;Park, Jeong-Hwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.42 no.4
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    • pp.373-379
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    • 2009
  • This study investigated oxygen consumption rate (OCR), $Q_{10}$ coefficient and ammonia excretion rate of the greenling, Hexagrammos otakii Jordan et Starks with the average body weight of 250 g in a semi-recirculated respiratory measuring system. The experiment was done under three different water temperatures (10, 15, $20^{\circ}C$) and five different ambient ammonia concentrations (0, 2.5, 5, 10, 20 mg/L). As the water temperature and ambient ammonia concentration increased the OCR has significantly increased (P<0.05). Given experimental conditions, the OCR of greenling were $50.8{\sim}159.4\;mg\;O_2\;kg^{-1}\;hr^{-1}$ and the relationship of water temperature (T) and ambient ammonia concentration (C) on the OCR were following: OCR = 41.3 - 1.87T - 7.38C + $0.463T^2$ + $0.66lC^2$ + 0.642TC - $0.011T^3$ - $0.010C^2$ - $0.031TC^2$ - $0.001T^2$C ($r^2$= 0.9226). $Q_{10}$ coefficients were $1.88{\sim}3.50$ for $10^{\circ}C$ to $15^{\circ}C$, $1.03{\sim}2.73$ for $15^{\circ}C$ to $20^{\circ}C$ and $1.40{\sim}1.90$ for $10^{\circ}C$ to $20^{\circ}C$, respectively. In general, the ammonia excretion rate tended to increase with increasing of the water temperature within normal ambient ammonia concentration. However, interestingly, it was observed that ammonia was absorbed rather than excreted above the ambient ammonia concentration of $2.5\;mg\;L^{-1}$, regardless of the water temperature. Thus, the largest ammonia absorption rate (AAR) was obserbed at the level of $98.4\;mg\;TAN\;kg^{-1}\;hr^{-1}$. The relationship ambient ammonia concentration (C) on AAR was following: Y = 1.61 + $10.9X^{0.7}$ ($r^2$ = 0.889).

Measurement of Ammonia Inhibition of Activated Sludge by DHA-INT (DHA-INT를 이용한 활성슬러지의 암모니아 저해도)

  • Lee, Sang-Min;Jung, Jin-Young;Chung, Yun-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.1969-1976
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    • 2000
  • It is a time consuming work to identify the inhibition of unknown chemicals or industrial wastewater. Thus it is needed to establish a fast assay tool for finding a toxicant source. Biomass activity and ammonia inhibition were measured by DHAINT method. Ammonia inhibition tests were comprised of total ammonia inhibition and free ammonia inhibition. Those inhibitions were carried out by nitrifier and heterotroph each other with nitrifier inhibitor. The ammonia inhibition was proportional to an amount of total ammonia and pH increase. It meaned that a free ammonia played a key role for ammonia inhibition. however both total ammonia and free ammonia should be considered for an accurate assay of the ammonia inhibition. Nitrifier was more sensitive than heterotroph when the ammonia concentration above 3.000mg/L.

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Exergy Analysis of Regenerative Ammonia-Water Rankine Cycle for Use of Low-Temperature Heat Source (저온열원 활용을 위한 암모니아-물 재생 랭킨사이클의 엑서지 해석)

  • Kim, Kyoung-Hoon;Ko, Hyung-Jong;Kim, Se-Woong
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.1
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    • pp.65-72
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    • 2012
  • Rankine cycle using ammonia-water mixture as a working fluid has attracted much attention, since it may be a very useful device to extract power from low-temperature heat source. In this work, the thermodynamic performance of regenerative ammonia-water Rankine cycle is thoroughly investigated based on the second law of thermodynamics and exergy analysis, when the energy source is low-temperature heat source in the form of sensible energy. In analyzing the power cycle, several key system parameters such as ammonia mass concentration in the mixture and turbine inlet pressure are studied to examine their effects on the system performance including exergy destructions or anergies of system components, efficiencies based on the first and second laws of thermodynamics. The results show that as the ammonia concentration increases, exergy exhaust increases but exergy destruction at the heat exchanger increases. The second-law efficiency has an optimum value with respect to the ammonia concentration.