• Title/Summary/Keyword: Ammonia gas sensor

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Worker Symptom-based Chemical Substance Estimation System Design Using Knowledge Base (지식베이스를 이용한 작업자 증상 기반 화학물질 추정 시스템 설계)

  • Ju, Yongtaek;Lee, Donghoon;Shin, Eunji;Yoo, Sangwoo;Shin, Dongil
    • Journal of the Korean Institute of Gas
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    • v.25 no.3
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    • pp.9-15
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    • 2021
  • In this paper, a study on the construction of a knowledge base based on natural language processing and the design of a chemical substance estimation system for the development of a knowledge service for a real-time sensor information fusion detection system and symptoms of contact with chemical substances in industrial sites. The information on 499 chemical substances contact symptoms from the Wireless Information System for Emergency Responders(WISER) program provided by the National Institutes of Health(NIH) in the United States was used as a reference. AllegroGraph 7.0.1 was used, input triples are Cas No., Synonyms, Symptom, SMILES, InChl, and Formula. As a result of establishing the knowledge base, it was confirmed that 39 symptoms based on ammonia (CAS No: 7664-41-7) were the same as those of the WISER program. Through this, a method of establishing was proposed knowledge base for the symptom extraction process of the chemical substance estimation system.

Fabrication and Characteristics of ZnO-based thin film sensors with high selectivity for TMA gas (TMA 가스 선택성 향상을 위한 ZnO계 박막센서의 제작 및 특성)

  • Park, Sung-Hyun;Choi, Woo-Chang;Kim, Sung-Woo;Ryu, Jee-Youl;Choi, Hyek-Hwan;Lee, Myong-Kyo;Kwon, Tae-Ha
    • Journal of Sensor Science and Technology
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    • v.9 no.1
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    • pp.36-43
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    • 2000
  • In oder to enhance the selectivity of TMA(trimethylamine) gas, the ZnO-based films which were doped with $Al_2O_3$, $TiO_2, $In_2O_3$ and $V_2O_5$ catalysts with various weight percents were deposited in oxygen by RF magnetron sputtering method. To improve electrical stability of sensors, the ZnO-based films were annealed in oxygen at $700^{\circ}C$ for 1 hour. The TMA selectivity of sensors was defined by the magnitude($S_{TMA}/S_{DMA}$ and $S_{TMA}/S_{NH3}$) of TMA sensitivity relative to DMA and sensitivity ammonia($NH_3$) sensitivity, respectively. The $ZnO+Al_2O_3(4\;wt.%)+TiO_2(1\;wt.%)+In_2O_3(1\;wt.%)$ sensor showed high $S_{TMA}/S_{DMA}$ of 5.9 and $S_{TMA}/S_{NH3}$ of 26 to 160 ppm at the working temperature of $300^{\circ}C$ respectively.

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Measuring the Environment of Pig Houses (돈사의 환경계측에 관한 연구)

  • 최규홍;손재룡;이강진;최동수;최용삼;남상일
    • Journal of Animal Environmental Science
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    • v.7 no.3
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    • pp.155-164
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    • 2001
  • Environmental factors such as $NH_3,\;H_2S,\;CO_2$, dust, temperature, and humidity in the animal house are a potential health hazard to humans and animals. Until now, most of measurement methods can only provide periodic results with low accuracy. A data acquisition system which can measure continuously and simultaneously $NH_3,\;H_2S,\;CO_2$, temperature, and humidity was developed and installed in two pig houses. Daily changes of environment for the pig-houses were investigated by the data acquisition system. In order to evaluate NH$_3$sensor, gas samples were obtained and NH$_3$concentrations were measured at nine positions; combinations of three positions(inlet, middle, and outlet) and three heights(0 cm, 40 cm, 150 cm). Ammonia concentration of 14.0 ~37.1 ppm for slurry pig-house is higher than that of 8.4~29.7 ppm for scraper pig-house, and there were no statistical differences among the positions. However, the concentration of $NH_3$at 150 cm was higher than thats of 0 cm and 40 cm.

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The Development and Implementation of Model-based Control Algorithm of Urea-SCR Dosing System for Improving De-NOx Performance and Reducing NH3-slip (Urea-SCR 분사시스템의 DeNOx 저감 성능 향상과 NH3 슬립저감을 위한 모델 기반 제어알고리즘 개발 및 구현)

  • Jeong, Soo-Jin;Kim, Woo-Seung;Park, Jung-Kwon;Lee, Ho-Kil;Oh, Se-Doo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.95-105
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    • 2012
  • The selective catalytic reduction (SCR) system is a highly-effective aftertreatment device for NOx reduction of diesel engines. Generally, the ammonia ($NH_3$) was generated from reaction mechanism of SCR in the SCR system using the liquid urea as the reluctant. Therefore, the precise urea dosing control is a very important key for NOx and $NH_3$ slip reduction in the SCR system. This paper investigated NOx and $NH_3$ emission characteristics of urea-SCR dosing system based on model-based control algorithm in order to reduce NOx. In the map-based control algorithm, target amount of urea solution was determined by mass flow rate of exhaust gas obtained from engine rpm, torque and $O_2$ for feed-back control NOx concentration should be measured by NOx sensor. Moreover, this algorithm can not estimate $NH_3$ absorbed on the catalyst. Hence, the urea injection can be too rich or too lean. In this study, the model-based control algorithm was developed and evaluated on the numerical model describing physical and chemical phenomena in SCR system. One channel thermo-fluid model coupled with finely tuned chemical reaction model was applied to this control algorithm. The vehicle test was carried out by using map-based and model-based control algorithms in the NEDC mode in order to evaluate the performance of the model based control algorithm.

Determination of L-Asparagine Using Proteus mirabilis Bacterial Electrode (Proteus mirabilis 박테리아 전극을 이용한 L-Asparagine의 정량)

  • Ihn Gwon-Shik;Moo-Jeong Sohn
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.422-427
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    • 1988
  • The bio-electrode for L-asparagine, excellent in the reproducibility of responsibility, has been constructed by immobilizing the bacterium Proteus mirabilis on an ammonia gas sensor. This electrode was investigated for the effects of pH, temperature, buffer solution, bacterial amounts and interferences, and stability with the lapse of time. The response of the bacterial electrode was linear in the range of $9.0{\times}10^{-5}$$1.0{\times}10^{-2}M$ L-asparagine with a slope of 58.9mV/decade in pH 7.8, 0.05M phosphate buffer solution at $30^{\circ}C$. The bacterial amounts used for this electrode was 3 mg and response time was 7∼9 min. Therefore, this assembly can be used for the determination of L-asparagine.

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