• Title/Summary/Keyword: Ammonia gas

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Analysis of Offensive Odorous Compounds Emitted From the Chemical Plants (화학공장에서 배출되는 악취규제물질의 분석 및 평가)

  • Choi, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.33-38
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    • 2007
  • The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous com-pounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.

Biofilter를 이용한 천연피혁제조공장의 악취성분제거

  • Kim, Jong-U;Mun, Jong-Hye;Park, Jin-Su;O, Gwang-Jung;Kim, Dong-Uk
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.163-166
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    • 2000
  • Hydrogen sulfide, ammonia and benzene which are generated from natural leather industry were simultaneously removed using biofilter including benzene degrading microbial consortia and sulfur oxidizer Thiobacillus sp.IW. The removal efficiency of benzene was maintained 90% in average for single and mixed gas treatment and that of ammonia was 99%, whereas at of hydrogen sulfide was relatively lower 85%.

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Biofilter를 이용한 축산 ${\cdot}$ 분뇨 중의 암모니아와 황화수소의 동시 제거

  • Gang, Yeom-Seok;Hwang, Jae-Ung;Jang, Seok-Jin;Park, Seong-Hun
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.516-519
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    • 2000
  • Lab-scale biofilter was studied for the simultaneous removal of ammonia and hydrogen sulfide in gas mixtures. Compost and polyurethane foam were used as packing materials (50 : 50) and activated sludge from a wastewater treatment plant was innoculated initially. When tested under varying inlet concentrations and empty bed residence time(EBRT), up to 80 ppmv of ammonia and 40 ppmv of hydrogen sulfide could be removed completely at an EBRT of 30 sec. The pH was found to be the key factor governing the biofilter performance.

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NUMERICAL STUDY ON THE MIXER TYPE OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템의 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.;Kim, W.S.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.368-375
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the NH3-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed device. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of NH3 by numerical simulation.

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NUMERICAL STUDY ON THE MIXER TYPES OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템에서 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.
    • Journal of computational fluids engineering
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    • v.15 no.4
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    • pp.9-16
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the $NH_3$-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore, it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed devices. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of $NH_3$ by numerical simulation.

A development of reactor design software for De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 De-NOx 시스템의 반응로 설계 전산프로그램 개발)

  • 정경열;오상훈;동은석;이수태;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.187-191
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    • 2002
  • The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

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Decomposition of Odorous Gases in a Pilot-scale Nonthermal Plasma Reactor

  • Hwang, Yoon-Ho;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.57-65
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    • 2005
  • An experimental study was performed on the decomposition of gaseous ammonia and two selected volatile organic compounds (VOCs: toluene and acetone) in a combined nonthermal plasma reactor with corona and glow discharges. A lab pilot scale reactor (206 liter) equipped with a high electric power pack was used to determine the decomposition efficiency in relation with the inlet concentration and applied voltage. Three different types of discharging electrode such as wired rack, wire strings for corona discharge, and thin plate for glow discharge were put in order in the reactor. While decomposition of ammonia decreased with an increase in the initial concentration, acetone showed an opposite result. In the case of toluene however no explicit tendency was found in toluene and aceton. Negative discharge resulted in high decomposition efficiency than the positive one for all gases. A better removal of gas phase element could be achieved when fume dust were present simultaneously.

Stability Analysis of Marangoni Convection for $NH_3\;-H_2O$ Absorption Process (전파이론을 통한 $NH_3\;-H_2O$ 흡수과정의 마란고니 대류 안정성 해석)

  • 최창균;김제익;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.6
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    • pp.450-455
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    • 2002
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas using the linear stability theory. The propagation theory is adapated to find the critical conditions of the onset of solutal Maragoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number It is interesting that for a smaller Biot number than 100, the system becomes stable with decreasing Bi but for a larger Bi, it becomes unstable with decreasing Bi.

The Study on the Removal of Odor Emitting Environmental Fundamental Facility (환경기초시설에서 발생하는 악취가스 제거에 관한 연구)

  • Lee, Byung-Kwan;Lee, Sang-Hun;Tak, Sung-Je;Lee, Byung-Ki
    • Journal of Climate Change Research
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    • v.8 no.1
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    • pp.51-56
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    • 2017
  • The objective of the research project is to develop the hybrid deodorizer for the removal of residual harmful gases generating during pretreatment process of biogas. This hybrid deodorizer is capable of treating harmful gases that contains hydrogen sulfide ($H_2S$), ammonia ($NH_3$) and other odor substances. This hybrid deodorizer reduced the hydrogen sulfide content from approximately 150~200 ppm to less than 16 ppm. These residual harmful gases were effectively removed in the effluent, achieving up to 97% removal of $H_2S$ and 94% removal of $NH_3$ after treatment using hybrid deodorizer.

Analysis of Thermal Control Performance of Variable Conductance Heat Pipe with Axial Grooves (축방향 그루브형 가변전열 히트파이프의 열제어 특성)

  • Park, Y.S.;Kim, D.E.;Byon, G.S.;Suh, J.S.;Lee, K.W.;Park, K.H.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1651-1656
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    • 2003
  • The present study has been conducted to analytically investigate the thermal control performance of variable conductance heat pipe(YCHP) with axial grooves. The condenser port of the YCHP is occupied by a inert gas in which the concentration of gas is varied with the operation temperature and the heat transport capacity is thus varied with the operating temperature due to the variation of inert gas concentration. In this study, numerical evaluation for the thermal control of the YCHP with axial grooves is made from the 1st order diffusion model that considers the diffusive expansion of inert gas by concentration gradient. Ammonia is used as a working fluid and Nitrogen as a control gas in the Aluminum tube. As a result, the thermal performance of YCHP based on diffusion model has been compared with that of YCHP from flat front model. Additionally, it is found that the concentration of inert gas is distributed in the condenser region of YCHP with axial grooves.

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