• Journal of Environmental Health Sciences
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• v.36 no.1
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• pp.33-43
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• 2010

Atmospheric ammonia is a very important constituent of the environment because it is the dominant alkaline gaseous species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. In this study flux profiles of ammonia emitted from the cattle housing were evaluated using a dynamic flux chamber (DFC). We have developed the emission factor of $NH_3$ from the cattle housing. Analysis of ammonia flux variation was made with respect to such variables as manure surface temperature, pH, and ammonium concentration. Ammonia flux has been measured up to summer in 2007 at calf and cattle housing. In the fall, average ammonia flux from calf and cattle housing was estimated as 1.406 (${\pm}0.947$) and 1.534 ((${\pm}0.956$) $mg\;m^2\;min^1$, respectively. In the winter, average ammonia flux was estimated 1.060 ((${\pm}0.569$) from the calf housing and 1.216 ((${\pm}0.655$) $mg\;m^2\;min^1$ from the cattle housing. The correlation coefficient (R=0.732) between ammonia flux and manure surface ammonium concentration exhibited stronger relationship than manure surface pH and temperature. In the fall, ammonia emission factor from calf and cattle housing was estimated as 3.94 ((${\pm}2.66$) and 11.41 ((${\pm}5.86$) kg-$NH_3$ animal$^1\;yr^1$, respectively. In the winter, ammonia average flux was estimated as 2.89 ((${\pm}1.59$) from the calf housing and 6.51 ((${\pm}3.67$) kg-$NH_3$ animal$^1\;yr^1$ from the cattle housing.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.701-711
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• 2006

Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

• Journal of Environmental Impact Assessment
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• v.19 no.1
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• pp.1-13
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• 2010

Ammonia ($NH_3$) is an important pollutant that plays a key role in several air pollution problems. It can create odors and have negative impacts on animal and human health. The largest source contributing to Ammonia emission is the agricultural production, in particular animal operation, in Korea. The present study evaluated flux profiles of Ammonia emitted from the cattle housing using a dynamic flux chamber. We have developed the emission factor of Ammonia from the cow housing. Analysis of Ammonia flux variation was made with respect to manure surface temperature, pH, and ammonium concentration. Ammonia has been measured from calf and cattle housing between October and December in 2007. In the fall, average Ammonia flux from calf and cattle housing was estimated 1.342(${\pm}0.728$) and 1.323(${\pm}0.655$)mg/$m^2$/min, respectively. In the winter, average Ammonia flux was estimated 0.889(${\pm}0.362$)mg/$m^2$/min from the calf housing and 0.925(${\pm}0.511$)mg/$m^2$/min from the cattle housing. The correlation coefficient between Ammonia flux and ammonium concentration showed stronger relationship than the relationship between manure pH and temperature. In the fall, Ammonia emission factor from calf and cattle housing was estimated 4.46(${\pm}2.39$) and 6.03(${\pm}3.27$)kg-$NH_3$/animal/yr, respectively. In the winter, average Ammonia flux was estimated 2.88(${\pm}1.53$) from the calf housing and 4.24({$\pm}1.63$)kg-$NH_3$/animal/yr from the cattle housing.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.4
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• pp.432-442
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• 2010

Ammonia is a very important constituent of the atmospheric environment because it is the most dominant gaseous alkaline species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. Ammonia flux from livestock facilities can be regulated by a number of environmental factors (pH, ammonium ion, temperature, wind speed, etc). The increases in wind speed above manure from 0.0 m/s to 1.0 7m/s resulted in 2.5 times increases in ammonia flux. Wind speed and ammonia flux showed 0.982. A linear relationship with a correlation coefficient (r=0.982). When manure temperature increased from $3^{\circ}C$ to $36^{\circ}C$, the manure pH decreased approximately 0.30 to 0.46. As wind speed above the manure increased from 0.0 m/s to 1.07 m/s, ammonia flux increased approximately 2.5 times. The increasing manure temperature from $3^{\circ}C$ to $10^{\circ}C$, raised ammonia flux from 2.0 to 3.6 times (2.6 times in average similarly). The increases of manure temperature from $3^{\circ}C$ to $25^{\circ}C$ increased ammonia flux from 5.7 to 12.9 times (8.5 times in average). In this study, the correlation coefficient between ammonia flux and manure temperature was found from 0.972 to 0.989. Results of our research showed that ammonium ion concentration, pH of manure and wind speed were important factors in controlling the ammonia flux from manure livestock facilities.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.4
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• pp.503-510
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• 2011

Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.33-41
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• 2010

Because ammonia from livestock production may substantially contribute to environmental pollution, emissions from all possible sources (housing systems, manure storage, manure application, outside grazing) should be reduced. The purpose of this study was to investigate the effect of different bedding materials on ammonia emissions in a cow house. By applying a combination of four treatment types: treatment $1-T_1$ (sawdust (50%)+sawdust pellets (50%)), treatment $2-T_2$ (sawdust (50%)+corn stalk pellets (50%)), treatment $3-T_3$ (sawdust (100%)), and treatment $4-T_4$ (sawdust (50%)+palm kernel meal pellets(50%)) as bedding materials in a cow house, the effects of such treatments on ammonia flux were assessed in approximately one month. The magnitude of ammonia emissions (mg $m^{-2}\;min^{-1}$) varied in the following order: $T_1$(2.226), $T_4$(2.052), $T_2$(1.845), and $T_3$(1.712). The patterns of pH had a decreasing trend for all bedding treatments during the experiment, and there was no significant relationship with ammonia flux. The results reveal that the most important factor influencing ammonia emissions is the physical structure of the bedding types.

• Journal of Environmental Impact Assessment
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• v.14 no.5
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• pp.263-273
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• 2005

In this study, the major emission procedures and emission characteristics were identified at the site of sewage treatment plant which is one of the major sources of ammonia. At the same time the emission factors and emission rates were estimated. In order to calculate the emission flux, we used a Dynamic Flux Chamber(DFC), which is found to be a proper sampling devise for area sources such as sewage treatment plant. It was found that the most stable sampling condition was when the stirrer's speed of DFC was 120RPM, and it would be the best time to take a sample 60 minutes later after setting the chamber. The relatively higher flux was shown in Autumn compared to summer and winter. Annual ammonia emission rates procedures were calculated as $906.32{\mu}g/activity-ton$, $1,114.72{\mu}g/activity-ton$ and $437.53{\mu}g/activity-ton$ each at the primary settling basin, aeration basin and the final settling basin, respectively. The ammonia emission rate the highest at in the aeration basin according to this test. This results was due to that the surface of aeration basin or the final settling basin is relatively wider than the primary settling basin.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.2
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• pp.101-108
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• 2013

This paper is presented an experimental study of flow boiling heat transfer characteristics of ammonia, and is focused on pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal small tube with inner diameter of 3.0 mm and length of 2000 mm. The direct heating method is applied for supplying heat to the refrigerant, where the test tube is uniformly heated by electric current. The local heat transfer coefficients were obtained over a heat flux range of 20 to $80kW/m^2$, a mass flux range of 50 to $500kg/m^2s$, a saturation temperature range of 0 to $10^{\circ}C$, and quality up to 1.0. The pressure drops increase with increasing mass flux and heat flux, and with decreasing saturation temperature. The heat transfer coefficients increase with increasing mass flux and saturation temperature in middle and high quality region. And the local heat transfer coefficient increase with increasing heat flux in low quality region. The heat transfer coefficient of the experimental result was compared with six existing heat transfer coefficient correlation. A new boiling heat transfer coefficient correlation based on the superposition model for ammonia in small tubes is developed average deviation of -0.17% and mean deviation of 10.85%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.6
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• pp.561-569
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• 2000

Single phase and condensation heat transfer characteristics of ammonia in a horizontal tube have been investigated experimentally The horizontal test section is composed of smooth SUS316 tube for refrigerant flow, surrounding annulus for water flow, and temperature and Pressure measuring sensors. For single phase test, subcooled ammonia mass flux was varied from 320 to 501 kg/mrs and temperature was varied from 18 to $47^{\circ}C$. For condensation test, mass flux and saturation temperature were varied from 86 to 128 kg/$m^2$s and 34 to $47^{\circ}C$, respectively. The equations of Gnielinski Soliman et al., Traviss et at., Cavallini and Zecchin, Shah, Chen et al., Tandon et al., and Chilli and Anand were compared with the experimental data. New correlations are proposed based on the experimental results and the absolute mean deviation of the experimental data becomes 1.0% for single phase test and 4.9% for condensation test.

• Ocean and Polar Research
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• v.26 no.4
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• pp.635-646
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• 2004

Chronic outbreaks of green tide in the Nakdong estuary toll a heavy socioeconomic cost. The paper investigates the influence of sediments on the nitrogen eutrophication, being claimed as the primary cause of green tide. To measure the flux of nitrate at the sediments-water interface, sediment cores were taken in Jan., Mar., May and Sep., 2000 at Noksan located in the West-Nakdong river estuary. The dissolved oxygen was profiled and then the pore water was extracted in situ. Core samples were analyzed for their textural characteristics. Cores were incubated by a novel technique to measure the fluxes of nitrate $(NO_3^-)$ and ammonia $(NH_4^+)$ at the sediment-water interface. The dissolved oxygen was depleted usually within several millimeters in the top sediments. Nitrate started to decrease drastically at the layer where dissolved oxygen was nearly depleted. Nitrate was also exhausted within several centimeters, followed by ammonia build up rapidly. The flux at the sediments-water interface calculated from the pore water concentrations revealed that nitrate was removed from the water column into the sediments. The sediment incubation experiment confirmed the above result. On the other hand ammonia were released from the sediment to the water column. As the incubation went on, however, the nitrate concentration in the overlying water was dropped below that of a top sediment. Then the flux is reversed, i.e., nitrate was released from the sediments to the water column. The implication is that the sediment can supply nitrate to the water column if it falls below a certain level. Thus it is likely that sediments in the eutrophicated river buffers the nitrate concentration in the water column, which leads to a prolonged green tide.