• 분석과학
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• 제34권5호
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• pp.202-211
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• 2021

Volatile organic compounds (VOCs) in hazardous air pollutants (HAPs) have been regulated by the Air Pollution Control Act (1978) and their atmospheric concentrations have been monitored in 39 monitor sites in Korea. However, measurement standards of volatile organic compounds (VOCs) in HAPs at ambient levels have not been established in Korea. Primary reference gas mixtures (measurement standards) at ambient levels are required for accurately monitoring atmospheric VOCs in HAPs and managing their emissions. In this study, primary reference gas mixtures (PRMs) at 5 nmol/mol were developed in order to establish primary national standards of VOCs in HAPs at ambient levels. Primary reference gas mixtures (PRMs) were prepared in pressurized aluminum cylinders with special internal surface treatment using gravimetric method. Analytical methods using gas chromatography-flame ionization detector (GC-FID) coupled with a cryogenic preconcentrator were also developed to verify the consistency of gravimetrically prepared HAP VOCs PRMs. Three different columns installed in the GC-FID were evaluated and compared for the retention times and separation of eighteen target components in a chromatogram. Results show that the HAP VOCs PRMs at 5 nmol/mol were consistent within a relative expanded uncertainty (k=2) of less than 3 % except acrylonitrile (less than 6 %) and the 18 VOCs were stable for 1 year within their associated uncertainties.

• International Journal of Automotive Technology
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• 제8권4호
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• pp.437-444
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• 2007

This paper experimentally investigates the effects of oxygen-enriched air (OEA) on the running behaviors of an LPG SI engine during both start/warm-up (SW) and hot idling (HI) stages. The experiments were performed on an air-cooled, single-cylinder, 4-stroke, LPG SI engine with an electronic fuel injection system and an electrically-heated oxygen sensor. OEA containing 23% and 25% oxygen (by volume) was supplied for the experiments. The throttle position was fixed at that of idle condition. A fueling strategy was used as following: the fuel injection pulse width (FIPW) in the first cycle of injection was set 5.05 ms, and 2.6 ms in the subsequent cycles till the achieving of closed-loop control. In closed-loop mode, the FIPW was adjusted by the ECU in terms of the oxygen sensor feedback. Instantaneous engine speed, cylinder pressure, engine-out time-resolved HC, CO and NOx emissions and excess air coefficient (EAC) were measured and compared to the intake air baseline (ambient air, 21% oxygen). The results show that during SW stage, with the increase in the oxygen concentration in the intake air, the EAC of the mixture is much closer to the stoichiometric one and more oxygen is made available for oxidation, which results in evidently-improved combustion. The ignition in the first firing cycle starts earlier and peak pressure and maximum heat release rate both notably increase. The maximum engine speed is elevated and HC and CO emissions are reduced considerably. The percent reductions in HC emissions are about 48% and 68% in CO emissions about 52% and 78%; with 23% and 25% OEA, respectively, compared to ambient air. During HI stage, with OEA, the fuel amount per cycle increases due to closed-loop control, the engine speed rises, and speed stability is improved. The HC emissions notably decrease: about 60% and 80% with 23% and 25% OEA, respectively, compared to ambient air. The CO emissions remain at the same low level as with ambient air. During both SW and HI stages, intake air oxygen enrichment causes the delay of spark timing and the increased NOx emissions.

• 한국대기환경학회지
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• 제23권4호
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• pp.498-506
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• 2007

이 논문에서는 최근 서울시에서 시행하고 있는 대기오염 개선을 위한 정책 중 하나인 승용차 요일제가 대기오염도 저감에 어느 정도 효과가 있는지를 밝히려고 하였다. 먼저, 승용차 요일제와 같은 형태인 차량 2부제의 효과에 대한 연구에서 서로 다른 결론을 내고 있는 두 논문 김철희 등(2005)과 Lee et al.(2005)을 분석해 보았다. 분석 결과, 언뜻 보기에 전혀 다른 결론을 내리고 있는 것 같았던 두 논문은 문제에 접근하는 시각이 달랐기 때문에 다른 결론에 이른 것일 뿐, 기본적으로 같은 사실에 동의하고 있음을 알 수 있었다. 즉, 두 연구 모두 대기오염도는 오염물질의 배출량과 매일매일의 기상조건에 의해 결정된다는 사실이다. 가장 최근의 자동차 관련 자료를 활용하여 2002년도 차량 2부제 시행시, 서울에서의 배출량 변화를 계산하였다. 전체 배출량에 대해 이산화질소는 22.3%, 미세먼지는 5.5%, 아황산가스는 2.4% 저감되었다. 이러한 배출량의 저감이 대기 농도 변화에 미친 기여율을((배출량 변화/대기 농도변화)$\times$100로 정의) 계산한 결과 이산화질소 97%, 미세먼지 28%, 아황산가스 6%였다. 또한, 비산먼지 배출을 고려하여야 정확한 미세먼지 저감 영향을 산출할 수 있음을 알았다.

• 대기
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• 제26권4호
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• pp.541-551
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• 2016

A real-time quality control algorithm for $PM_{10}$ concentration measured by Continuous Ambient Particulate Monitor (FH62C14, Thermo Fisher Scientific Inc.) has been developed. The quality control algorithm for $PM_{10}$ data consists of five main procedures. The first step is valid value check. The values should be within the acceptable range limit. Upper ($5,000{\mu}g\;m^{-3}$) and lower ($0{\mu}g\;m^{-3}$) values of instrument detectable limit have to be eliminated as being unrealistic. The second step is valid error check. Whenever unusual condition occurs, the instrument will save error code. Value having an error code is eliminated. The third step is persistence check. This step checks on a minimum required variability of data during a certain period. If the $PM_{10}$ data do not vary over the past 60 minutes by more than the specific limit ($0{\mu}g\;m^{-3}$) then the current 5-minute value fails the check. The fourth step is time continuity check, which is checked to eliminate gross outlier. The last step is spike check. The spikes in the time series are checked. The outlier detection is based on the double-difference time series, using the median. Flags indicating normal and abnormal are added to the raw data after quality control procedure. The quality control algorithm is applied to $PM_{10}$ data for Asian dust and non-Asian dust case at Seoul site and dataset for the period 2013~2014 at 26 sites in Korea.

• 한국생물환경조절학회:학술대회논문집
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• 한국생물환경조절학회 2004년도 추계학술대회 논문집
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• pp.139-143
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• 2004

To evaluate the biological and physiological response of Picea koraiensis Nakai to elevated $CO_2$ and nitrogen.3-year old seedlings were planted in an ambient and 700 ppm $CO_2$ at low (2mM $NH_4NO_3$) or high nitrogen (16mM $NH_4NO_3$) supplying treatments for 3 months. Photosynthetic parameters were measured monthly. Seedlings were harvested at monthly intervals and growth parameters of root system, stem and needle fractions were evaluated. The result showed that height of the seedlings grown at both of elevated $CO_2Xhigh$ nitrogen and elevated CO2×low nitrogen supplying treatments increased significantly more than that of at ambient CO2 treatments. Seedlings grown at elevated $CO_2Xhigh$ nitrogen produced more root biomass than at elevated $CO_2Xlow$ nitrogen and ambient $CO_2Xhigh$ nitrogen treatments. This result suggested that the root growth response of Picea koraiensis seedlings was greater in elevated $CO_2{\times}high$ nitrogen regime, which is very important for carbon sequestration in soil. $A_{max}$ of the seedlings grown at elevated $CO_2Xhigh$ nitrogen increased during the three months significantly, and $A_{max}$ of the seedlings grown at the other three treatments decreased significantly, suggesting that the interaction between elevated $CO_2$ and high nitrogen supplying stimulates the $A_{max}$ of Picea koraiensis. $A_{max}$ of the seedlings grown at elevated $CO_2Xlow$ nitrogen showed higher than other three treatments in the first month of the experiment, but decreased in succedent two months, suggesting that elevated $CO_2$ promotes the photosynthesis of the seedlings. However long term growth in elevated $CO_2Xlow$ nitrogen supplying condition resulted in an acclimatory decreased in leaf photosynthesis.

• 센서학회지
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• 제25권5호
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• pp.377-381
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• 2016

NDIR $CO_2$ gas sensor was prototyped with ASIC implemented thermopile sensor which included temperature sensor and White-Cell structure in this paper. The temperature dependency of dual infrared sensors ($CO_2$ and reference IR sensors) has been characterized and their output voltage ratios according to the temperature and gas concentration were presented in this paper for achieving temperature compensation algorithm. The initial output voltages of NDIR $CO_2$ gas and reference IR sensors showed $3^{rd}$ order polynomial and linear output voltages according to the variation of ambient temperatures from 253 K to 333 K, respectively. The output voltages of temperature sensor presented a linear dependency according to the ambient temperature and could be described with V(T) = -3.0069+0.0145T(V). The characteristics of output voltage ratios could be modeled with five parameters which are dependent upon the ambient temperatures and gas concentration. The estimated $CO_2$ concentrations showed relatively high error below 300 ppm (maximum 572 % at 7 ppm $CO_2$ concentration), however, as the concentration increased from 500 ppm to 2,000 ppm, the overall estimated errors of $CO_2$ concentrations were less than ${\pm}10%$ in this research.

• 농업과학연구
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• 제48권4호
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• pp.703-718
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• 2021

An irrigation monitoring system is an efficient approach to save water and to provide effective irrigation scheduling for rice cultivation in desert soils. This research aimed to design, fabricate, and evaluate the basic performance of an irrigation monitoring system based on information and communication technology (ICT) for rice cultivation under drip and micro-sprinkler irrigation in desert soils using a Raspberry Pi. A data acquisition system was installed and tested inside a rice cultivating net house at the United Arab Emirates University, Al-Foah, Al-Ain. The Raspberry Pi operating system was used to control the irrigation and to monitor the soil water content, ambient temperature, humidity, and light intensity inside the net house. Soil water content sensors were placed in the desert soil at depths of 10, 20, 30, 40, and 50 cm. A sensor-based automatic irrigation logic circuit was used to control the actuators and to manage the crop irrigation operations depending on the soil water content requirements. A developed webserver was used to store the sensor data and update the actuator status by communicating via the Pi-embedded Wi-Fi network. The maximum and minimum average soil water contents, ambient temperatures, humidity levels, and light intensity values were monitored as 33.91 ± 2 to 26.95 ± 1%, 45 ± 3 to 24 ± 3℃, 58 ± 2 to 50 ± 4%, and 7160-90 lx, respectively, during the experimental period. The ICT-based monitoring system ensured precise irrigation scheduling and better performance to provide an adequate water supply and information about the ambient environment.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2006년도 춘계학술대회 논문집
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• pp.374-375
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• 2006

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.764-767
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• 2003

The characteristics of diesel spray have much effect on the engine performances such as power. fuel consumption rate and emissions. Therefore, the measurement of fuel spray characteristics is very important for the improvement of heat engine. The factors which control diesel spray characteristics are injection pressure, ambient temperature and density etc. Spray behaviors are visualized by using the high speed video camera and spray angle, spray penetration are measured. Experimental equations of spray penetration and spray angle were derived by using the experimental results. 1) Ambient temperature and density influence on the characteristics of diesel spray. 2) Experimental equation of spray penetration is expressed as follows 0＜t＜ $t_{b}$ ; $S_1$=11.628$\Delta$ $P^{0.485}$ $\rho$$_{a}$ $^{-0.478}$ $t^{1.337}$, $t_{b}$ ＜t; $S_2$=7.457$\Delta$ $P^{0.523}$ $\rho$$_{a}$ $^{-0.382}$ $t^{0.548}$ 3) Experimental equation of spray Angie is expressed as follows $T_{a}$ =293K; Tan($\theta$/2)=059($\rho$$_{a}$ / $\rho$$_{f}$ )$^{0.437}$, $T_{a}$ =473K; Tan($\theta$/2)=0588($\rho$$_{a}$ / $\rho$$_{f}$ )$^{0.404}$_{f}$ )$^{0.404}$

• Asian-Australasian Journal of Animal Sciences
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• 제31권4호
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• pp.556-563
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• 2018

Objective: Spirulina has been recognized formerly as a filamentous spiral-shaped blue- green algae but more recently as a genus of photosynthetic bacteria (Arthrospira). This microorganism is considered as a rich source of essential nutrients for human and animals. The present study was conducted to determine potential application of Spirulina for heat- exposed broilers. Methods: Two hundred and fifty Cobb 500 chicks with male to female in equal ratio with average initial weight of 615.6 g at 17 days of age were divided into 5 treatments with 5 replicates of 10 chicks. Treatment groups were as follows: positive and negative controls with 0% Spirulina supplement and three Spirulina receiving groups with 5 g/kg (0.5%), 10 g/kg (1%), and 20 g/kg (2%) supplementation. Spirulina receiving groups as well as positive control were exposed to high ambient temperature at $36^{\circ}C$ for 6 h/d from 38 to 44 days of age. Biochemical variables were measured in serum samples at 35, 38, 42, and 45 days of broiler chickens age. Results: The results showed that supplementation of the diet with Spirulina decreased concentration of stress hormone and some serum lipid parameters while enhanced humoral immunity response and elevated antioxidant status whereas it didn't meaningfully affect performance characteristics. Nevertheless, feed conversion ratio was improved numerically but not statistically in broilers fed with 1% Spirulina under high ambient temperature. Conclusion: Overall, the present study suggests that alleviation of adverse impacts due to high ambient temperature at biochemical level including impaired enzymatic antioxidant system, elevated stress hormone and lipid profile can be approached in broiler chickens through supplementation of the diet with Spirulina platensis.