• Journal of Environmental Science International
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• v.18 no.5
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• pp.589-594
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• 2009

The goals of this study were conducted to investigate the effects of applying liquid aluminum chloride ($AlCl_3$) to rice hulls on pH and soluble reactive P (SRP). A total of 800 broiler chicks (4 treatments $\times$ 4 replicates $\times$ 50 birds) were housed into 16 floor pens in a single house for 5 weeks. The treatments were divided into 4 groups: control, 100 g of liquid $AlCl_3/kg$ of rice hulls, 200 g of liquid $AlCl_3/kg$ of rice hulls, and 300 g of liquid $AlCl_3/kg$ of rice hulls. Liquid $AlCl_3$ was sprayed on the rice hulls surface at a rate of 100 g, 200 g, and 300 g liquid $AlCl_3$ per kg rice hull. pH values and SRP contents were significantly decreased (P<0.05) with the increased liquid $AlCl_3$ levels in comparison with control. However, no significant differences in SRP contents were observed among all treatments at 3 and 4 weeks. Applying 100 g, 200 g, and 300 g liquid $AlCl_3$ to rice hulls reduced SRP contents by 18, 25, and 52% for 5 weeks, respectively, compared with the controls. In conclusion, these results suggest that using liquid $AlCl_3$ on rice hulls should be promising for reducing water contamination and resulted in a reduction in SRP contents, which reduced pH.

• Ocean and Polar Research
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• v.29 no.4
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• pp.379-389
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• 2007

This paper presents an attempt to determine natural background levels of heavy metals which could be used for assessing heavy metal contamination. For this study, a large archive dataset of heavy metal concentration (Cu, Cr, Ni, Pb, Zn) for more than 900 surface sediment samples from various Korean coastal environments was newly compiled. These data were normalized for aluminum (grain-size normalizer) concentration to isolate natural factors from anthropogenic ones. The normalization was based on the hypothesis that heavy metal concentrations vary consistently with the concentration of aluminum, unless these metals are of anthropogenic origin. So, the samples (outliers) suspected of receivingany anthropogenic input were removed from regression to ascertain the "background" relationship between the metals and aluminum. Identification of these outliers was tested using a model of predicted limits at 95%. The process of testing for normality (Kolmogorov-Smirnov Test) and selection of outliers was iterated until a normal distribution was achieved. On the basis of the linear regression analysis of the large archive (please check) dataset, background levels, which are applicable to heavy metal assessment of Korean coastal sediments, were successfully developed for Cu, Cr, Ni, Zn. As an example, we tested the applicability of this baseline level for metal pollution assessment of Masan Bay sediments.

• Applied Science and Convergence Technology
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• v.27 no.1
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• pp.9-13
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• 2018

Samples of anodic oxide film used in semiconductor and display manufacturing processes were prepared at different electrolyte temperatures to investigate the corrosion resistance. The anodic oxide film was grown on aluminum alloy 6061 by using a sulfuric acid ($H_2SO_4$) electrolyte of 1.5 M at $0^{\circ}C$, $5^{\circ}C$, $10^{\circ}C$, $15^{\circ}C$, and $20^{\circ}C$. The insulating properties of the samples were evaluated by measuring the breakdown voltage, which gradually increased from 0.43 kV ($0^{\circ}C$) to 0.52 kV ($5^{\circ}C$), 1.02 kV ($10^{\circ}C$), and 1.46 kV ($15^{\circ}C$) as the electrolyte temperature was increased from $0^{\circ}C$ to $15^{\circ}C$, but then decreased to 1.24 kV ($20^{\circ}C$). To evaluate the erosion of the film by fluorine plasma, the plasma erosion and the contamination particles were measured. The plasma erosion was evaluated by measuring the breakdown voltage after exposing the film to $CF_4/O_2/Ar$ and $NF_3/O_2/Ar$ plasmas. With exposure to $CF_4/O_2/Ar$ plasma, the breakdown voltage of the film slightly decreased at $0^{\circ}C$, by 0.41 kV; however, the breakdown voltage significantly decreased at $20^{\circ}C$, by 0.83 kV. With exposure to $NF_3/O_2/Ar$ plasma, the breakdown voltage of the film slightly decreased at $0^{\circ}C$, by 0.38 kV; however, the breakdown voltage significantly decreased at $20^{\circ}C$, by 0. 77 kV. In addition, for the entire temperature range, the breakdown voltage decreased more when sample was exposed to $NF_3/O_2/Ar$ plasma than to $CF_4/O_2/Ar$ plasma. The decrease of the breakdown voltage was lower in the anodic oxide film samples that were grown slowly at lower temperatures. The rate of breakdown voltage decrease after exposure to fluorine plasma was highest at $20^{\circ}C$, indicating that the anodic oxide film was most vulnerable to erosion by fluorine plasma at that temperature. Contamination particles generated by exposure to the $CF_4/O_2/Ar$ and $NF_3/O_2/Ar$ plasmas were measured on a real-time basis. The number of contamination particles generated after the exposure to the respective plasmas was lower at $5^{\circ}C$ and higher at $0^{\circ}C$. In particular, for the entire temperature range, about five times more contamination particles were generated with exposure to $NF_3/O_2/Ar$ plasma than for exposure to $CF_4/O_2/Ar$ plasma. Observation of the surface of the anodic oxide film showed that the pore size and density of the non-treated film sample increased with the increase of the temperature. The change of the surface after exposure to fluorine plasma was greatest at $0^{\circ}C$. The generation of contamination particles by fluorine plasma exposure for the anodic oxide film prepared in the present study was different from that of previous aluminum anodic oxide films.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.191-193
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• 2001

This paper presents the result of groundwater analysis in Changwon area and the characteristics of the groundwater properties. Changwon city conducted groundwater analysis at 551 sites in 1996 and 1997. The water quality is suitable as groundwater use at 466 sites (84.6 %) and exceeds maximum contaminant levels (MCLs) at 85 sites (15.4 %). Major contaminants are total bacteria, coliform and nitrate-N. DNAPLs, e.g. TCE and PCE are detected in the areas of industrial complex and residence. The detection of TCE and PCE is due to organic solvents from manufacturing companies. They are also derived from laundries, Photographer's studios, septic tanks, etc. In addition, fifty groundwater samples were analyzed. Iron, manganese, zinc, copper, lead, aluminum and fluorine are detected in nearly all the groundwater samples. The groundwaters shown on the Piper diagram mostly belong to Ca-HCO$_3$ type.

• Journal of the Korean Society of Food Science and Nutrition
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• v.28 no.1
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• pp.22-27
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• 1999

This study was performed to investigated the contamination levels of harmful heavy metals were sampled from Aug. 1 to Aug. 31, 1997, at 9 areas in Cheonbuk area. The heavy metal contents were determinated by ICPS(Inductively Coupled Plasma Spectrometer) method. The levels of total lead, cadmium, aluminum, iron and copper were determined and the results were summarized as follows: The minimum and maximum values(ppm) of 9 areas of Carassius auratus were Pb: 2.03~6.19, Cd: 0.06~ 0.76, Al: 8.84~23.5, Zn: 10.68~48.71, Cu: 0.60~1.51ppm. Among the five heavy metals contents, the highest was zinc and the lowest was cadmium. The results showed that the contents of Pb, Cd, Al, Zn and Cu in Carassius auratus were lower than the FAO/WHO maximum allowance.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2002.10a
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• pp.302-307
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• 2002

In electropolishing, the ion from the surface of the metal is eliminated by means of an electrical potential and current. Electropolishing is being generally known as a replacement for mechanical finishing. In addition to making a surface smoother, it is a more visible means of brightening, deburring, cleaning, stress-relieving and improving the physical characteristics of most metals and alloys. Therefore, the aim of the present study is to investigate the characteristic of electropolishing STS304 and A12024 in terms of current density, polishing time and electrode gap, etc.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.100-106
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• 2000

Recently, the population of vehicles using LPG as fuel has been increasing due to relatively low fuel price and low tax. Although gasoline engine oils we usually used to lubricate LPG engines, some troubles such as oil thickening and TBN depletion were found in them under severe operating condition. In order to investigate the deterioration mechanism of lubricants in LPG engine, field trials were performed. The results from the field trials showed that the deterioration of oils in LPG engine is different from that in normal gasoline engine. LPG engine oil was deteriorated mainly through oxidation and nitration at high temperature rather than contamination of fuel combustion products.

• Journal of the Korean Society of Food Science and Nutrition
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• v.29 no.5
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• pp.758-761
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• 2000

This study was performed to investigate the contamination levels of harmful heavy metals that sampled from June. 1 to June. 31, 1999, at 3 areas in Jeonbuk west cost area. The heavy metal contents were determinated by ICPS (Inductively Coupled Plasma Spectrometer) method. The levels of total lead, cadmium, aluminum, zinc and copper were determined and the results were summarized as follows: The minimum and maximum values (ppm) of 3 areas of shellfishes (shortneck clam, hard clam, cockle clam, snail and top sell) were Pb: 1.29~4.35, Cd:0.12~0.37, Al: 9.45~54.06, Zn: 9.65~15.14, Cu: 0.62~1.64 ppm.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.5
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• pp.670-677
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• 2010

There are many surface protection methods for numerous steel structures being used under severely corrosive environment, one of them, metallizing(thermal spray) is a available protection method which is comparatively and recently developed for surrface protection of various steel structures. However coating film obtained by spraying is to be needed increasingly more good corrosion resistance due to accelerating of environmental contamination. In this study, coating films(DFT:$200{\mu}m$) are performed with arc spray by wire metal and their types of films are pure zinc, pure aluminum, alloy film(Al:Zn=85:15) and alloy film(Al:Zn=95:5). And corrosion resistance of their films was investigated with electrochemical methods in seawater solution. Pure aluminum film showed a relatively somewhat good corrosion resistance compared to among those of other films and alloy films also showed a good corrosion resistance compared to pure zinc film. Especially it was observed that pure aluminum film showed a comparatively good corrosion resistance than that of alloy film named as galvarium spray(Al:Zn=85:15) in seawater solution. Morphology of corroded surface of pure zinc film appeared the pattern like intergranlar corrosion, however films of pure aluminum and alloy metal showed a general corrosion pattern.

• Corrosion Science and Technology
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• v.7 no.1
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• pp.50-60
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• 2008

The majority of the described experimental results deal with relatively pure aluminium. Variations were made in the pretreatment of the aluminum substrates and an investigation was performed on the resulting changes in oxide layer composition and chemistry. Subsequently, the bonding behavior of the surfaces was investigated by using model adhesion molecules. These molecules were chosen to represent the bonding functionality of an organic polymer. They were applied onto the pretreated surfaces as a monolayer and the bonding behavior was studied using infrared reflection absorption spectroscopy. A direct and clear relation was found between the hydroxyl fraction on the oxide surfaces and the amount of molecules that subsequently bonded to the surface. Moreover, it was found that most bonds between the oxide surface and organic functional groups are not stable in the presence of water. The best performance was obtained using molecules, which are capable of chemisorption with the oxide surface. Finally, it was found that freshly prepared relatively pure aluminum substrates, which are left in air, rapidly lose their bonding capacity towards organic functional groups. This can be attributed to the adsorption of contamination and water to the oxide surface. In addition the adhesion of a typical epoxy-coated aluminum system was investigated during exposure to water at different temperatures. The coating was found to quite rapidly lose its adhesion upon exposure to water. This rapid loss of adhesion corresponds well with the data where it was demonstrated that the studied epoxy coating only bonds through physisorptive hydrogen bonding, these bonds not being stable in the presence of water. After the initial loss the adhesion of the coating was however found to recover again and even exceeded the adhesion prior to exposure. The improvement could be ascribed to the growth of a thin oxyhydroxide layer on the aluminum substrate, which forms a new, water-stable and stronger bond with the epoxy coating. Two routes for improvement of adhesion are finally decribed including an interphasial polymeric thin layer and a treatment in boiling water of the substrate before coating takes place. The adhesion properties were finely also studied as a function of the Mg content of the alloys. It was shown that an enrichment of Mg in the oxide could take place when Mg containing alloys are heat-treated. It is expected that for these alloys the (hydr)oxide fraction also depends on the pre-treatment and on the distribution of magnesium as compared to the aluminium hydroxides, with a direct impact on adhesive properties.