• Title/Summary/Keyword: Aluminum compound

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The Compound Refractive Lens for Hard X-ray Focusing

  • Choi, J.;Jung, J.;Park, S.;Kwon, T.
    • Journal of the Optical Society of Korea
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    • v.11 no.2
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    • pp.76-81
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    • 2007
  • The compound refractive X-ray lens (CRL) for focusing hard X-rays is investigated to determine the parameters such as the focal length, the focal spot size, and spatial distribution at the focal spot using a simple theoretical calculations and CRLs fabricated by the self-assembly method. The number of individual compound lenses are defined for the given focal length of 1 m. The X-ray energy of 1 to 40 keV is used in the calculations. The CRL for focusing hard X-rays which generated from the X-ray tube is fabricated by nanoparticle-polymer composite in the form of circular concaves. The self-assembly method is applied to form the nanoaluminum-poly (methly meth-acrylate) composite and carbon-polymer composite CRL lenses. Aluminum nanoparticles of 100 nm and carbon microparticles are diffused in the polymer solution then the high gravity up to 6000G is applied in it to form the concave lens shape. X-ray energy at 8 keV is used for characterization of the composite CRLs. The FWHM of intensity for the fabricated nanoaluminium composite CRL system, N=10 is measured as 1.8 mm, which would give about $70{\mu}m$ in FWHM at 1 m of the focal length.

Photodegradation of Volatile Organic Compound (VOC) Through V-Doped or CuOx-grafted $TiO_2$ nanoparticles

  • Kim, Beum Woo;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.271.1-271.1
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    • 2013
  • Titania is usually used in sun-screens, tooth paste, and other daily used objects as a pigment. However, scientists have focused on titania as photocatalyst due to its excellent activities. By fabricating vanadium doped TiO2 and CuOx co-catalyzed TiO2 nano-size filter, the degradation level of the volatile organic compound (VOC) concentration was tested using 365nm UV LED as light source in a closed chamber. Main purpose for this test is to evaluate the activities of various catalysts for degrading the VOCs which are detrimental to human body and toluene and p-xylene were chosen in the VOC removal test. Target gas materials were injected into the test chamber with dry air as carrier gas which was flowed into the gas washer bottle filled with liquid form of VOC substance. When the VOC gas flows into the chamber, it is circulated by 200 mm fan in order to contact with the set-up filter on the aluminum holder. Target gas concentration in the chamber was monitored using VOC detector (miniRae3000, Raesystems) which was also placed inside the chamber. With the measured concentration, the VOC degradation efficiency and the degradation rate were evaluated and used to compare the catalytic activities.

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The basic study on the surface treatment of aluminum substract for lithography (평판인쇄용 Aluminum지지체의 표면처리에 관한 기초연구)

  • 황찬/
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.17-34
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    • 1994
  • Recently, the photopolymer made of novolak resin as the base and the naphthoquinonediazide(NQD) as the photoreactive compound is used for the presensitized plate(PS plate). The reaction mechanism of the NQD-novolak resin on light exposure is considered. Upon exposure it undergoes a Wolff rearrangement, via ketene intermediate which react with water ti form an 3-indene carboxylic acid. It was also found that NQD type resin in this experiment shows a high relative sensitivity compared with imported sample from Japan.

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Catecholalane (1,3,2-Benzodioxaluminole) as a Selective Reducing Agent

  • 차진순;장석원;이지은;김종미;권오운;이형수;송한철
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.720-724
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    • 1996
  • Catecholalane (1,3,2-Benzodioxaluminole, CA) prepared from catechol and aluminum hydride in tetrahydrofuran (THF) is found to be a selective reducing agent. The systematic study in order to characterize the reducing properties of the reagent under practical conditions (THF, 0 or 25 ℃, the quantitative amount of reagent to compound) has been done. The reagent reduces aldehydes, ketones, esters and acid chlorides to the corresponding alcohols, and primary amides to the corresponding amines. Especially noteworthy is that the reagent can convert both aromatic and aliphatic nitriles to the corresponding aldehydes in very high yields.

A Study on Electrochemical Characteristics Aluminum Multi Matrix Compound (Al-MMC) of Neutron Absorber Material

  • Lee, Jung Hwan;Lee, Yunju;Yoo, Seung Chang;Kim, Seunghyun;Kim, Ji Hyun
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.11a
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    • pp.179-180
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    • 2018
  • Al - MMC, used as a neutron absorber, shows pitting corrosion and/or galvanic corrosion in 3.5wt.% NaCl solution. If pitting corrosion penetrates the core, neutron absorption performance could be affected. Galvanic corrosion was observed between Al 5052 and Al 1070, and pitting corrosion was observed around $B_4C$.

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Effects of Aluminum Compound on Kidney Tissues of Rats (알루미늄 화합물이 흰쥐의 신장조직에 미치는 영향)

  • Han, Sung-Hee;Kim, Joong-Man;Baek, Seung-Hwa;Han, Du-Seok;Sin, Mee-Kung
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1264-1268
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    • 1997
  • This study was performed to investigate the effects of aluminium treatment on renal damage in rats. Seventy five male Sprague-Dawley strains were divided into five groups; the control, 250 ppm $AlCl_3$, group, 500 ppm AlCl3 group, 250 ppm $Al_2(SO_4)_3$, group, 500 ppm $Al_2(SO_4)_3$ group and kept on the diet for 2 weeks. The body weight gain was more increased in $AlCl_3$, treated of rats but decreased in $Al_2(SO_4)_3$, treated rats than the control, on based in histophysiological examination, in $AlCl_3$, treated group, thyrodization of kidney tubular lumen and interstitial inflammatory cell infiltration, abscess formation were demonstrated and in $Al_2(SO_4)_3$, treated animals destruction of glomeruli and necrosis in kidney cortex by inflammatory cells were shownd. On the other hand, blue-pigmented cast was noted in tubules of $AlCl_3$ administration group whereas focal aluminium accumulation was noted at interstitial tissue in kidney of $Al_2(SO_4)_3$, administration group.

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Effects of Fe, Mn Contents on the Al Alloys and STD61 Steel Die Soldering (Al 합금과 STD61강의 소착에 미치는 첨가원소 Fe, Mn의 영향)

  • Kim, Yu-Mi;Hong, Sung-Kil;Choi, Se-Weon;Kim, Young-Chan;Kang, Chang-Seog
    • Korean Journal of Materials Research
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    • v.22 no.4
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    • pp.169-173
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    • 2012
  • Recently, various attempts to produce a heat sink made of Al 6xxx alloys have been carried out using die-casting. In order to apply die-casting, the Al alloys should be verified for die-soldering ability with die steel. It is generally well known that both Fe and Mn contents have effects on decreasing die soldering, especially with aluminum alloys containing substantial amounts of Si. However, die soldering has not been widely studied for the low Si aluminum (1.0~2.0wt%) alloys. Therefore, in this study, an investigation was performed to consider how the soldering phenomena were affected by Fe and Mn contents in low Si aluminum alloys. Each aluminum alloy was melted and held at $680^{\circ}C$. Then, STD61 substrate was dipped for 2 hr in the melt. The specimens, which were air cooled, were observed using a scanning electron microscope and were line analyzed by an electron probe micro analyzer. The SEM results of the dipping soldering test showed an Al-Fe inter-metallic layer in the microstructure. With increasing Fe content up to 0.35%, the Al-Fe inter-metallic layer became thicker. In Al-1.0%Si alloy, the additional content of Mn also increased the thickness of the inter-metallic layer compared to that in the alloy without Mn. In addition, EPMA analysis showed that Al-Fe inter-metallic compounds such as $Al_2Fe$, $Al_3Fe$, and $Al_5Fe_2$ formed in the die soldering layers.

The effects of Mg2Si(p) on microstructure and mechanical properties of AA332 composite

  • Zainon, Fizam;Ahmad, Khairel Rafezi;Daud, Ruslizam
    • Advances in materials Research
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    • v.5 no.1
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    • pp.55-66
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    • 2016
  • This paper describes a study on the effects of $Mg_2Si_{(p)}$ addition on the microstructure, porosity, and mechanical properties namely hardness and tensile properties of AA332 composite. Each composite respectively contains 5, 10, 15, and 20 wt% reinforcement particles developed by a stir-casting. The molten composite was stirred at 600 rpm and melted at $900^{\circ}C{\pm}5^{\circ}C$. The $Mg_2Si$ particles were wrapped in an aluminum foil to keep them from burning when melting. The findings revealed that the microstructure of $Mg_2Si_{(p)}/AA332$ consists of ${\alpha}$-Al, binary eutectic ($Al+Mg_2Si$), $Mg_2Si$ particles, and intermetallic compound. The intermetallic compound was identified as Fe-rich and Cu-rich, formed as polygonal or blocky, Chinese script, needle-like, and polyhendrons or "skeleton like". The porosity of $Mg_2Si_{(p)}/AA332$ composite increased from 8-10% and the density decreased from 9-12% from as-cast. Mechanical properties such as hardness increased for over 42% from as-cast and the highest UTS, elongation, and maximum Q.I were achieved in the sample of 10% $Mg_2Si$. The study concludes that combined with AA332, the amount of 10 wt% of$Mg_2Si$ is a suitable reinforcement quantity with the combination ofAA332.

Study on the Isomerization Reaction of Tetrahydrodicyclopentadiene, Tetrahydrodi(methylcyclopentadiene) Using Heteropolyacid Catalyst (헤테로폴리산 촉매를 이용한 Tetrahydrodicyclopentadiene 및 Tetrahydrodi(methylcyclopentadiene)의 이성화반응 연구)

  • Jeong, Byung Hun;Han, Jeong Sik;Kim, Seong Bo;Kang, Cheol Han;Lee, Bum Jae
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.36-40
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    • 2007
  • The study on the isomerization reaction of endo-tetrahydrodicyclopentadiene and endo-tetrahydrodi(methylcyclopentadiene) using heteropolyacid catalyst was carried out. Exo compound was prepared from endo compound through isomerization reaction. To improve the problem of aluminum chloride as an isomerization catalyst, application of heteropolyacid was attempted. In use of Keggin type heteropolyacid, catalytic activity was extremely high at cesium substitution instead of 2.5 hydrogen atoms of $H_3PW_{12}O_{40}$. Using the cesium substituted heteropolyacid, isomerization reaction rate was faster than aluminum chloride and the effect of reaction temperature and times on reactivities were compared in isomerization of tetrahydrodicyclopentadiene and tetrahydrodi(methylcyclopentadiene).

Characteristics of the Decontamination by the Melting of Aluminum Waste (용융에 의한 알루미늄 폐기물의 제염 특성)

  • Song Pyung-Seob;Choi Wang-Kyu;Min Byung-Youn;Kim Hak-I;Jung Chong-Hun;Oh Won-Zin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.95-104
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    • 2005
  • Effects of the aluminum melting temperature, melting time and a kind of flux agents on the distribution of surrogate nuclide were investigated in the electric furnace at the aluminum melting including surrogate radionuclides(Co, Cs, Sr) in order to establish the fundamental research of the melting technology for the metallic wastes from the decommissioning of the TRIGA research reactor. It was verified that the fluidity of aluminum melt was increased by adding flux agent but it was slightly varied according to the sort of flux agents. The results of the XRD analysis showed that the surrogate nuclides move into the slag phase and then they were combined with aluminum oxide to form more stable compound. The weight of the slag generated from aluminum melting test increased with increasing melting temperature and melting time and the increase rate of the slag depended on the kind of flux agents added in the aluminum waste. The concentration of the cobalt in the ingot phase decreased with increasing reaction temperature but it increased in the slag phase up to 90$\%$according to the experimental conditions. The volatile nuclides such as Cs and Sr considerably transferred from the ingot phase to the slag and dust phase.

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